Chelating monoborane phosphines: Rational and high-yield synthesis of [(COD)Rh{(eta(2)-BH(3))Ph(2)PCH(2)PPh(2)}][PF(6)] (COD=1,5-cyclooctadiene) by Ingleson, M, Patmore, N, Ruggiero, G, Frost, C, Mahon, M, Willis, M, Weller, A

“…Complex 1 is isolated as an air-stable crystalline salt, and its applicability as a catalyst in organic synthesis has been demonstrated in the coupling of boronic acids with enones.…”

Novel animal-bone-meal-supported palladium as a green and efficient catalyst for Suzuki coupling reaction in water, under sunlight by Yassine Riadi, Mohammed Geesi, Oussama Dehbi, Mohammed A. Bakht, Mohammed Alshammari, Marie-Claude Viaud-Massuarde

“…This palladium has showed a high catalytic activity than tetrakis(triphenylphosphine) palladium (Pd(PPh3)4) in the Suzuki cross-coupling reaction (the reaction of 4-halogenopyridopyrimidine with boronic acids) in water via sunlight as the light source, with no addition of ligands. …”
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Copper(I)-catalyzed sulfonylative Suzuki-Miyaura cross-coupling by Willis, M, Chen, Y

“…The process provides a single step route to diaryl sulfones from the direct combination of aryl boronic acids, sulfur dioxide and aryl iodides, and represents the first sulfonylative variant of a classic cross-coupling reaction. …”

A Convenient Synthesis of Diketopyrrolopyrrole Dyes by Vitor A. S. Almodôvar, Augusto C. Tomé

“…The synthesis includes a Suzuki–Miyaura cross-coupling reaction of a bis(4-chlorophenyl)DPP derivative with aryl and hetaryl boronic acids under mild reaction conditions. The new dyes show large Stokes shifts and high fluorescence quantum yields, important features for their potential use in technical and biological applications.…”
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Synthesis of Boron-Containing Primary Amines by Sheng-Hsuan Chung, Ting-Ju Lin, Qian-Yu Hu, Chia-Hua Tsai, Po-Shen Pan

“…The prepared Ugi-4CR boronate esters were then successfully converted to the corresponding boronic acids. Finally, the peptoid structures were successfully modified by cross-coupling to aryl/heteroaryl chlorides via a palladium-mediated Suzuki coupling reaction to yield the corresponding derivatives in moderate to good yields.…”
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P III /P V =O Catalyzed Cascade Synthesis of N‐Functionalized Azaheterocycles by Nykaza, Trevor V, Li, Gen, Yang, Junyu, Luzung, Michael R, Radosevich, Alexander T

“…The method employs a small-ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane P-oxide) and a hydrosilane reductant to drive the conversion of ortho-functionalized nitroarenes into azaheterocycles through sequential intermolecular reductive C−N cross coupling with boronic acids, followed by intramolecular cyclization. …”
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Direct synthesis of highly substituted pyrroles and dihydropyrroles using linear selective hydroacylation reactions by Majhail, MK, Ylioja, PM, Willis, MC

“…The hydroacylation reactions can also be combined in a cascade process with a RhI-catalysed Suzuki-type coupling employing aryl boronic acids, providing a three-component assembly of highly substituted pyrroles.…”

Palladium (0) catalyzed synthesis of thiophene based 1,3,4-oxadiazoles their reactivities and potential nonlinear optical properties by Abbas, Mujahad, Abbas, Komal, Rizwan, Nasir, Rasool, Muhammad Ali, Hashmi, Gulraiz, Ahmad, Umer, Rashid

“…Novel thiophene based 1,3,4-oxadiazoles were synthesized via Suzuki cross-coupling of 2-(5-bromothiphen-2-yl)-5-phenyl-1,3,4-oxadiazole with various substituted aryl-boronic acids in significant yields (58-78%). Density functional theory (DFT) investigations were accomplised on novel oxadiazoles (5a-5j) to explore their structural properties. …”

Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent by Najmedin Azizi, Elham Farhadi

“…An efficient and straightforward one-pot three-component Petasis reactions of salicylaldehyde derivatives with various amines and boronic acids in the glycerol/choline chloride-based deep eutectic solvent (DES) were developed. …”
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Three-Component Suzuki–Knoevenagel Synthesis of Merocyanine Libraries and Correlation Analyses of Their Oxidation Potentials and Optical Band Gaps by Tim Meyer, Roxanne Krug, Thomas J. J. Müller

“…The Suzuki coupling Knoevenagel condensation one-pot synthesis of boronic acids/esters, (hetero)aromatic bromo aldehydes and methylene active compounds is a highly practical consecutive three-component process to provide substance libraries with 60 donor-π-bridge-acceptor molecules, i.e., merocyanines in a broader sense, in moderate to excellent yield. …”
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Highly Luminescent 4<i>H</i>-1,2,4-Triazole Derivatives: Synthesis, Molecular Structure and Photophysical Properties by Monika Olesiejuk, Agnieszka Kudelko, Marcin Świątkowski

“…The described methodology allows one to conduct the coupling reaction with the use of commercially available boronic acids in the presence of conventional solvents or ionic liquids and produced excellent yields. …”
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Ultrasound assisted synthesis of 6-flavonyl substituted 1,4-dihydro-benzo[d][1,3]oxazin-2-ones via Suzuki–Miyaura coupling under Pd/C catalysis by Namburi Suresh, Gutta Lakshmi Prasanna, Mandava Venkata Basaveswara Rao, Manojit Pal

“…Pd/C facilitated Suzuki–Miyaura coupling of 2-aryl-3-bromoflavones with 4,4-disubstituted (1,4-dihydro-2-oxo-2H-3,1-benzoxazin-6-yl)boronic acids under ultrasound irradiation. The methodology involving the use of 10%Pd/C-TBAB-K2CO3 system in DMF/H2O afforded corresponding 6-flavonyl substituted 1,4-dihydro-benzo[d][1,3]oxazin-2-ones in good yield within a short reaction time. …”
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Recyclable graphene-supported palladium nanocomposites for Suzuki coupling reaction by Upadhyay Praveenkumar Ramprakash, Srivastava Vivek

“…The optimized protocol was applied to a wide range of substituted aryl/hetroaryl halides along with various aryl boronic acids and afforded the corresponding reaction products in good to excellent yield. …”
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P(III)/P(V)-Catalyzed Methylamination of Arylboronic Acids and Esters: Reductive C–N Coupling with Nitromethane as a Methylamine Surrogate by Li, Gen, Qin, Ziyang, Radosevich, Alexander T

“…This method operates by the action of a small ring organophosphorus-based catalyst (1,2,2,3,4,4-hexamethylphosphetane P-oxide) together with a mild terminal reductant hydrosilane to drive the selective installation of the methylamino group to (hetero)aromatic boronic acids and esters. This method also provides for a unified synthetic approach to isotopically labeled N-methylanilines from various stable isotopologues of nitromethane (i.e., CD3NO2, CH315NO2, and 13CH3NO2), revealing this easy-to-handle compound as a versatile precursor for the direct installation of the methylamino group.…”
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Structural basis of metallo-β-lactamase, serine-β-lactamase and penicillin-binding protein inhibition by cyclic boronates by Brem, J, Cain, R, Cahill, S, McDonough, M, Clifton, I, Jiménez-Castellanos, J, Avison, M, Spencer, J, Fishwick, C, Schofield, C

“…Pioneering work revealed that acyclic boronic acids can act as 'transition state analogue' inhibitors of nucleophilic serine enzymes, including serine-β-lactamases. …”

Structural and kinetic studies on beta-lactamase mechanism and inhibition by Cahill, S

“…In the work described herein, cyclic boronic acids were explored as a chemotype with inhibitory activity against the two mechanistic classes of beta-lactamase and are shown to be potent inhibitors of both. …”

Development of Facile and Simple Processes for the Heterogeneous Pd-Catalyzed Ligand-Free Continuous-Flow Suzuki–Miyaura Coupling by Tsuyoshi Yamada, Jing Jiang, Naoya Ito, Kwihwan Park, Hayato Masuda, Chikara Furugen, Moeka Ishida, Seiya Ōtori, Hironao Sajiki

“…A continuous-flow ligand-free Suzuki–Miyaura coupling reaction of (hetero)aryl iodides, bromides, and chlorides with (hetero)aryl boronic acids was developed using cartridges packed with spherical resin (tertiary amine-based chelate resin: WA30)-supported palladium catalysts (7% Pd/WA30). …”
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Synthesis and Herbicidal Activity of Phenylpyridines – A New Lead by Peter Schäfer, Gerhard Hamprecht, Michael Puhl, Karl-Otto Westphalen, Cyrill Zagar

“…Their preparation follows Suzuki-type coupling conditions of reactive 2-chloro-pyridines with appropriate 2,5-substituted 4-chloro-phenyl boronic acids. Depending on the nature of substituents in the pyridine, and in particular the phenyl group, a large number of derivatives are readily accessible. …”
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A Facile One-Pot Synthesis of New Poly Functionalized Pyrrolotriazoles via a Regioselective Multicomponent Cyclisation and Suzuki–Miyaura Coupling Reactions by Simon Garnier, Kévin Brugemann, Agnieszka Zak, Johnny Vercouillie, Marie Potier-Cartereau, Mathieu Marchivie, Sylvain Routier, Frédéric Buron

“…Palladium-catalyzed cross-coupling conditions were optimized and a representative library of various boronic acids was employed to establish the scope and limitations of the method.…”
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Part I: Catalytic asymmetric arylation of esters for profen synthesis. Part II: Fast Suzuki coupling of heteroaryl chlorides by Yang, Junfeng

“…Part two describes a new catalytic system for Suzuki-Miyaura coupling of heteroaryl chlorides and heteroayl boronic acids. Most of the major families of heteroaryl chlorides can reached full conversion within minutes to hours at room temperature. …”
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