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A generalization of the Shell Theorem. Electric potential of charged spheres and charged vesicles surrounded by electrolyte
Published 2020-05-01Subjects: Get full text
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Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model
Published 2018-08-01“…This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation) and Eyring absolute rate theory were used to fit the viscosity values of ternary aqueous solutions of polymer + electrolyte with considering temperature dependency. …”
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On the Development of a Modified Nonelectrolyte NRTL-NRF Model for Strong and Weak Electrolyte Solutions
Published 2021-02-01“…The modified model for electrolytes is composed of short-range parts expressed by the modified nonelectrolyte NRTL-NRF and the Pitzer-Debye-Hückel equation to represent the long-range interactions of ions in the solution. …”
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Chemical Thermodynamics and Calculation of Parameters of Ionic Equilibria of Indium(III) in Perchlorate, Chloride and Sulphate Aqueous Solutions
Published 2019-07-01“…The Bmnsted-Guggenheim-Scatchard’s model (Specific ion Interaction Theory, SIT), basing on extended semi-empirical Debye-Huckel equation in third approximation is supplied. …”
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The Casimir Interaction between Spheres Immersed in Electrolytes
Published 2021-05-01“…We follow the electrostatic fluctuational approach and derive the zero-frequency contribution from the linear Poisson-Boltzmann (Debye-Hückel) equation for the geometry of two spherical surfaces of arbitrary radii. …”
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HighPGibbs, a Practical Tool for Fluid‐Rock Thermodynamic Simulation in Deep Earth and its Application on Calculating Nitrogen Speciation in Subduction Zone Fluids
Published 2020-05-01“…Chemical potentials of minerals are calculated using the equations of states included in HCh; free energy of aqueous species is calculated using the Deep Earth Water model; and activity coefficients of charged species are estimated using the Davies variant of the Debye‐Hückel equation. HighPGibbs was applied to calculate nitrogen speciation in eclogite‐buffered fluids from 400 to 790 °C and 30 to 54 kbar, to evaluate the mobility of nitrogen in subducting oceanic crust. …”
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The Solution Behavior of Dopamine in the Presence of Mono and Divalent Cations: A Thermodynamic Investigation in Different Experimental Conditions
Published 2021-09-01“…The dependence on the ionic strength of complex formation constants was modeled by using both an extended Debye–Hückel equation that included the Van’t Hoff term for the calculation of enthalpy change values of the formation and the Specific Ion Interaction Theory (SIT). …”
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The Effect of Metal Cations on the Aqueous Behavior of Dopamine. Thermodynamic Investigation of the Binary and Ternary Interactions with Cd<sup>2+</sup>, Cu<sup>2+</sup> and UO<sub...
Published 2021-12-01“…The dependence on the ionic strength of complex formation constants was modelled by using both an extended Debye–Hückel equation that included the Van’t Hoff term for the calculation of the formation enthalpy change values and the Specific Ion Interaction Theory (SIT). …”
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A Review of Geochemical Modeling for the Performance Assessment of Radioactive Waste Disposal in a Subsurface System
Published 2021-06-01“…The results demonstrated that when the solution’s ionic strength was <0.5 m, the differences in the activity coefficients between the Davies and modified Debye–Hückel equations were <5%. The difference between the Pitzer and Davies equations, or between the Pitzer and modified Debye–Hückel equations in terms of the calculated activity coefficients was <8%. …”
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