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1221
(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)
Published 2010“…The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. …”
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1222
Poly[(mu(3)-4-carboxypyridine-3-carboxylato-kappa N-3:O-3:O-4)(triphenylphosphine-kappa P)silver(I)]
Published 2010“…The Ag atom exists in a distorted tetrahedral geometry. The H atom of the carboxylate is midway between two O atoms of the two carboxyl groups, thus forming a strong intramolecular hydrogen bond.…”
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1223
catena-Poly[[triphenyltin(IV)]-mu-2-(cyclohexylaminocarbonyl)benzoat o-kappa 2 O 1:O 2]
Published 2010“…The amide N atom is a hydrogen-bond donor to the uncoordinated carboxylate O atom. The geometry at the five-coordinate Sn atom is trans-C3SnO2 trigonal-bipyramidal.…”
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1224
Bis(quinoline-2-carboxylato-kappa 2 N,O)lead(II)
Published 2010“…These long interactions give rise to a layer coordination polymer having the lead atom in a distorted Psi-monocapped octahedral geometry.…”
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1225
Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)
Published 2010“…The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. …”
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1226
[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](triphenylphosphine-kappa P)gold(I)
Published 2010“…The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S, P-donor set [S-Au-P angle = 174.61 (4)degrees], with the distortion related to a short intramolecular Au center dot center dot center dot O contact [2.988 (3) angstrom]. …”
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1227
4,5-Dihydro-3a, 5a-diazoniapyrene triiodidocuprate(I)
Published 2011“…In the dianion of the title salt, (C14H12N2)[CuI3], the Cu-I atom is coordinated by three I- ions that define a nearly trigonalplanar geometry; the Cu-I atom lies 0.1407 (6) angstrom out of the plane. …”
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1228
Bis(acetato-kappa O-2,O `)diphenyl(pyridine-kappa N)tin(IV)
Published 2010“…In both molecules, the Sn-IV atom is sevencoordinated in a distorted pentagonal-bipyramidal geometry with the two phenyl groups in axial positions. …”
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1229
[(Z)-O-Methyl N-(3-chlorophenyl)thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
Published 2010“…In each molecule, the Au atom is coordinated within a S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)degrees for the two molecules], with the distortion due in part to the close intramolecular approach of the O atom [Au center dot center dot center dot O contacts = 3.054 (4) and 3.013 (4) angstrom, respectively, for the two molecules].…”
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1230
[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)
Published 2010“…The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060 (3) angstrom]. …”
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1231
8-Hydroxy-2-methylquinolinium tetrachlorido(quinolin-8-olato-kappa N-2,O) stannate(IV) acetonitrile monosolvate
Published 2010“…In the title solvated salt, (C10H10NO)[SnCl4(C9H6NO)]center dot-CH3CN, the Sn-IV atom is chelated by the N,O-bidentate 8-hydroxyquinolinate ligand and four chloride ions, generating a distorted SnONCl4 octahedral coordination geometry for the metal. In the crystal, the cations are linked to the anions and the solvent molecules by O-H center dot center dot center dot O and N-H center dot center dot center dot N hydrogen bonds, respectively.…”
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1232
(2,2 `-Bipyridine-kappa N-2,N `)bis(N-ethyl-N-methyldithiocarbamato-kappa S-2,S `)zinc(II)
Published 2010“…The metal atom is chelated by two S,S'-bidentate dithiocarbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN2S4 octahedral geometry. The methyl and ethyl groups of the anion are statistically disordered.…”
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1233
[N `-(5-Bromo-2-oxidobenzylidene-kappa O)-3-hydroxy-2-naphthohydrazidato-kappa N-2 `,O]dimethyltin(IV)
Published 2010“…The Sn-IV atom in the title compound, [Sn(CH3)(2)(C18H11BrN2O3)], shows a distorted cis-C2NO2Sn trigonal-bipyramidal coordination geometry, with an axial O-Sn-O angle of 155.27 (9)degrees. …”
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1234
The Effect of Impeller Design on the Mixing of Non-Newtonian Internal Tyre Lubricant
Published 2001“…This study highlights the importance of impeller-to-tank diameter ratio (D/T) and impeller geometry for optimal mixing results, based on the flow of fluid and impeller power requirement. …”
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1235
Direct optical observation of walls and disclination effects in active photonic devices
Published 2009“…These tuning features are shown to be a manifestation of physical processes occurring in the confined geometry of our tunable devices. Such physical processes include the formation and removal of line disclinations and an associated wall. …”
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1236
Bis(3-phenylprop-2-enylidene)propane-1,3-diamine-kappa N-2,N' dibromidocobalt(II)
Published 2009“…In the crystal structure of the title compound, [CoBr2(C21H22N2)], the Co-II atom is four-coordinated by two bromide anions and two N atoms from the bidentate Schiff base ligand in a distorted tetrahedral geometry.…”
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1237
Bis{2′-[1-(2-hydroxyphenyl)ethylidene]-benzohydrazido} bis(pyridine-κN)zinc(II)
Published 2004“…In the centrosymmetric title compound, [Zn(C15H 13N2O2)2-(C5H 5N)2], the Zn atom is chelated by the O and N atoms of two bidentate ligands. The coordination geometry of the central Zn atom is octahedral. The crystal packing is stabilized by intermolecular C - H⋯O interactions. © 2004 International Union of Crystallography Printed in Great Britain - all rights reserved.…”
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1238
Poly[(μ(3)-nicotinato-κO:O':N)(μ(2)-nicotinato-κO,O':N)iron(II)].
Published 2008“…The Fe atom shows octa-hedral coordination geometry but one of the Fe-O bonds is somewhat long [2.522 (2) Å].…”
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1239
Geometrical behaviors of LRS bianchi type-I cosmological models.
Published 2009“…It is shown that, LRS Bianchi type-I has always flat geometry in empty space. Also we have shown that the vacuum model does not have singularity when time goes to zero.…”
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1240
The geometrical concept in manuscripts of Funan: a preliminary study
Published 2010“…In this paper we shall discuss the influence of Buddhism geometry to the Malay world in Southeast Asia region during 4th -6th centuries in the era of Funan kingdom. …”
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