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Synthesis, Crystal Structures and Luminescence Properties of Three New Cadmium 3D Coordination Polymers
Published 2020-05-01“…Under solvothermal reaction conditions, cadmium ion with BPPT in the presence of various carboxylic acids including (1,1′-biphenyl)-4,4′-dicarboxylic acid (BPDC), isophthalic acid (IP), and benzene-1,3,5-tricarboxylic acid (BTC) gave rise to three coordination complexes, viz, [Cd(BPPT)(BPDA)](BPPT)n (<b>1</b>), [Cd(BPPT) (IP)] (CH<sub>3</sub>OH) (<b>2</b>), and [Cd<sub>3</sub>(BPPT)<sub>3</sub>(BTC)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>] (<b>3</b>). …”
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322
Zinc(II) Iminopyridine Complexes as Antibacterial Agents: A Structure-to-Activity Study
Published 2024-04-01“…Metallodrugs, especially metal coordination complexes, comprise a broad variety of candidates to combat antibacterial infections. …”
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Rational Design of a Gd(III)–Cu(II) Nanobooster for Chemodynamic Therapy Against Cancer Cells
Published 2022-04-01“…Copper (II) containing coordination complexes have attracted much attention for chemodynamic therapy (CDT) against cancer cells. …”
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324
Broadband EPR Spectroscopy of the Triplet State: Multi-Frequency Analysis of Copper Acetate Monohydrate
Published 2023-09-01“…A case in point is the triplet system S = 1 of coordination complexes with two unpaired electrons when the electronic Zeeman interaction and the electronic zero-field interaction are similar in strength. …”
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325
Easily Tunable Membrane Thickness of Microcapsules by Using a Coordination Assembly on the Liquid-Liquid Interface
Published 2018-09-01“…A model solvent, 1,3,5-trimethylbenzene, was encapsulated using coordination assembly between metal ions and tannic acid to reveal the deposition of coordination complexes on the liquid-liquid interface. The deposition was confirmed by zeta potential, energy dispersive spectroscopy and X-ray photoelectron spectroscopy. …”
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326
Highly robust supramolecular polymer networks crosslinked by a tiny amount of metallacycles
Published 2024-04-01“…These remarkable performances are attributed to the thermodynamically stable, but dynamic metallacycle-based supramolecular coordination complexes that offer strong linkages with good adaptive characteristics.…”
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327
From Discrete Complexes to Metal–Organic Layered Materials: Remarkable Hydrogen Bonding Frameworks
Published 2020-03-01“…A series of metal−organic coordination complexes based on alkaline-earth metal centers [Mg(II), Ca(II), and Ba(II)] and the ligand 5-aminoisophthalate (aip<sup>2−</sup>) revealed notable structural diversity, both in the materials’ dimensionality and in their hydrogen bonding networks: [Mg(H<sub>2</sub>O)<sub>6</sub>]∙[Mg<sub>2</sub>(Haip)(H<sub>2</sub>O)<sub>10</sub>]∙(Haip)∙3(aip)∙10(H<sub>2</sub>O) (<b>1</b>) and [Mg(aip)(phen)(H<sub>2</sub>O)<sub>2</sub>]∙(H<sub>2</sub>O) (<b>2</b>) were isolated as discrete complexes (0D); [Ca(aip)(H<sub>2</sub>O)<sub>2</sub>]∙(H<sub>2</sub>O) (<b>3</b>), [Ca(aip)(phen)(H<sub>2</sub>O)<sub>2</sub>]∙(phen)∙(H<sub>2</sub>O) (<b>4</b>), and [Ba<sub>2</sub>(aip)<sub>2</sub>(phen)<sub>2</sub>(H<sub>2</sub>O)<sub>7</sub>]∙2(phen)∙2(H<sub>2</sub>O) (<b>5</b>) revealed metal−organic chain (1D) structures, while the [Ba(aip)(H<sub>2</sub>O)] (<b>6</b>) showed a metal−organic layered (2D) arrangement. …”
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328
Harnessing inorganic coordination chemistry for novel sensing applications
Published 2016Get full text
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329
Synthesis and Structural Investigation of New Bio-Relevant Complexes of Lanthanides with 5-Hydroxyflavone: DNA Binding and Protein Interaction Studies
Published 2016-12-01“…In the present work, we attempted to develop new metal coordination complexes of the natural flavonoid 5-hydroxyflavone with Sm(III), Eu(III), Gd(III), Tb(III). …”
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330
Outlook on the Application of Metal-Liganded Bioactives for Stimuli-Responsive Release
Published 2017-11-01“…Direct metal-liganded bioactive coordination complexes are known to be sensitive to stimuli such as pH, light, ion activation, or redox cues. …”
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Mechanism of the oxidation of 1-(ferrocenyl)-ethanone/ethanol by dicyanobis(phenanthroline)iron(III)
Published 2019-12-01“…Keywords: Iron coordination complexes, Dicyanobis(phenanthroline)iron(III), 1-Ferrocenylethanone, 1-Ferrocenylethanol, 1,4-Dioxane, Visible absorption spectrophotometry…”
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335
A Promising Copper(II) Complex as Antifungal and Antibiofilm Drug against Yeast Infection
Published 2018-07-01“…In this context, coordination complexes of metal ions and ligands appear to be important. …”
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336
Synthesis, Characterization, and In Vivo Anti-Cancer Activity of New Metal Complexes Derived from Isatin-<i>N</i>(4)antipyrinethiosemicarbazone Ligand Against Ehrlich Ascites Carci...
Published 2019-09-01“…The current study aimed to synthesize new metal coordination complexes with potential biomedical applications. …”
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337
Development of Copper Complexes with Diimines and Dipicolinate as Anticancer Cytotoxic Agents
Published 2023-04-01“…Coordination complexes may act as anticancer agents. Among others, the formation of the complex may facilitate the ligand uptake by the cell. …”
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338
ON donor tethered copper (II) and vanadium (V) complexes as efficacious anti-TB and anti-fungal agents with spectroscopic approached HSA interactions
Published 2022-08-01“…Antimicrobial drug resistance poses a significant threat worldwide, hence triggering an urgent situation for developing feasible drugs. 3D-transition metal coordination complexes being multifaceted, offer tremendous potency as drug candidates. …”
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339
Catalyst-Inspired Charge Carriers for High Energy Density Redox Flow Batteries
Published 2019-01-01“…Specifically, we have proposed two Fe-coordination complexes (I, Fe(Me2Pytacn)(C2N3H2), and II, Fe(H2pmen)(C2N3H2)) combining two different types of ligands, i.e., catalyst-inspired scaffolds and triazole ring, which were previously shown to promote high and low oxidation states in transition metals, respectively. …”
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