Synthesis of a π-extended azacorannulenophane enabled by strain-induced 1,3-dipolar cycloaddition by Zhang, Xinjiang, Mackinnon, Marc R., Bodwell, Graham J., Ito, Shingo

“…The first example of a cyclophane bearing a nitrogen-containing buckybowl was synthesized via sequential 1,3-dipolar cycloaddition and palladium-catalyzed intramolecular cyclization. The key to the successful synthesis is the strain-induced 1,3-dipolar cycloaddition of a polycyclic aromatic azomethine ylide to the K-region of [7](2,7)pyrenophane. …”
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Electroless copper deposition as a seed layer on TiSiN barrier by Chen, Z., Xu, S., Chan, L., See, K. H., Law, S. B., Ee, Elden Yong Chiang

“…The properties of deposited electroless copper are characterized by x-ray diffraction, four-point resistivity probe, atomic force microscopy, and field emission scanning electron microscope. The required palladium activation time is greatly reduced on TiSiN compared to TiN. …”
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