Part I: Iron (III)-catalyzed reactions of benzylic analogs with organosilanes & Conia-ene cyclization. Part II: Palladium (II)-catalyzed C-H functionalizations using mono-phosphoric acid directing group by Chan, Li Yan

“…In the second part, a novel mono-phosphoric acid directing group was used to facilitate palladium(II)-catalyzed C-H functionalization reactions, that occurred in high selectivity at the ortho-position. …”
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Asymmetric synthesis of functionalized chiral diphosphines via organopalladium promoted hydrophosphination and diels-alder reactions by Yuan, Mingjun

“…Introduction of functionalities on chiral diphosphines using organic transformations with palladium template as protection is also demonstrated. …”
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Deposition of metal nanoparticles on g-C3N4 for efficient photocatalyst by Lim, Andrew Dekun

“…Three types of metals including gold, palladium, platinum and its alloys were used to dope graphitic carbon nitride. …”
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A concise, efficient synthesis of sugar-based benzothiazoles through chemoselective intramolecular C–S coupling by Shen, Chao, Xia, Haijun, Yan, Hua, Chen, Xinzhi, Ranjit, Sadananda, Xie, Xiaoji, Tan, Davin, Lee, Richmond, Yang, Yanmei, Xing, Bengang, Huang, Kuo-Wei, Zhang, Pengfei, Liu, Xiaogang

“…Here, we have synthesized a wide range of sugar-based benzothiazoles from readily accessible glycosyl thioureas by chemoselective, palladium-catalyzed C–S coupling reactions. Corroborated by theoretical calculations, a mechanistic investigation indicates that the coordination to the palladium by a pivaloyl carbonyl group and the presence of intramolecular hydrogen bonding play important roles in the efficiency and chemoselectivity of reaction. …”
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Design and fabrication of singular phase nanophotonic cavities for phase sensitive hydrogen sensing by Goh, Gordon Jun Sheng

“…For both optical and electrical sensors, palladium is commonly used for hydrogen sensing due to its high selectivity and response to hydrogen adsorption. …”
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A study of pd-b nanoparticles synthesized by stepwise electroless deposition for oxygen reduction reaction catalysts by Choo, Nigel Kian Wee

“…Several combinations of metal solution and reducing agent such as Dimethylamineborane (DMAB) doped Palladium (Pd) was tested out in this report to observe their catalytic ability. …”
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Site-Selective Anion Exchange in a Palladophosphorane by Khuichad, Nichakan

“…Reported here are studies on the chemoselective ligand substitution at a palladophosphorane possessing two potential sites of chloride substitution. Ligation of palladium(II) chloride with a tridentate chelating ligand (L, P(N(o-N(2-pyridyl)C₆H₄)₂) results in formation of a complex comprising a d⁸ square planar palladium center supported by a geometrically constrained chlorophosphorane (PdClL superscript Cl). …”
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Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes by Lim, Maricar Bungabong

“…The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. …”
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Synthesis of an unnatural amino acid for genetic incorporation into recombinant proteins. by Chia, Siew Meng.

“…The benzyl protecting groups can be removed by catalytic hydrogenation using palladium black as catalyst. The azalysine obtained could be used for incorporation into recombinant proteins for applications such as detection of oxidized carbonyl-containing protein molecules, or labeling with reactive carbonyl-containing probes to visualize proteins in vivo so as to study protein localization, concentrations or dynamics.…”
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α-palladation of Imines as entry to dehydrogenative heck reaction: Aerobic oxidative cyclization of N-Allylimines to Pyrroles by Ding, Zhenhua, Gao, Ke, Chen, Zhiyuan, Lu, Beili, Yoshikai, Naohiko

“…We report here a palladium(II)-catalyzed oxidative cyclization reaction of N-allylimines derived from methyl ketones, typically acetophenones, affording pyrrole derivatives at room temperature under oxygen atmosphere. …”
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Calibration-free reaction yield quantification by HPLC with a machine-learning model of extinction coefficients by McDonald, Matthew A., Koscher, Brent A., Canty, Richard B., Jensen, Klavs F.

“…We demonstrate the method for a variety of reactions important in medicinal and process chemistry, including amide couplings, palladium catalyzed cross-couplings, nucleophilic aromatic substitutions, aminations, and heterocycle syntheses. …”
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Synthetic protocols for designing chiral P,N-chelate complexes by Katona, David

“…The synthesized P,N ligand proved to be suitable for performing the complexation of Pd(II), Pt(II), Rh(I), Ir(I), Ni(II) and Ru(II) metal sources. Palladium and platinum dimethylmalonate complexes could be achieved in an enantiopure form, and their rhodium and iridium counterparts could be realized as enantioenriched mixtures. …”
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Total synthesis of complex natural products by Kučera, R

“…</p> <p><strong>Chapter 2</strong> details the development of the enantioselective synthesis of <em>Daphniphyllum</em> alkaloids based on the previous accomplishments of our research group. The combination of palladium/enamine cocatalysed enantioselective synthesis of the morphan core and Michael addition – ketone allylation – ringclosing metathesis sequence enabled a highly convergent total synthesis of Himalensine A. …”

Catalytic asymmetric diarylphosphine addition to α-diazoesters for the synthesis of P-stereogenic phosphinates via P*-N bond formation by Balázs, László B., Huang, Yinhua, Khalikuzzaman, Jasmina B., Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing

“…Interaction between the diazoester and the palladium catalyst resulted in the unusually enhanced electrophilic ability of the terminal nitrogen in the diazo functionality, as opposed to the commonly expected formation of a metal carbene by nitrogen elimination. …”
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Atomic layer deposition of metallic tri-layer for alloy formation by Yong, Sidney Kwong Roong

“…In this paper, we studied the deposition of metallic tri-layer consisting of Platinum (Pt), Iridium (Ir), and Palladium (Pd), which was synthesized using ALD. The metal layers were deposited on Sapphire (Al2O3) with ozone as a reactive agent. …”
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Fabrication of PANI/GO/Pd nanocomposite based tapered optical fiber for hydrogen gas sensing applications by Alkhabet, Mohammed M., Girei, Saad H., Farhan, Ammar Hatem, Altalebi, Omar, Al-Isawi, Zaid Khalaf, Khalaf, Ahmed L., Jaafar, Jaafar A., Yaacob, Mohd H.

“…The study focuses on developing and evaluating H2 gas sensors based on optical fiber coated with nanocomposites such as polyaniline (PANI), graphene oxide (GO), and palladium (Pd) as sensing layers. An optical transducing channel was developed using a 125 μm diameter multimode optical fiber to improve the light field. …”
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Applications of bio-resource based sustainable heterogeneous Pd-Nanocatalyst for Cross-Coupling and Michael addition reactions by Islam, Md. Shaharul, Sarkar, Shaheen M., Rahman, Md Lutfor, Hasan, Kamrul, O’Reilly, Emmet J.

“…Herein, we developed a bio-heterogeneous Pd-nanocatalyst (PdNc@PA) by incorporating palladium nanoparticles into biodegradable kenaf-cellulose modified with poly(amidoxime) ligands. …”
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Heck reaction of alkyl halides and α-selective heck reaction of styrenes by Zou, Yinjun

“…In the second part, we disclosed an efficient catalyst – Pd/dppf for the intermolecular Heck reaction of alkyl halides, which is a challenging problem in palladium catalysis. The simple and easily accessible Pd/dppf catalyst showed good reactivity as well as good selectivity. …”
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Effect of processing parameters on electroless Cu seed layer properties by Chen, Z., Chan, L., See, Alex K. H., Law, S. B., Zeng, K. Y., Shen, L., Tee, K. C., Ee, Elden Yong Chiang

“…In the current work, electroless copper was deposited on a TiN surface activated by palladium. The effect of deposition time on the properties of electroless Cu films was reported. …”
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Development of cellulose-supported Pd-nanocatalyst for the heck coupling and michael addition reactions by Sarkar, Shaheen M., Rahman, Md Lutfor, Hasan, Kamrul, Rahman Khan, Md. Maksudur, O’Reilly, Emmet J., Mohd Hasbi, Ab Rahim

“…Herein, cellulose-supported bio-resourced poly(hydroxamic acid) is employed as a ligand in the synthesis of a palladium nanocomposite (PdNc-PHA) that exhibits higher TONs that previously reported similar systems for the Mizoroki-Heck and Michael addition reactions. …”
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