Triaryl carbenium ion pair mediated electrocatalytic benzylic C-H oxygenation in air by Zhang, Zhenguo, Lv, Yongheng, Ji, Liang, Chen, Peng, Han, Shuyan, Zhu, Yufei, Li, Lanyang, Jia, Zhenhua, Loh, Teck-Peng

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Addition of allylstannanes to an oxy-stabilized carbenium ion on a 1.7-dioxaspirol[5.5]undecane ring system / by 403452 Brimble, Margaret A, Fares, Fares A, Turner, Peter

Three-Component Reactions of 3-Arylidene-3<i>H</i>-Indolium Salts, Isocyanides and Amines by Hung M. Nguyen, Nikita E. Golantsov, Alexandra S. Golubenkova, Victor B. Rybakov, Leonid G. Voskressensky

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Deamination of 1-Aminoalkylphosphonic Acids: Reaction Intermediates and Selectivity by Anna Brol, Tomasz K. Olszewski

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Application of ammonia probe-assisted solid-state NMR technique in zeolites and catalysis by Chang Wang, Weili Dai, Guangjun Wu, Naijia Guan, Landong Li

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7-((5-Bromo-1H-indol-3-yl)(4-methoxyphenyl)methyl)-1,3,5-triaza-7-phosphaadamantan-7-ium Tetrafluoroborate by Siva Sankar Murthy Bandaru, Carola Schulzke

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CALCULATION OF THERMODYNAMIC AND KINETIC PARAMETERS OF CATALYTIC CRACKING REACTIONS ON LEWIS AND BRØNSTED ACID SITES by Galina Y. Nazarova, Elena N. Ivashkina, Vladislav V. Maltsev

“…Further study shows that the activation energy of carbenium ion formation from izohexane and C8–C10 alkanes with normal structure on the Lewis acid site was 257,6 and 279,2…277,9 kJ/mol. …”
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Synthesis of the ABC fragment of pectenotoxin-4 by Lipinski, RM

“…After successfully developing a model system for the synthesis of the AB anomeric 6,5 spiroketal, which involved the employment of a hydride shift initiated oxo carbenium ion formation followed by intramolecular spiroketalisation, the developed system was then applied to the fully elaborated synthesis of the ABC fragment.…”

Trading N and O. Part 3: Synthesis of 1,2,3,4-tetrahydroisoquinolines from alpha-hydroxy-beta-amino esters by Davies, S, Fletcher, A, Frost, AB, Kennedy, MS, Roberts, P, Thomson, J

“…Activation of the α-hydroxy group upon treatment with Tf2O and 2,6-di-tert-butyl-4-methylpyridine promotes aziridinium formation, which is then followed by rupture of the C(3)-N bond and Friedel-Crafts alkylation-type cyclisation of an N-benzyl moiety onto the resultant benzylic carbenium ion. The nature of the N-protecting group was varied and it was found that superior yields were obtained for reactions employing two benzylic groups. …”

Total synthesis of rubriflordilactone A by Goh, S

“…Construction of the F ring, followed by attachment of the G ring by an intriguing oxo-carbenium ion addition reaction completed two enantioselective total syntheses of (+)-rubriflordilactone A.…”

Conversion of low density polyethylene (LDPE) over ZSM-5 zeolite to liquid fuel by Wong, S. L., Ngadi, N., Abdullah, T. A. T., Inuwa, I. M.

“…Hence, it is concluded that the catalytic cracking of LDPE is dominated by free radical mechanism, while the influence of carbenium ion is less pronounced due to low acidity of the catalyst. …”

A Molecular Modeling Study into Brønsted and Lewis Acid Catalyzed Conversion of CBD into Other Cannabinoids by Wim Buijs

“…BF₃·Et₂O catalysis leads to the formation of tertiary carbenium ions in the transition states, which yield Δ⁹-THC and some iso THC. …”
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Site Diversity and Mechanism of Metal‐Exchanged Zeolite Catalyzed Non‐Oxidative Propane Dehydrogenation by Yong Yuan, Zhaoqi Zhao, Raul F. Lobo, Bingjun Xu

“…The reaction mechanism could be both intricately related to and nearly independent of the details of the assumed active structure, as in the two main proposed PDH mechanisms on Ga/H‐ZSM‐5, that is, the carbenium mechanism and the alkyl mechanism. Perspectives on potential approaches to further elucidate the active structure of metal‐exchanged zeolite catalysts and reaction mechanisms are discussed in the final section.…”
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Exploration of reaction mechanisms on the plastic waste polyethylene terephthalate (PET) dissolved in phenol steam reforming reaction to produce hydrogen and valuable liquid fuels by Nabgan, Walid, Nabgan, Bahador, Tuan Abdullah, Tuan Amran, Ngadi, Norzita, Abdul Jalil, Aishah, Abdul Fatah, Nor Aiza, Alqaraghuli, Hasan, Tahir, Muhammad

“…It was found that during the catalytic reforming of PET, several types of reactions such as dehydrogenation reaction, thermal cracking, steam reforming, water gas shift reaction, carbenium ion reaction, free radical reaction, dihydroxylation reaction, and coke formation occurred.…”

Increased Light Olefin Production by Sequential Dehydrogenation and Cracking Reactions by Xiaoqiao Zhang, Jianhong Gong, Xiaoli Wei, Lingtao Liu

“…This could accelerate the formation of carbenium ions, thus promoting the conversion of n-octane to produce light olefins. …”
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Cracking of low density polyethylene dissolved in benzene to liquid fuels using zeolite-based catalysts by Wong, Syie Luing

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Cracking of low density polyethylene dissolved in benzene to liquid fuels using zeolite-based catalysts by Wong, Syie Luing

“…It is suggested that the catalytic cracking of LDPE is dominated by free radical mechanism, while the influence of carbenium ion mechanism is less pronounced due to low acidity of the catalyst. …”
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Hydrogen production from the steam reforming of phenol-pet solution using nickle-palladium based catalyst by Nabgan, Bahador

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Hydrogen production from the steam reforming of phenol-pet solution using nickle-palladium supported catalyst by Nabgan, Bahador

“…Based on the product formation in the proposed reaction mechanism, free radical and carbenium ion mechanisms are of high chance to occur. …”
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