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781
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782
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783
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784
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785
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786
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787
Nucleophilic vinylic substitution in bicyclic methyleneaziridines: SNVπ or SNVσ?
Published 2021“…Ring-opening of this aziridine with copper-based organometallics follows a pathway that results in stereoretentive substitution, replacing the exo-C–N bond with a corresponding C–C bond; this stereochemical outcome supports either an overall SNVπ mechanism or a C–N insertion / reductive coupling process.…”
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788
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789
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790
SURFACE DECOMPOSITION MECHANISM OF THE NOVEL PRECURSOR BISTRIMETHYLAMINE ALUMINUM-HYDRIDE ON GAAS(100)
Published 1990“…This contrasts markedly with the decomposition of organometallics like trimethyl aluminium (TMA) which are traditionally used in Al CVD where carbon incorporation is an intrinsic part of the decomposition process. © 1990.…”
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791
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792
Electronic structure, excited states, and photoelectron spectra of uranium, thorium, and zirconium bis(Ketimido) complexes (C5R5)2M[-NCPh2]2 (M = Th, U, Zr; R = H, CH3).
Published 2005“…Soc., 2005, 127, 682; Jantunen et al., Organometallics, 2004, 23, 4682; Morris et al., Organometallics, 2004, 23, 5142.] …”
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793
Exploring the phase stability in interpenetrated diamondoid covalent organic frameworks
Published 2023-01-01Get full text
Article -
794
Metal Sulfide Nanoparticles for Imaging and Phototherapeutic Applications
Published 2023-03-01Get full text
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795
Catalytic asymmetric carbon-carbon bond formation using alkenes as alkylmetal equivalents.
Published 2012“…Catalytic asymmetric conjugate addition reactions with organometallic reagents are powerful reactions in synthetic chemistry. …”
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796
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797
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798
Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Chlorobenzenesulfonates
Published 2021-09-01“…A broad range of chlorobenzenesulfonates as well as challenging alkyl organometallics containing β-hydrogens are compatible with these conditions, affording alkylated products in high to excellent yields. …”
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799
The 2-pyridyl problem: challenging nucleophiles in cross-coupling arylations
Published 2020“…However, 2‐pyridine organometallics are capricious coupling partners and 2‐pyridyl boron reagents in particular are notorious for their instability and poor reactivity in Suzuki‐Miyaura cross‐coupling reactions. …”
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800