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Asymmetric synthesis of (-)-(S,S)-homaline
Published 2012“…The asymmetric synthesis of (-)-(S,S)-homaline was achieved in 8 steps from commercially available starting materials using the diastereoselective conjugate addition of the novel lithium amide reagent lithium (R)-N-(3-chloropropyl)-N-(α-methyl-p-methoxybenzyl)amide to methyl cinnamate to install the correct stereochemistry. …”
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Asymmetric synthesis of cyclopropanes
Published 1988“…<p>This thesis is concerned with the asymmetric synthesis of cyclopropyl derivatives <em>via</em> the use of chiral iron acyl complexes of the type (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Fe(CO)(PPh<sub>3</sub>)(COCH=CR'R), Chapter 1 reviews previous routes to optically active cyclopropyl derivatives and reviews the use of the chiral auxiliary (η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)Fe(CO)(PPh<sub>3</sub>) for asymmetric synthesis.…”
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Asymmetric synthesis of (-)-codonopsinine
Published 2011“…The asymmetric synthesis of (-)-codonopsinine was achieved in 7 steps (from commercially available tert-butyl crotonate) in 5% overall yield and >99:1 dr. …”
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Asymmetric synthesis and applications of beta-amino Weinreb amides: asymmetric synthesis of (S)-coniine.
Published 2004Journal article -
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