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The hydrogen-lead, hydrogen-palladium, and deuterium-palladium equilibria
Published 2005Get full text
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Palladium catalysed allene carbocyclisation
Published 2010“…The method is mild, efficient and broad in scope.</p> <p>A palladium catalysed diastereoselective allene carbocyclisation reaction was developed via enamine catalysis and palladium catalysis, which allows for the efficient carbocyclisation of formyl or ketone allenes. …”
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Palladium mediated allylic fluorination
Published 2013“…<p>In this thesis, the construction of the allylic fluorides under palladium catalysis was investigated.</p> <p>Chapter 1 provides a general introduction to organofluorine compounds and the use of palladium for the formation of both Csp<sup>2</sup>- and Csp<sup>3</sup>-F bonds. …”
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Palladium-catalysed heterocycle synthesis
Published 2012“…<p><strong>Chapter 1</strong> is a literature review of selected palladium-catalysed aryl C-N and C-S bond forming reactions. …”
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Palladium- and copper-catalysed heterocycle synthesis
Published 2014“…This work describes efforts to develop and extend the utility of two of these general heterocycle precursors - <em>ortho</em>-(haloalkenyl)aryl halides A and α-(<em>ortho</em>-haloaryl) ketones B - in conjunction with cascade reactions involving the construction of key carbon-heteroatom bonds <em>via</em> palladium or copper catalysis.</p> <p>Chapter 1 entails an overview of the development of palladium- and copper-catalysed carbon-heteroatom bond forming processes. …”
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Organometallic Palladium Reagents for Polypeptide Bioconjugation and Macrocyclization
Published 2022“…The identity of the linker plays a critical role in enforcing the structure of the cyclic entity. Palladium-mediated arylation has enabled cysteine-specific modifications with a number of previously inaccessible aryl groups. …”
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Palladium catalysis in the synthesis of polyaniline-related materials
Published 2005Get full text
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Interstitial modification of palladium for partial hydrogenation reactions
Published 2016“…EELS analysis on Pd-<sup>interstitial</sup>B is the closest to direct observation of boron within the palladium lattice to date. PDF on Pd-<sup>interstitial</sup>Li shows 13.7 % of the palladium octahedral interstitial sites are occupied by lithium. …”
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Novel palladium-catalysed routes to aromatic heterocycles
Published 2013“…<p><strong>Chapter 1: Introduction</strong> A brief summary of the use of palladium as a catalyst, the characteristic reactivity of palladium complexes and the commonly used palladium-catalysed cross coupling reactions is given, with a special focus on the palladium-catalysed α-arylation of enolates and its application to the synthesis of aromatic heterocycles. …”
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Palladium-catalysed enolate arylation in the synthesis of isoquinolines
Published 2014“…Introduction</strong></p> <p>Scientific background on the development of homogeneous palladium-catalysed cross coupling reactions, focusing on the α-arylation reaction of enolates and its application to the synthesis of heteroaromatic compounds. …”
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Modification of Biopolymers Using Palladium Oxidative Addition Complexes
Published 2024“…Chapter 4: Oligonucleotide Bioconjugation with Bifunctional Palladium Reagents Organometallic reagents enable practical strategies for bioconjugation. …”
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Palladium-catalyzed allylic alkylation of enamides and allylic acetates
Published 2012“…Functionalization of enamides via allylic alkylation was achieved under the catalysis of palladium. The 5-membered N-(1H-inden-3-yl)acetamides afforded the corresponding allylic alkylation products 3 in high yields. …”
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Nickel and palladium complexes of Di-N-Heterocyclic carbenes
Published 1999“…<p>This thesis is concerned with the synthesis of two di-N-heterocyclic carbene ligands, and their reactivity towards nickel and palladium precursors in order to synthesise new organometallic pre-catalysts for a number of important reactions. …”
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Palladium-catalysed cyclisations of bromoenynamides in the synthesis and applications of amidodienes
Published 2013“…<p>The aim of this work was to investigate palladium-catalysed cyclisations of bromoenynamides in the synthesis of amidodienes, which on further reaction or oxidation can lead to a diverse range of heteroaromatic systems.…”
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