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Synthesis of Dihydrooxepino[3,2-c]Pyrazoles via Claisen Rearrangement and Ring-Closing Metathesis from 4-Allyloxy-1H-pyrazoles
Published 2018-03-01Subjects: Get full text
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Access to a guanacastepene and cortistatin-related skeleton via ethynyl lactone Ireland−Claisen rearrangement and transannular (4 + 3)-cycloaddition of an azatrimethylenemethane diyl
Published 2017“…The cyclization precursors were prepared via the first reported examples of the Ireland–Claisen rearrangement of an ethynyl lactone.…”
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Synthesis and late stage modifications of Cyl derivatives
Published 2022-02-01Subjects: Get full text
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Synthesis of Indoloquinolines: An Intramolecular Cyclization Leading to Advanced Perophoramidine-Relevant Intermediates
Published 2021-10-01Subjects: Get full text
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Recent Advances in Catalytic [3,3]-Sigmatropic Rearrangements
Published 2022-02-01Subjects: “…Claisen rearrangement…”
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Claisen, Cope and Related Rearrangements in the Synthesis of Flavour and Fragrance Compounds
Published 2000-08-01Subjects: “…Claisen rearrangements…”
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PENATAAN ULANG CLAISEN 4,6-DIALIL-2-METOKSIFENOL MENGGUNAKAN GELOMBANG MIKRO
Published 2014“…Synthesis of 4,6-diallyl-2-methoxyphenol through Claisen rearrangement of eugenol using microwave had been conducted. …”
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An organocatalytic approach to the core of eunicellin.
Published 2007“…A stereocontrolled synthesis of the core of eunicellin is described featuring a Claisen rearrangement and a diastereoselective organocatalytic Diels-Alder reaction as the key steps.…”
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A short synthesis of aphanamol I in both racemic and enantiopure forms
Published 2016“…Key steps include: a catalytic enantioselective conjugate addition, an oxidative radical cyclisation, and a ringexpanding Claisen rearrangement.…”
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Synthesis of (+)-obtusenyne.
Published 2008“…An enantioselective synthesis of the halogenated medium-ring ether natural product (+)-obtusenyne is reported which uses the ring expansion of a seven-membered ketene acetal by means of a Claisen rearrangement to construct the core nine-membered oxygen heterocycle. …”
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A Concise Synthesis of the Octalactins
Published 2004“…Key steps include the Paterson-Aldol reaction for the rapid assembly of the carbonate 46, methylenation of 46 and subsequent Claisen rearrangement of the corresponding alkenyl-substituted cyclic ketene acetal to provide the core unsaturated medium-ring lactone 47, and the use of enzyme-mediated acetate deprotection in the presence of a medium-ring lactone.…”
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Mechanism and applications of lithium amide-induced asymmetric rearrangements of 4-substituted and 4,4-disubstituted cyclopentene oxides to cyclopentenols
Published 1999“…Also described are asymmetric syntheses of prostaglandin precursor 40 and (+)-iridomyrmecin (48) via highly enantioselective rearrangement of the epoxide 3 and subsequent Ireland-Claisen rearrangement. © The Royal Society of Chemistry 1999.…”
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A concise synthesis of the octalactins.
Published 2004“…Key steps include the Paterson-Aldol reaction for the rapid assembly of the carbonate 46, methylenation of 46 and subsequent Claisen rearrangement of the corresponding alkenyl-substituted cyclic ketene acetal to provide the core unsaturated medium-ring lactone 47, and the use of enzyme-mediated acetate deprotection in the presence of a medium-ring lactone.…”
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Synthesis of (+)-obtusenyne.
Published 2008“…An enantioselective synthesis of the halogenated medium-ring ether natural product (+)-obtusenyne is reported which uses the ring expansion of a seven-membered ketene acetal by means of a Claisen rearrangement to construct the core nine-membered oxygen heterocycle. …”
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Synthesis of (+)-obtusenyne
Published 2008“…An enantioselective synthesis of the halogenated medium-ring ether natural product (+)-obtusenyne is reported which uses the ring expansion of a seven-membered ketene acetal by means of a Claisen rearrangement to construct the core nine-membered oxygen heterocycle. …”
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Carbohydrate-derived molecular diversity : synthesis and application in cell biology
Published 2010“…This strategy features Claisen rearrangement of hexose to obtain the cyclohexene backbone and introduction of diamino groups through tandem intramolecular aziridination and ring opening. …”
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SINTESIS DAN AKTIVITAS ANTIOKSIDAN SENYAWA 2-METOKSI- 4,6-DI(PROP-1-ENIL) FENOL DARI EUGENOL
Published 2011“…Compound (2) was subsequently heated under Claisen rearrangement to produce 2,4-diallyl-6-methoxyphenol (3). …”
Thesis