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Dinitrogen fixation chemistry of a molybdenum trisanilide system
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Synthesis and Reversible Reductive Coupling of Cationic, Dinitrogen-Derived Diazoalkane Complexes
Published 2011“…A series of cationic diazoalkane complexes [4-RC6H4C(H)NNMo(N[t-Bu]Ar)3][AlCl4] 4-RC subscript 6 H subscript 4 C(H)NNMo(N[t-Bu]Ar) subscript 3] [AlCl subscript 4]], [1-R][AlCl4] (R = NMe2, Me, H, Br, CN; Ar = 3,5-C6H3Me2) [[1-R][AlCl subscript 4] (R = NMe subscript 2, Me, H, Br, CN; Ar = 3,5-C subscript 6 H subscript 3 Me subscript 2)] has been prepared by treatment of the N2-derived [N subscript 2 derived] diazenido complex Me3SiNNMo(N[t-Bu]Ar)3 [Me subscript 3 SiNNMo(N[t-Bu]Ar) subscript 3] with 4-RC6H4CHO [4-RC subscript 6 H subscript 4 CHO] and 2 equiv of AlCl3 [AlCl subscript 3]. …”
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Deterministic parallel random-number generation for dynamic-multithreading platforms
Published 2016“…We persuaded Intel to modify its commercial C/C++ compiler, which provides the Cilk Plus concurrency platform, to include pedigrees, and we built a library implementation of a deterministic parallel random-number generator called DotMix that compresses the pedigree and then "RC6-mixes" the result. The statistical quality of DotMix is comparable to that of the popular Mersenne twister, but somewhat slower than a nondeterministic parallel version of this efficient and high-quality serial random-number generator. …”
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