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2101
Optimization of an experimental study of cationic Pb metal adsorption by resin polymer
Published 2023-11-01“…These values indicated that the adsorption process was endothermic and spontaneous, further emphasizing its impetuous nature. …”
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2102
Ammonia removal from aqueous solution using modified oil palm empty fruit bunches based adsorbent
Published 2017“…Thermodynamic parameter ( , and ) studies showed that the biosorption ammonia nitrogen onto modified EFB was predicted to be spontaneous and endothermic in nature. These modified fresh EFB were applied into urban drainage at Kampung Sembulan Lama, Kota Kinabalu for 7 days and the recovery of ammonia nitrogen recovered by Cymbopogon citrus plant growth. …”
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Thesis -
2103
Removal of Basic and Reactive Dyes by Sorption Using Ethylenediamine-Modified Rice Hull
Published 2006“…The sorption of BB3 and RO16 from single and binary dye solution was found to be endothermic and exothermic, respectively. The kinetics of dye sorption fitted a pseudo-second order rate expression. …”
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Thesis -
2104
Enzymatic directed interesterification of palm oil for production of highly unsaturated palm fraction
Published 2017“…Differential Scanning Calorimetry melting profile showed that the EDIE PO had two well-separated high-melting and low-melting endothermic peaks, indicating ease of fractionation. …”
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Thesis -
2105
Adsorption of lead from aqueous solution using modified activated carbon prepared from palm kernel shell
Published 2018“…The adsorption process was endothermic and spontaneous in nature and the data fitted the pseudo-second order kinetics and Langmuir isotherm model. …”
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Thesis -
2106
Adsorption of Pb(II), Cu(II) and Cd(II) from aqueous solution by natural and chemically modified pineapple plant stem
Published 2019“…The increase of temperature lowered the adsorption capacities of NPPS and OAPPS for Cu(II) and Cd(II) ions but enhanced the Pb(II) adsorption, suggested that Pb(II) adsorption is endothermic while Cu(II) and Cd(II) adsorption are exothermic reactions in nature. …”
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Thesis -
2107
Extraction of lipids and eicosapentaenoic acid from Nannochloropsis oceanica biomass using ionic liquid-based microwave-assisted extraction method
Published 2020“…The values of thermodynamic parameters such as Gibbs free energy change (ΔG), enthalpy change (ΔH) of +403.0557 (kJ/mol.K), and entropy change (ΔS) of + 0.1485 (kJ/mol.K) indicate that this process is endothermic, irreversible, and spontaneous, respectively. …”
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Thesis -
2108
Synthesis And Interaction Mechanism Of Zwitterionic Adsorbent Coating For Cationic And Anionic Dyes Removal
Published 2019“…Thermodynamic studies also revealed that adsorption was spontaneous and endothermic process. The current study discovered the potential of ZwitAd as a feasible and practical coating adsorbent for future wastewater treatment technology.…”
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Thesis -
2109
Horse manure derived biofuel production via microwave induced pyrolysis
Published 2020“…Such a decomposition process was found to be endothermic and endergonic in nature, giving an activation energy of approximately 148.5-300.1 kJ/mol. …”
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Thesis -
2110
Microbial community profiling of arsenic-rich mine tailing and arsenic bioadsorption by indigenous bacteria
Published 2020“…S° revealed that the adsorptions of both As (III) and As (V) were spontaneous, feasible and endothermic in nature. FESEM-EDX analysis established diverse cell morphological changes with significant amounts of arsenic adsorbed onto biomass compared to original biomass. …”
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Thesis -
2111
One-step synthesis and adsorptive characteristics of composite magnetic activated carbon for rhodamine B removal
Published 2019“…The positive values of enthalpy change and entropy change indicate that the adsorption process is endothermic and spontaneous at high temperature. The activation energy of 24.1 - 28.9 kJ/mol suggested that the adsorption of RB onto ZMAC-2.5 is a physisorption process. …”
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Thesis -
2112
Age-Related Properties of Aquaponics-Derived Tilapia Skin (<i>Oreochromis niloticus</i>): A Structural and Compositional Study
Published 2023-01-01“…Thermal analysis registered a shift of the endothermic peak (+1.7 °C) and an increase in the enthalpy (+3.3 J/g), while mechanical properties were found to be anisotropic, with an age-dependent brittle behavior. …”
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2113
A Magnetic Reduced Graphene Oxide Nanocomposite: Synthesis, Characterization, and Application for High-Efficiency Detoxification of Aflatoxin B<sub>1</sub>
Published 2024-01-01“…Moreover, the results of isotherm, kinetic, and thermodynamic analyses indicated that the adsorption of AFB<sub>1</sub> by Fe<sub>3</sub>O<sub>4</sub>@rGO conformed to the Langmuir model, with a maximum adsorption capacity of 82.64 mg·g<sup>−1</sup>; the rapid and efficient adsorption of AFB<sub>1</sub> occurred mainly through chemical adsorption via a spontaneous endothermic process. When applied to treat vegetable oil and peanut milk, the prepared material minimized the loss of nutrients and thus preserved food quality. (4) Conclusions: The above findings reveal a promising adsorbent, Fe<sub>3</sub>O<sub>4</sub>@rGO, with favorable properties for AFB<sub>1</sub> adsorption and potential for food safety applications.…”
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2114
Study of the Effectiveness of Alumina and HDTMA/Alumina Composite in the Removal of Para-Nitrophenol and the Deactivation of Bacterial Effect of <i>Listeria monocytogenes</i> and <...
Published 2022-10-01“…Physical adsorption of p-NP onto the adsorbents proved to be an endothermic and spontaneous process at high temperatures, which mainly involves a hydrogen bonding mechanism of interactions between p-NP and functional groups of adsorbents. …”
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2115
Structural, Spectroscopic, and Thermal Decomposition Features of [Carbonatotetraamminecobalt(III)] Iodide—Insight into the Simultaneous Solid-Phase Quasi-Intramolecular Redox React...
Published 2023-02-01“…The C-N bond containing intermediates reduced Co<sub>3</sub>O<sub>4</sub> into CoO and Co, whereas in oxygen-containing atmosphere, the end-product was Co<sub>3</sub>O<sub>4</sub>, even at 200 °C, and the endothermic ligand loss reaction coincided with the consecutive exothermic oxidation processes.…”
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2116
Diversity of Solid Forms Promoted by Ball Milling: Characterization and Intrinsic Dissolution Studies of Pioglitazone Hydrochloride and Fluvastatin Sodium Drug–Drug Systems
Published 2023-05-01“…By differential scanning calorimetry (DSC), the presence of two endothermic events was observed in this screening: incongruous melting point (solidus) and excess of one of the components (liquidus), except in the 1:1 solid form. …”
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2117
Process Optimization and Equilibrium, Thermodynamic, and Kinetic Modeling of Toxic Congo Red Dye Adsorption from Aqueous Solutions Using a Copper Ferrite Nanocomposite Adsorbent
Published 2024-01-01“…Considering the obtained negative ΔG and positive ΔH<sub>ads</sub> and ΔS<sub>ads</sub> values across all tested temperatures in the thermodynamic investigations, it was confirmed that the adsorption process was characterized as endothermic, spontaneous, and feasible, with an increased level of randomness. …”
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2118
The cultivation of immobilized chlorella vulgaris in different culture medium for biodiesel production
Published 2021“…Both enthalpy (ΔH) and entropy (ΔS) indicate positive value whereas the negative value of Gibbs energy (ΔG) indicates that this process is endothermic, irreversible and spontaneous. The research findings show that the BBM was more effective in culturing process and the applicability of the matric systems of SA+GT made a new structure that improve the oil production than using single matric. …”
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Thesis -
2119
Thermochemical Performance Analysis of the Steam Reforming of Methane in a Fixed Bed Membrane Reformer: A Modelling and Simulation Study
Published 2020-12-01“…When the H<sub>2</sub>O/CH<sub>4</sub> ratio decreases in PBMR, the Endothermic Reaction Temperature (ERT) is notably increased (998.32 K) at the outlet of the PBMR’s reaction zone. …”
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2120
Polymer-Based Nano-Adsorbent for the Removal of Lead Ions: Kinetics Studies and Optimization by Response Surface Methodology
Published 2022-11-01“…Studying the thermodynamic showed that the adsorption was endothermic as illustrated from the positive value of value of ΔH° is 1.439 kJ/mol which indicates that the uptake of Pb<sup>2+</sup> onto nanoadsorbent PPy-PEI could be attributed to a physical adsorption process. …”
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