-
1601
The mitochondrial genome of the mountain wooly tapir, Tapirus pinchaque and a formal test of the effect of altitude on the adaptive evolution of mitochondrial protein coding genes...
Published 2023-09-01“…Abstract Background The harsh conditions of high-altitude environments are known to drive the evolution of physiological and morphological traits in endothermic animals. These conditions are expected to result in the adaptive evolution of protein coding genes encoded in mitochondrial genomes that are vital for the oxidative phosphorylation pathway. …”
Get full text
Article -
1602
β-CD-Induced Precipitation of Eriochrome Black T Recovered via CTAB-Assisted Foam Fractionation for Adsorption of Trace Cu(II)
Published 2023-06-01“…Thermodynamic analysis showed that the mechanism of Cu<sup>2+</sup> removal via β-CD-CTAB-EBT was spontaneous and endothermic physisorption. Under the optimized conditions, we achieved a removal ratio of 95.3 ± 3.0% for Cu<sup>2+</sup> ions, and the adsorption capacity remained at 78.3% after four reuse cycles. …”
Get full text
Article -
1603
Preparation and Characterization of a Hybrid Complex of Cyclodextrin-Based Metal—Organic Frameworks-1 and Ascorbic Acid Derivatives
Published 2021-11-01“…Differential scanning calorimetry results revealed that the endothermic peaks of evaporated samples (ASCP/CD-MOF-1 = 1/2 and ASCDP/CD-MOF-1 = 1/4) were not detected due to melting. …”
Get full text
Article -
1604
Improved Adsorption of the Toxic Herbicide Diuron Using Activated Carbon Obtained from Residual Cassava Biomass (<i>Manihot esculenta</i>)
Published 2022-11-01“…The thermodynamic parameters showed that the adsorption was spontaneous, favorable, and endothermic. The enthalpy of adsorption magnitude was consistent with physical adsorption. …”
Get full text
Article -
1605
Ecofriendly Application of <i>Calabrese</i> Broccoli Stalk Waste as a Biosorbent for the Removal of Pb(II) Ions from Aqueous Media
Published 2024-03-01“…The thermodynamic parameters evaluated showed the endothermic and spontaneous nature of the Pb(II) biosorption. …”
Get full text
Article -
1606
Application of Response Surface Design for Optimization of Direct Red Dye Biosorption onto Cockleshells
Published 2023-11-01“…The adsorption process was endothermic and fit the pseudo-second-order model. The negative values of ∆H and ∆S in the thermodynamic research showed that the bio-adsorption technique for the removal of Direct Red 81 is exothermic, spontaneous, and feasible. …”
Get full text
Article -
1607
Preparation, Characterization, Solubility, and Antioxidant Capacity of Ellagic Acid-Urea Complex
Published 2022-04-01“…DSC analysis revealed that the UR peak at 134 °C disappeared, and a new endothermic peak was observed at approximately 250 °C for EVP (EA/UR = 1/1). …”
Get full text
Article -
1608
Adsorption of cobalt (II) ions from aqueous solution using cow bone and its derivatives: Kinetics, equilibrium and thermodynamic comparative studies
Published 2023-12-01“…The study of the thermodynamic properties of the adsorption of Co2+ showed the process was endothermic, non-spontaneous and endogenic for the ACBC adsorbent, while being exothermic for the CB, and CBC adsorbents in addition to having physisorption properties.…”
Get full text
Article -
1609
Kinetic study of thermal decomposition of sugarcane bagasse pseudo-components at typical pretreatment conditions: Simulations of opportunities towards the establishment of a feasib...
Published 2022-12-01“…An essential advance of this work is related to the quantitative interpretation of the degradation process (an endothermic and non-spontaneous process) via a multi-stage model governed by diffusion-controlled reactions and order-based models, which helps explain the differences observed in the mass balance of biorefining processes. …”
Get full text
Article -
1610
A Novel Chitosan/Nano-Hydroxyapatite Composite for the Adsorptive Removal of Cd(II) from Aqueous Solution
Published 2023-03-01“…Furthermore, the thermodynamic study suggested that Cd(II) adsorption onto CS/n-Hap was endothermic and spontaneous. The regeneration study showed only about a 3% loss in Cd(II) uptake by CS/n-Hap after five consecutive cycles. …”
Get full text
Article -
1611
The Using of Nanoparticles of Microalgae in Remediation of Toxic Dye from Industrial Wastewater: Kinetic and Isotherm Studies
Published 2022-05-01“…The highest adsorption capacity was found by the Langmuir model to be 58.8 mg g<sup>−1</sup>. It is an endothermic process with spontaneity increasing with temperature. …”
Get full text
Article -
1612
Adsorptive Removal of 2,6-Dichlorophenol from Aqueous Solution by Surfactant-Modified Palygorskite Sorbents: Equilibrium, Kinetics and Thermodynamics
Published 2011-02-01“…Thermodynamic studies showed that the adsorption of 2,6-DCP onto the three sorbents examined occurred spontaneously and that the process was endothermic in nature. The results indicate that the surfactant-modified palygorskite exhibited a significant potential as a sorbent material for the removal of phenolic compounds from aqueous solution.…”
Get full text
Article -
1613
Radionuclide Removal from Aqueous Solutions Using Oxidized Carbon Fabrics
Published 2023-12-01“…The data obtained from the experiments regarding the temperature effect implied that the relative adsorption for both actinides increases with temperature and that adsorption is an endothermic and entropy-driven reaction. The application of the fabrics to remove the two actinides from contaminated seawater samples showed that both the relative removal efficiency and the K<sub>d</sub> values decreased significantly due to the presence of competitive cations (e.g., Ca<sup>2+</sup> and Fe<sup>3+</sup>) and complexing anions (CO<sub>3</sub><sup>2−</sup>) in the respective waters. …”
Get full text
Article -
1614
Adsorption of Pb<sup>2+</sup> by Activated Carbon Produced by Microwave-Assisted K<sub>2</sub>CO<sub>3</sub> Activation of Date Palm Leaf Sheath Fibres
Published 2023-11-01“…The Langmuir ΔG° and E<sub>a</sub> were 6.39 kJ/mol, 0.12 kJ/mol K, −31.28 kJ/mol and 15.90 kJ/mol, respectively, which demonstrated that the adsorption of Pb<sup>2+</sup> by the LSDPFAC was endothermic, spontaneous and governed by physisorption.…”
Get full text
Article -
1615
Halogen-Free Flame Retardant Polypropylene Fibers with Modified Intumescent Flame Retardant: Preparation, Characterization, Properties and Mode of Action
Published 2021-07-01“…In addition, the IFR decomposed endothermically to release of non-combustible gases such as NH<sub>3</sub> and CO<sub>2</sub> which dilutes the combustible gases in the combustion zone.…”
Get full text
Article -
1616
Transformation of Residual Açai Fruit (<i>Euterpe oleracea</i>) Seeds into Porous Adsorbent for Efficient Removal of 2,4-Dichlorophenoxyacetic Acid Herbicide from Waters
Published 2022-11-01“…The thermodynamic behavior indicated a spontaneous, favorable, and endothermic behavior. The magnitude of the enthalpy of adsorption was in agreement with the physical adsorption. …”
Get full text
Article -
1617
Use of Chitosan from Southern King Crab to Develop Films Functionalized with RGD Peptides for Potential Tissue Engineering Applications
Published 2023-07-01“…Thermal properties of films showed similar endothermic peaks at 53.4 and 53.0 °C in commercial CS and SKC-CS, respectively. …”
Get full text
Article -
1618
Magnetized inulin by Fe3O4 as a bio-nano adsorbent for treating water contaminated with methyl orange and crystal violet dyes
Published 2022-12-01“…The thermodynamic parameters exhibited that the dye adsorption process is endothermic and spontaneous, which supported the enhanced adsorption rate by increasing temperature. …”
Get full text
Article -
1619
Isothermal, Kinetic, and Thermodynamic Studies on the Adsorption of Molybdenum by a Nanostructured Magnetic Material
Published 2020-12-01“…Based on the negative standard Gibbs free energy change (ΔG° < 0) and the positive standard enthalpy change (ΔH° > 0), it was found that the adsorption was an endothermic and a spontaneous process in nature.…”
Get full text
Article -
1620
Phase-Transition Thermal Charging of a Channel-Shape Thermal Energy Storage Unit: Taguchi Optimization Approach and Copper Foam Inserts
Published 2021-02-01“…The principle of energy storage is to drive an endothermic phase change when excess energy is available and to allow the phase change to reverse and release heat when energy demand exceeds supply. …”
Get full text
Article