Synthesis and Properties of the 5,10,15-Trimesityltruxen-5-yl Radical by Frantz, Derik K., Walish, Joseph John, Swager, Timothy Manning

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Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst by Cheung, Chi Wai, Buchwald, Stephen Leffler

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Synthesis of Spirocyclic Indolines by Interruption of the Bischler–Napieralski Reaction by Medley, Jonathan William, Movassaghi, Mohammad

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Synthesis and Application of Palladium Precatalysts that Accommodate Extremely Bulky Di-tert-butylphosphino Biaryl Ligands by Bruno, Nicholas C., Buchwald, Stephen Leffler

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Palladium-Catalyzed Amination of Unprotected Five-Membered Heterocyclic Bromides by Su, Mingjuan, Hoshiya, Naoyuki, Buchwald, Stephen Leffler

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Palladium-Catalyzed Synthesis of N-Aryl Carbamates by Fors, Brett P., Vinogradova, Ekaterina, Park, Nathaniel Hamilton, Buchwald, Stephen Leffler

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Palladium-Catalyzed N-Monoarylation of Amidines and a One-Pot Synthesis of Quinazoline Derivatives by McGowan, Meredeth A., McAvoy, Camille Z., Buchwald, Stephen Leffler

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Development of an Air-Stable Nickel Precatalyst for the Amination of Aryl Chlorides, Sulfamates, Mesylates, and Triflates by Teverovskiy, Georgiy, Park, Nathaniel Hamilton, Buchwald, Stephen Leffler

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Synthesis of Solid 2-Pyridylzinc Reagents and Their Application in Negishi Reactions by Bernhardt, Sebastian, Stathakis, Christos, Knochel, Paul, Colombe, James Robert, Buchwald, Stephen Leffler

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Twofold C−H Functionalization: Palladium-Catalyzed Ortho Arylation of Anilides by Brasche, Gordon, Garcia-Fortanet, Jorge, Buchwald, Stephen Leffler

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Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts by Cheung, Chi Wai, Surry, David S., Buchwald, Stephen Leffler

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An Improved Catalyst System for the Pd-Catalyzed Fluorination of (Hetero)Aryl Triflates by Lee, Hong Geun, Buchwald, Stephen Leffler, Milner, Phillip John

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Investigations of new potential photo-acid generators: crystal structures of 2-[(E)-2-phenylethenyl]phenol (orthorhombic polymorph) and (2E)-3-(2-bromophenyl)-2-phenylprop-2-enoic... by William T. A. Harrison, M. John Plater, Lee J. Yin

“…In (I), which crystallizes in the orthorhombic space group Pca21, compared to P21/n for the previously known monoclinic polymorph [Cornella & Martin (2013). Org. Lett. 15, 6298–6301], the dihedral angle between the aromatic rings is 4.35 (6)° and the OH group is disordered over two sites in a 0.795 (3):0.205 (3) ratio. …”
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Visible Light-Induced Homolytic Cleavage of Perfluoroalkyl Iodides Mediated by Phosphines by Mario Bracker, Lucas Helmecke, Martin Kleinschmidt, Constantin Czekelius, Christel M. Marian

“…In an effort to explain the experimentally observed variation of the photocatalytic activity of <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mi>t</mi> </msup> </semantics> </math> </inline-formula>Bu<inline-formula> <math display="inline"> <semantics> <msub> <mrow></mrow> <mn>3</mn> </msub> </semantics> </math> </inline-formula>P, <inline-formula> <math display="inline"> <semantics> <msup> <mrow></mrow> <mi>n</mi> </msup> </semantics> </math> </inline-formula>Bu<inline-formula> <math display="inline"> <semantics> <msub> <mrow></mrow> <mn>3</mn> </msub> </semantics> </math> </inline-formula>P and (MeO)<inline-formula> <math display="inline"> <semantics> <msub> <mrow></mrow> <mn>3</mn> </msub> </semantics> </math> </inline-formula>P in the blue-light regime [Helmecke et al., Org. Lett. 21 (2019) 7823], we have explored the absorption characteristics of several phosphine– and phosphite–IC<inline-formula> <math display="inline"> <semantics> <msub> <mrow></mrow> <mn>4</mn> </msub> </semantics> </math> </inline-formula>F<inline-formula> <math display="inline"> <semantics> <msub> <mrow></mrow> <mn>9</mn> </msub> </semantics> </math> </inline-formula> adducts by means of relativistic density functional theory and multireference configuration interaction methods. …”
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