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1721
Recovering the Soybean Hulls after Peroxidase Extraction and Their Application as Adsorbent for Metal Ions and Dyes
Published 2023-01-01“…Calculated thermodynamic parameters suggested that the adsorption of all pollutants is spontaneous and of endothermic character. Moreover, different binary mixtures were prepared, and the competitive adsorptions revealed that the soybean hulls are the most efficient adsorbent for the mixture of AB 225 and Cu2+. …”
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1722
LTA and FAU-X Iron-Enriched Zeolites: Use for Phosphate Removal from Aqueous Medium
Published 2022-08-01“…The phosphate adsorption using LTA-Fe and FAU-X-Fe does not require pH adjustment, and it is endothermic. The reusability of both iron zeolites is limited, and they can be finally disposed for soil amendment applications.…”
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1723
Absorption of Cu(II) and Zn(II) from Aqueous Solutions onto Biochars Derived from Apple Tree Branches
Published 2020-07-01“…The values of ΔG<sup>0</sup> for the absorption of Cu(II) and Zn(II) on all BCs were negative, while the values of ΔH<sup>0</sup> were positive, suggesting that the absorption was a spontaneous endothermic process. The mechanisms of BC adsorption of metal ions adsorption include surface precipitation, ion exchange, and minor contribution by cation-π interaction. …”
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1724
Synthesis and evaluation of a new CeO2@starch nanocomposite particles for efficient removal of toxic Cr(VI) ions
Published 2023-12-01“…Interestingly, the adsorption capacity increased with higher temperatures, suggesting an endothermic adsorption process. To gain further insights into the nature of the adsorption, we performed thermodynamic analysis, revealing that the adsorption of hexavalent Cr onto the CeO2@starch nanocomposite was spontaneous and had a chemical nature.…”
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1725
Zeolite NaP1 Functionalization for the Sorption of Metal Complexes with Biodegradable <i>N</i>-(1,2-dicarboxyethyl)-D,L-aspartic Acid
Published 2021-05-01“…The thermodynamic parameters indicate that adsorption is spontaneous and endothermic. The highest desorption percentage was achieved using the HCl solution, therefore, proving that method can be used to design slow-release fertilizers.…”
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1726
Preparation and characterization of polyethyleneimine functionalized magnetic graphene oxide as high uptake and fast removal for Hg (II)
Published 2022-09-01“…The adsorption removal was a fast and endothermic process governed by the chemical process. …”
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1727
Performance and Mechanism of Functionalized Water Hyacinth Biochar for Adsorption and Removal of Benzotriazole and Lead in Water
Published 2023-05-01“…The adsorption process of WL on BTA and Pb<sup>2+</sup> is spontaneous and is endothermic monolayer chemisorption. In addition, the adsorption of WL on BTA and Pb<sup>2+</sup> involves many mechanisms, but the main adsorption mechanisms are different. …”
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1728
Adsorption of Ni2+ Ions onto NaX and NaY Zeolites: Equilibrium, Kinetics, Intra Crystalline Diffusion, and Thermodynamic Studies
Published 2019-12-01“…The process has proved it's spontaneous and endothermic. Diffusion mechanisms of Ni (II)ions adsorption onto NaX and NaY has shown that intraparticle diffusion is the limiting step of the process. …”
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1729
Development of Self-Assembled Nanoribbon Bound Peptide-Polyaniline Composite Scaffolds and Their Interactions with Neural Cortical Cells
Published 2018-01-01“…Thermal phase changes studied indicated broad endothermic peaks upon incorporation of the proteins which were diminished upon binding with PANI. …”
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1730
Solubility of mesalazine in pseudo-binary mixtures of choline chloride/ethylene glycol deep eutectic solvent and water at 293.15 K to 313.15 K
Published 2023-11-01“…This analysis presented an endothermic and entropy-driven process of 5-ASA dissolution in ChCl/EG DES + water. …”
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1731
Evolution of pore structure and changes in oxidation characteristics of coal after heating freezing treatment
Published 2024-04-01“…Oxidized coal shows stronger oxidation and heat release ability in the stageⅡ under the action of LN2, resulting in higher apparent activation energy in this endothermic stage. The addition of LN2 blocked the oxidation reaction of preheated coal and sealed the structure of -C = O, –COOH and –OH. …”
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1732
Amorphous Elastomeric Ultra-High Molar Mass Polypropylene in High Yield by Half-Titanocene Catalysts
Published 2024-02-01“…Differential scanning calorimetry (DSC) established that the polymers are fully amorphous aPP, and no melting endotherm events are detected. Glass transition temperatures were detected between −2 and 2 °C. …”
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1733
Biochar from Rice Husk as Efficient Biosorbent for Procion Red Removal from Aqueous Systems
Published 2021-07-01“…Thermodynamic analysis showed positive enthalpy and entropy, indicating that Procion Red adsorption is endothermic; thus, the Gibbs energy values decreased with increase in temperature, indicating that high temperatures are favourable for the adsorption process. …”
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1734
Superparamagnetic Multifunctionalized Chitosan Nanohybrids for Efficient Copper Adsorption: Comparative Performance, Stability, and Mechanism Insights
Published 2023-02-01“…The adsorption was endothermic with fast kinetics (except TA-type was exothermic). …”
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1735
Functionalization of ZnO Particles with Tetraethyl Orthosilicate (TEOS) and Application as Heavy Metal Adsorbent Cu2+
Published 2024-01-01“…The ΔH value of P-ZnO was 12.34 kJ/mol and S-ZnO was 7.21 kJ/mol which indicated that the reaction occurred endothermically.…”
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1736
Fashionable epoxy/clay nanocomposites using modified clay-loaded methyl blue dye
Published 2023-06-01“…The adsorption of MB on claytone was endothermic and exothermic for the adsorption on clayD2000. …”
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1737
Activated Sawdust-Based Adsorbent for the Removal of Basic Blue 3 and Methylene Green from Aqueous Media
Published 2022-01-01“…Different thermodynamic parameters, such as enthalpy (∆H=18.5 and 8.334 kJ/mol respectively for basic blue 3 and methylene green), entropy (∆S°=62.41 and 29.22 kJ/molK respectively for basic blue 3 and methylene green), and Gibbs free energy (∆G°=−83.6, -410, and -1658 kJ/mol (basic blue)/-65, -519, and -1139 kJ/mol (methylene green), were estimated, and the process was found to be endothermic, spontaneous, and feasible. The increase in ΔG° with increase in temperature indicates that the adsorption process is favorable at high temperature. …”
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1738
Biodiesel Production through Acid Catalyst In Situ Reactive Extraction of <i>Chlorella vulgaris</i> Foamate
Published 2022-06-01“…The activation entropy (ΔS), change in Gibbs free energy (ΔG) and variation in activation enthalpy (ΔH) revealed that the transesterification reaction is endergonic and unspontaneous, while the endothermic nature of the reaction was confirmed by the positive value (16.6 kJ/mol) of the ΔH. …”
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1739
Providing New Insights on the Molecular Properties and Thermal Stability of Ovotransferrin and Lactoferrin
Published 2023-01-01“…The results showed that although obviously different isoelectric point (5.31, 9.12 and 8.75 for OVT, BLF and HLF, respectively), particle size distribution and hydrophobicity were found, they exhibited good dispersity because of high potential value. They showed an endothermic peak at 80.64 °C, 65.71 °C and 90.01 °C, respectively, and the denaturation temperature varied at different pH and ionic strength. …”
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1740
Mechanism-Enhanced Active Attapulgite-Supported Nanoscale Zero-Valent Iron for Efficient Removal of Pb<sup>2+</sup> from Aqueous Solution
Published 2022-05-01“…The adsorption of nZVI@ATP to Pb<sup>2+</sup> was mainly a spontaneous endothermic reaction of heterogeneous surfaces, and the adsorption rate of nZVI@ATP to Pb<sup>2+</sup> was proportional to pH in the range of 2–5.5. …”
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