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Molten Alkali Metal Borates for High Temperature Carbon Capture
Published 2022“…As liquids with inherent immunity to morphological degradation the molten alkali metal borates displayed stable performance over 1,000 hours of continuous operation. …”
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Nickel-Borate Oxygen-Evolving Catalyst that Functions under Benign Conditions
Published 2011“…Thin catalyst films with electrocatalytic water oxidation properties similar to those of a recently reported Co-based catalyst can be electrodeposited from dilute Ni2+ solutions in borate electrolyte at pH 9.2 (Bi). The Ni-Bi films can be prepared with precise thickness control and operate at modest overpotential providing an alternative to the Co catalyst for applications in solar energy conversion.…”
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Capture and electrochemical conversion of CO2 in molten alkali metal borate–carbonate blends
Published 2022“…<jats:p>CO<jats:sub>2</jats:sub> captured from high temperature effluent gases by molten borate salts are reduced electrochemically to form carbon nanotubes.…”
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A General Method for Suzuki–Miyaura Coupling Reactions Using Lithium Triisopropyl Borates
Published 2013“…Conditions for the Suzuki–Miyaura coupling of lithium triisopropyl borates are reported, as well as a procedure for a one-pot lithiation, borylation, and subsequent Suzuki–Miyaura coupling of various heterocycles with aryl halides. …”
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Molten Alkali Metal Borate/Carbonate Salts for High Temperature CO₂ Capture and Electrochemical Conversion
Published 2022“…First, we examine molten alkali borates as a novel hybrid sorbent for CO2 conversion. …”
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Tetraarylborate polymer networks as single-ion conducting solid electrolytes
Published 2017“…A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. …”
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Molten ionic oxides for CO2 capture at medium to high temperatures
Published 2020“…Molten ionic oxides based on sodium borate and the mixed alkali-metal borates show remarkably fast kinetics and intrinsic regenerability, with no observable deterioration in performance over multiple absorption–desorption cycles under both temperature- and pressure-swing operations. …”
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Structural and Thermal Properties of Ignition Resistant Coatings for Reusable Rocket Engines
Published 2024“…From experimentation, the coating has been determined to be a three-phase metal-ceramic composite composed of nickel, cerium borate, and barium alumino-borate glass. These phases have been verified through thermodynamic modeling using FactSage. …”
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Boron in the primary and secondary coordination spheres of iron and nickel
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Bio-Inspired Polymer Composite Actuator and Generator Driven by Water Gradients
Published 2014“…Combining both a rigid matrix (polypyrrole) and a dynamic network (polyol-borate), strong and flexible polymer films were developed that can exchange water with the environment to induce film expansion and contraction, resulting in rapid and continuous locomotion. …”
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Modeling integrated photovoltaic-electrochemical devices using steady-state equivalent circuits
Published 2013“…This predictive utility is demonstrated in the case of water oxidation at the surface of a Si solar cell, using a Co–borate catalyst.…”
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Enantioselective nickel catalysis : exploiting activated C-H bonds
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Interplay of oxygen-evolution kinetics and photovoltaic power curves on the construction of artificial leaves
Published 2013“…For such a condition, we show here that the current density-voltage characteristic of the catalyst is a key determinant of the solar-to-fuels efficiency (SFE). Oxidic Co and Ni borate (Co-B[subscript i] and Ni-B[subscript i]) thin films electrodeposited from solution yield oxygen-evolving catalysts with Tafel slopes of 52 mV/decade and 30 mV/decade, respectively. …”
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