Validation of a purity method for a Suzuki-Miyaura boronic ester by liquid chromatography with derivatization by John J. Salisbury, William Georgian, Michael Herr, Michele Buetti-Weekly

“…However, analyses of these boronic acid/ester products and their derivatives are rarely discussed. …”
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Structure guided development of potent reversibly binding penicillin binding protein inhibitors. by Woon, E, Zervosen, A, Sauvage, E, Simmons, K, Zivec, M, Inglis, SR, Fishwick, C, Gobec, S, Charlier, P, Luxen, A, Schofield, C

“…Following from the evaluation of different types of electrophiles, combined modeling and crystallographic analyses are used to generate potent boronic acid based inhibitors of a penicillin binding protein. …”

Spatially resolved Suzuki coupling reaction initiated and controlled using a catalytic AFM probe. by Davis, J, Coleman, K, Busuttil, K, Bagshaw, C

“…Herein we report a chemically specific Suzuki coupling reaction between a surface-confined aryl bromide and boronic acid reagents in solution achieved using a catalytic AFM probe.…”

Ameliorative Properties of Boronic Compounds in In Vitro and In Vivo Models of Alzheimer’s Disease by Panchanan Maiti, Jayeeta Manna, Zoe N. Burch, Denise B. Flaherty, Joseph D. Larkin, Gary L. Dunbar

“…Reports that certain boronic compounds can reduce amyloid accumulation and neuroinflammation prompted us to compare trans-2-phenyl-vinyl-boronic-acid-MIDA-ester (TPVA) and trans-beta-styryl-boronic-acid (TBSA) as treatments of deficits in in vitro and in vivo models of AD. …”
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Construction of supramolecular dimer based on benzothiazole derivative through host–guest interaction for photocatalysis by Xin‐Long Li, Yue‐Bo Wang, Ying Wang, Rong‐Zhen Zhang, Rui‐Zhi Dong, Hui Liu, Shengsheng Yu, Ning Han, Ling‐Bao Xing

“…The generated O2⋅− could be used to catalyze the oxidative hydroxylation of aryl boronic acid. Therefore, the 2MPBT‐CB[8] had become a highly efficient photocatalyst for the oxidative hydroxylation of aryl boronic acid. …”
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Selective electrochemical detection of hydrogen fluoride by ambiphilic ferrocene derivatives. by Bresner, C, Aldridge, S, Fallis, I, Jones, C, Ooi, L

“…(Graph Presented) Appropriate linking of Lewis acidic and Lewis basic components - in this case boronic acid and tertiary amine functionalities - allows the construction of a robust organometallic receptor capable of selectively binding hydrogen fluoride. …”

Traceless rhodium-catalyzed hydroacylation using alkyl aldehydes: the enantioselective synthesis of β-aryl ketones by Willis, M, Bouisseau, A, Gao, M

“…A one-pot three-step sequence involving Rh-catalyzed alkene hydroacylation, sulfide elimination and Rh-catalyzed aryl boronic acid conjugate addition, delivers products of traceless chelation-controlled hydroacylation employing alkyl aldehydes. …”

An asymmetric Suzuki-Miyaura approach to prostaglandins: Synthesis of Tafluprost by Kučera, R, Goetzke, FW, Fletcher, SP

“…Key steps include a diastereo- and enantioselective Rh-catalyzed Suzuki–Miyaura reaction of a racemic bicyclic allyl chloride and an alkenyl boronic acid and a regio- and diastereoselective Pd-catalyzed Tsuji–Trost reaction with an enolate surrogate. …”

Fluorescent probes for monitoring myeloperoxidase-derived hypochlorous acid: a comparative study by Karolina Pierzchała, Marlena Pięta, Monika Rola, Małgorzata Świerczyńska, Angelika Artelska, Karolina Dębowska, Radosław Podsiadły, Jakub Pięta, Jacek Zielonka, Adam Sikora, Andrzej Marcinek, Radosław Michalski

“…We have also determined the rate constants of the reaction between HOCl and the probes and they are equal to 1.8 × 104 M−1s−1 for coumarin boronic acid (CBA), 1.1 × 104 M−1s−1 for fluorescein based boronic acid (FLBA), 3.1 × 104 M−1s−1 for 7-(p-aminophenyl)-coumarin (APC), 1.6 × 104 M−1s−1 for 3’-(p-aminophenyl)-fluorescein (APF), and 1 × 107 M−1s−1 for 4-thiomorpholino-7-nitrobenz-2-oxa-1,3-diazole (NBD-TM). …”
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Detection of OXA-181-producing Pseudomonas aeruginosa in Germany by Jennifer Schauer, Sören G. Gatermann, Jessica Eisfeld, Jörg Hans, Niels Pfennigwerth

“…Methods: Carbapenemase detection was performed by using several phenotypic tests such as the modified Hodge test, a combined disc test with boronic acid, EDTA or cloxacillin, a lysate-based inhibition assays and by PCR for common and rare carbapenemase genes. …”
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Quaternary Ammonium-Tethered Phenylboronic Acids Appended Supramolecular Nanomicelles as a Promising Bacteria Targeting Carrier for Nitric Oxide Delivery by Yu Fang, Haiyan Cui, Xiaoqin Liang, Jianping Yu, Jianrong Wang, Guanghui Zhao

“…The strong specific interaction of the boronic acid moiety with the surface of <i>E. coli</i> and the electrostatic interaction of the quaternary amine salt with the cell membrane were confirmed by antibacterial experiments on molecules with and without the targeting moiety. …”
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Catalytic and Biological Applications of Benzoxaborolones by Graham, Brian James

“…Though first isolated 150 years ago, boronic acids have historically been neglected species. …”
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Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions by Gan, Kennard Jun Hao

“…Following which, the second part of the thesis comprises the successful application of cyclometalated Palladium(II)-complexes as catalysts toward aryl boronic acid addition onto a variety of unsaturated enones.…”
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Heterocycle-derived β-S-enals as bifunctional linchpins for the catalytic synthesis of saturated heterocycles by Niu, J, Willis, M

“…Substrates based on N-, O- and S-heterocycles are included, as are a range of alkenes, alkynes and boronic acid derivatives.…”

Phenotypic Detection of ESBL, AmpC, MBL, and Their Co-occurrence among MDR Enterobacteriaceae Isolates by Thounaojam Salvia, Karma G. Dolma, Om Prakash Dhakal, Bidita Khandelwal, Laishram Shantikumar Singh

“…AmpC was detected in 11.8% and 13.1% using a commercial E-test and boronic acid test, respectively. MBL were identified in 12.8% and 14.8% based on MBL imipenem-EDTA and carba-NP tests, respectively. …”
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HIV-1 protease as a target for antiretroviral therapy by Windsor, Ian William.

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2-{9-(10-Bromoanthracenyl)}-1,3-dihydro-1<i>H</i>-[<i>d</i>]-1,3,2-benzodiazaborole by Siphamandla Sithebe

“…In this paper, a synthesis and characterization of a novel three coordinate 2-{9-(10-Bromoanthracenyl)}-1,3-dihydro-1<i>H</i>-[<i>d</i>]-1,3,2-benzodiazaborole from a cyclo-condensation reaction of <i>o</i>-phenylenediamine and 10-bromoanthracene-9-boronic acid is described. The desired product was obtained in 0.343 g (92% yields) with its structure characterized by ¹H, ¹¹B, ¹³C NMR, HRMS and FT-IR.…”
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Multicomponent Synthesis of Luminescent Iminoboronates by Samuel Guieu, Cátia I. C. Esteves, João Rocha, Artur M. S. Silva

“…A family of iminoboronates was prepared through a one-pot multicomponent reaction, starting from boronic acid, anthranilic acid, and different salicylaldehydes. …”
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Design of a “turn-Off/turn-On” biosensor : understanding carbohydrate-lectin interactions for use in noncovalent drug delivery by Gorityala, Bala Kishan, Lu, Zhiqiang, Leow, Min Li, Ma, Jimei, Liu, Xue-Wei

“…This combination of glyco-gold nanoparticles and boronic acid biosensor system opens a way to study noncovalent drug delivery.…”
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Super-resolution imaging for in situ monitoring sub-cellular micro-dynamics of small molecule drug by Huimin Chen, Guiqian Fang, Youxiao Ren, Weiwei Zou, Kang Ying, Zhiwei Yang, Qixin Chen

“…As a proof of concept, we have meticulously designed and constructed a boronic acid fluorescence drug beacon using coumarin–hemicyanine (CHB). …”
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