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Hydrodehalogenation of aryl halides through direct electrolysis
Published 2020“…A catalyst- and metal-free electrochemical hydrodehalogenation of aryl halides is disclosed. Our reaction by a flexible protocol is operated in an undivided cell equipped with an inexpensive graphite rod anode and cathode. …”
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Electrophotocatalytic hydrogenation of imines and reductive functionalization of aryl halides
Published 2024-01-01“…In the absence of TfOH, the reducing ability of the system can reach a potency even comparable to that of Na0 or Li0, thereby allowing the hydrogenation, borylation, stannylation and (hetero)arylation of aryl halides to construct C−H, C−B, C−Sn, and C−C bonds.…”
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Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides
Published 2023-07-01“…This heterogeneous approach is successfully applied in the photoreduction of inert aryl halides and the successive formation of CAr−C/S/P/B bonds with potential pharmaceutical applications.…”
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Palladium-catalyzed asymmetric reductive heck reaction of aryl halides
Published 2015“…Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.…”
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Palladium-catalyzed solid-state borylation of aryl halides using mechanochemistry
Published 2022-07-01“…This study describes the solid-state palladium-catalyzed cross-coupling between aryl halides and bis(pinacolato)diboron using ball milling. …”
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Protocol for Sonogashira coupling of alkynes and aryl halides via nickel catalysis
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INFLUENCE OF HALOGEN NATURE ON THE ADSORPTION ABILITY OF ARYL HALIDES ON PALLADIUM CLUSTERS
Published 2021-12-01Subjects: Get full text
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Palladium-catalysed addition of aryl halides to N-sulfinylamines for the synthesis of sulfinamides
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Palladium-Catalyzed Addition of Aryl Halides to N ‑Sulfinylamines for the Synthesis of Sulfinamides
Published 2024Journal article -
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Visible-Light Photocatalytic Reduction of Aryl Halides as a Source of Aryl Radicals
Published 2022-08-01Subjects: Get full text
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Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media
Published 2017“…A mild, efficient, and low-temperature palladium-catalyzed cyanation of (hetero)aryl halides and triflates is reported. Previous palladium-catalyzed cyanations of (hetero)aryl halides have required higher temperatures to achieve good catalytic activity. …”
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Amino/alkoxycarbonylation of aryl halides mediated by group VI metal carbonyl complexes
Published 2012“…Caboxylic amides are easily prepared by carbamoylation of aryl halides which was accomplished in the reaction of aryl halides and amines in the presence of group VI metal carbonyl complex such as Mo(CO)6. …”
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Nickel-Catalyzed Asymmetric Reductive Heck Cyclization of Aryl Halides to Afford Indolines
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Synthesis, Reactivity and Stability of Aryl Halide Protecting Groups towards Di-Substituted Pyridines
Published 2016-03-01Subjects: “…aryl halide protecting groups…”
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An Electrochemical Synthesis of Functionalized Arylpyrimidines from 4-Amino-6-Chloropyrimidines and Aryl Halides
Published 2011-06-01“…A range of novel 4-amino-6-arylpyrimidines has been prepared under mild conditions by an electrochemical reductive cross-coupling between 4-amino-6-chloro-pyrimidines and functionalized aryl halides. The process, which employs a sacrificial iron anode in conjunction with a nickel(II) catalyst, allows the formation of coupling products in moderate to high yields.…”
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Prospects and Applications of Palladium Nanoparticles in the Cross‐coupling of (hetero)aryl Halides and Related Analogues
Published 2021-04-01“…This review presents the progress, the challenges and the prospects of palladium nanoparticle with focus on Heck, Suzuki, Hiyama and Sonogashira cross‐coupling reactions involving (hetero) aryl halides and the analogues.…”
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Photo-induced transition-metal and photosensitizer free cross–coupling of aryl halides with disulfides
Published 2021-08-01Subjects: Get full text
Article