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  1. 51321

    Selective Formation, Reactivity, Redox and Magnetic Properties of Mn<sup>III</sup> and Fe<sup>III</sup> Dinuclear Complexes with Shortened Salen-Type Schiff Base Ligands by Luca Rigamonti, Paolo Zardi, Stefano Carlino, Francesco Demartin, Carlo Castellano, Laura Pigani, Alessandro Ponti, Anna Maria Ferretti, Alessandro Pasini

    Published 2020-10-01
    “…The selective formation of the dinuclear complexes [M<sub>2</sub>(μ-salmp)<sub>2</sub>], M = Mn (<b>1a</b>), Fe (<b>2a</b>), [M<sub>2</sub>(μ-salmen)<sub>2</sub>(μ-OR)<sub>2</sub>)], R = Et, Me, H and M = Mn (<b>3a</b>–<b>c</b>) or Fe (<b>4a</b>–<b>c</b>), and (M<sub>2</sub>(μ-sal[<i>p</i>-X]ben)<sub>2</sub>(μ-OMe)<sub>2</sub>), X = <i>t</i>Bu, Me, H, F, Cl, CF<sub>3</sub>, NO<sub>2</sub> and M = Mn (<b>5a</b>–<b>g</b>) or Fe (<b>6a</b>–<b>g</b>), could be identified by reaction of the Schiff bases with metal salts and the base NEt<sub>3</sub>, and their characterization through elemental analysis, infrared spectroscopy, mass spectrometry and single-crystal X-ray diffraction of <b>2a</b>·2AcOEt, <b>2a</b>·2CH<sub>3</sub>CN and <b>3c</b>·2DMF was performed. …”
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  2. 51322

    Investigating the Relationship between Land Cover and Thermal Island Changes Using Single channel Algorithm and Decision Tree Conceptual Method (Case Study: Ahvaz) by Najma Esmailpoor, fatemah esmaeilpoor, mojtaba yami, hosein amirazodi

    Published 2022-01-01
    “…Data and Method To determine the spatial-place changes of the heated islands of Ahvaz and also to determine its relationship with land use changes, first the Landsat satellite TM sensor images in the last 30 days and Envi software were used and the following main steps were performed: Stage 1 - Preparation of thermal map of the city: To calculate the temperature of the single channel algorithm (SCA) in order to extract LST, an extended infrared thermal band was used and to calculate it, Equation 1 was used. …”
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  3. 51323

    Ambulatory Monitoring of Cerebrovascular Responses to Upright Posture and Walking in Older Adults With Heart Failure by Kevin R. Murray, MSc, Jessica A. Poirier, MSc, Jason S. Au, PhD, Eric T. Hedge, MSc, Andrew D. Robertson, PhD, George A. Heckman, MD, Richard L. Hughson, PhD

    Published 2023-12-01
    “…In this study, we monitored central hemodynamics and middle cerebral artery blood velocity (MCAv) and cerebral tissue oxygenation (near-infrared spectroscopy) in 10 individuals with HF (aged 78 ± 4 years; left ventricular ejection fraction 20%-61%) and 13 similar-aged controls (79 ± 8 years; 52%–73%) during 3 randomized transitions, as follows: (i) supine-to-standing; (ii) sitting-to-slow-paced over-ground walking; and (iii) sitting-to-normal-paced over-ground walking. …”
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  4. 51324

    <i>Moringa concanensis</i>-Mediated Synthesis and Characterizations of Ciprofloxacin Encapsulated into Ag/TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub>/CS Nanocomposite: A Therapeuti... by Naheed Zafar, Bushra Uzair, Farid Menaa, Barkat Ali Khan, Muhammad Bilal Khan Niazi, Fatima S. Alaryani, Kamlah Ali Majrashi, Shamaila Sajjad

    Published 2022-08-01
    “…The resulting CS-based nanoparticulate drug delivery system (NDDS), i.e., CIP-Ag/TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub>/CS, was characterized in vitro by gold standard physical techniques such as X-ray diffractometry (XRD), field emission scanning electron microscopy (FESEM), Fourier-transform infrared (FTIR) spectroscopy. Pharmacological analyses (i.e., LC, EE, ex-vivo drug release behavior) were also assessed. …”
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  5. 51325

    TiO2 催化剂改性方法对光热催化麻疯树籽油制备 生物燃油的影响 by 杨依婕1,2, 刘莹1, 张伟1, 刘娜1, 桂超1, 蔡正达3,孙鲁闽2,陈玉保1 YANG Yijie1,2, LIU Ying1, ZHANG Wei1, LIU Na1, GUI Chao1, CAI Zhengda3, SUN Lumin2, CHEN Yubao1

    Published 2023-01-01
    “…To improve the problems of low catalytic efficiency and difficult recovery of TiO2 in the photothermal catalysis process, the Pt/TiO2-HZSM-5 catalysts were prepared by combining TiO2 with HZSM-5 molecular sieve using solid dispersion method and sol-gel method, respectively, and loaded with active metal Pt.The two catalysts were characterized by X-ray diffraction (XRD), N2 adsorption-desorption, high-resolution transmission electron microscopy (HRTEM), ultraviolet-visible light(UV-Vis), X-ray fluorescence (XRF) and pyridine-infrared (Py-IR), and used in the photothermal catalytic hydrogenation of Jatropha oil for the preparation of bio-fuel to investigate the catalytic effects of the two modified catalysts.The results showed that TiO2 was successfully dispersed on the surface of the HZSM-5 molecular sieve,the specific surface area of TiO2 increased, and the pore volume and pore size of the HZSM-5 molecular sieve changed.The modified catalyst showed a significant red shift in the diffraction peak with improved absorption of visible light, and the acidic sites increased.Compared with sol-gel method,Pt/TiO2-HZSM-5 prepared by solid dispersion method had better Pt dispersion and no agglomeration phenomenon, smaller particle size and better catalytic performance. …”
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  6. 51326
  7. 51327
  8. 51328

    BMP-2@PNH-TA hydrogel with osteogenic and antibacterial properties for integrated photothermal therapy by Jiwei Sun, Haojie Wei, Haoqi Lei, Tiantian Chen, Keqi Wo, Junyuan Zhang, Guangxia Feng, Jiechen Wang, Yifan Zhang, Yifan Wang, Jinyu Wang, Zhen Zhang, Yingying Chu, Lihong Fan, Jian Zhou, Lili Chen

    Published 2023-06-01
    “…Here, a bioactive hydrogel BMP-2@PNH-TA with simultaneously osteogenic and anti-bacterial capacities is presented, which is based on the near infrared (NIR) induced photothermal effect to perform integrated photothermal therapy (PTT). …”
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  9. 51329

    Magnetic and Electrical Behaviors of the Homo- and Heterometallic 1D and 3D Coordination Polymers Based on the Partial Decomposition of the [Cr(C<sub>2</sub>O<sub>4</sub>)<sub>3</s... by Lidija Kanižaj, Pavla Šenjug, Damir Pajić, Luka Pavić, Krešimir Molčanov, Marijana Jurić

    Published 2020-11-01
    “…One-dimensional (1D) oxalate-bridged homometallic {[Mn(bpy)(C<sub>2</sub>O<sub>4</sub>)]·1.5H<sub>2</sub>O}<i><sub>n</sub></i> (<b>1</b>) (bpy = 2,2’-bipyridine) and heterodimetallic {[CrCu<sub>3</sub>(bpy)<sub>3</sub>(CH<sub>3</sub>OH)(H<sub>2</sub>O)(C<sub>2</sub>O<sub>4</sub>)<sub>4</sub>][Cu(bpy)Cr(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·CH<sub>2</sub>Cl<sub>2</sub>·CH<sub>3</sub>OH·H<sub>2</sub>O}<i><sub>n</sub></i> (<b>2</b>) coordination polymers, as well as the three-dimensional (3D) heterotrimetallic {[CaCr<sub>2</sub>Cu<sub>2</sub>(phen)<sub>4</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>6</sub>]·4CH<sub>3</sub>CN·2H<sub>2</sub>O}<i><sub>n</sub></i> (<b>3</b>) (1,10-phenanthroline) network, have been synthesized by a building block approach using a layering technique, and characterized by single-crystal X-ray diffraction, infrared (IR) and impedance spectroscopies and magnetization measurements. …”
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  10. 51330

    Magnetite nanoparticles decorated on cellulose aerogel for p-nitrophenol Fenton degradation: Effects of the active phase loading, cross-linker agent and preparation method by Thi Thuy Van Nguyen, Quang Khai Nguyen, Ngoc Quan Thieu, Hoang Diem Trinh Nguyen, Thanh Gia Thien Ho, Ba Long Do, Thi Thuy Phuong Pham, Tri Nguyen, Huynh Ky Phuong Ha

    Published 2023-11-01
    “…As-synthesized samples were analysed by various methods, including Powder X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy dispersive X-ray analysis and Brunauer–Emmett–Teller. …”
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  11. 51331

    Updated trends of the stratospheric ozone vertical distribution in the 60°&thinsp;S–60°&thinsp;N latitude range based on the LOTUS regression model by S. Godin-Beekmann, N. Azouz, V. F. Sofieva, D. Hubert, I. Petropavlovskikh, P. Effertz, G. Ancellet, D. A. Degenstein, D. Zawada, L. Froidevaux, S. Frith, J. Wild, S. Davis, W. Steinbrecht, T. Leblanc, R. Querel, K. Tourpali, R. Damadeo, E. Maillard Barras, R. Stübi, C. Vigouroux, C. Arosio, G. Nedoluha, I. Boyd, R. Van Malderen, E. Mahieu, D. Smale, R. Sussmann

    Published 2022-09-01
    “…Longitudinally resolved merged satellite records are also considered in order to provide a better comparison with trends retrieved from ground-based records, e.g. lidar, ozonesondes, Umkehr, microwave and Fourier transform infrared (FTIR) spectrometers at selected stations where long-term time series are available. …”
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  12. 51332
  13. 51333

    Solar FTIR measurements of NO<sub><i>x</i></sub> vertical distributions – Part 1: First observational evidence of a seasonal variation in the diurnal increasing rates of stratosphe... by P. Nürnberg, M. Rettinger, R. Sussmann

    Published 2024-03-01
    “…Thus, we present in this work the evaluation of NO<span class="inline-formula"><sub>2</sub></span> and NO stratospheric partial columns (<span class="inline-formula">&gt;</span> 16 km altitude) retrieved from ground-based Fourier-transform infrared (FTIR) measurements of over 25 years at Zugspitze (47.42° N, 10.98° E; 2964 m a.s.l.) and 18 years at Garmisch (47.47° N, 11.06° E; 745 m a.s.l.), Germany. …”
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  14. 51334

    Optimization of Ethanolic Extraction of <i>Enantia chloranta</i> Bark, Phytochemical Composition, Green Synthesis of Silver Nanoparticles, and Antimicrobial Activity by Mbarga M. J. Arsene, Podoprigora I. Viktorovna, Marukhlenko V. Alla, Morozova A. Mariya, Goriainov V. Sergei, Esparza Cesar, Anyutoulou K. L. Davares, Kezimana Parfait, Kamgang N. Wilfrid, Tuturov S. Nikolay, Manar Rehailia, Smolyakova A. Larisa, Souadkia Sarra, Senyagin N. Alexandr, Ibrahim Khelifi, Khabadze S. Zurab, Karnaeva S. Amina, Todua M. Iia, Pikina P. Alla, Ada A. Gabin, Ndandja T. K. Dimitri, Kozhevnikova A. Liudmila, Pilshchikova V. Olga

    Published 2022-10-01
    “…In this study, using the Box–Behnken model, we optimized the ethanolic extraction of phytochemicals from <i>Enantia chloranta</i> bark for the first time, assessed the composition with HPLC-MS/MS, performed the green synthesis of silver nanoparticles (AgNPs) and characterized them with UV-Vis spectrophotometry, photon cross-correlation spectroscopy, energy-dispersive X-ray fluorescence spectrometry, and Fourier transform infrared spectroscopy. The antibacterial and antibiotic-resistance reversal properties of optimized extract (O-ECB) and AgNPs were assessed on various microorganisms (15 Gram−, 7 Gram+, and 2 fungi) using the well diffusion method and microbroth dilution assay. …”
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  15. 51335
  16. 51336

    Sr(II) and Ba(II) Alkaline Earth Metal–Organic Frameworks (AE-MOFs) for Selective Gas Adsorption, Energy Storage, and Environmental Application by Nikolas Király, Dominika Capková, Róbert Gyepes, Nikola Vargová, Tomáš Kazda, Jozef Bednarčík, Daria Yudina, Tomáš Zelenka, Pavel Čudek, Vladimír Zeleňák, Anshu Sharma, Vera Meynen, Virginie Hornebecq, Andrea Straková Fedorková, Miroslav Almáši

    Published 2023-01-01
    “…The activation process of the compounds was studied by the combination of in situ heating infrared spectroscopy (IR), thermal analysis (TA) and in situ high-energy powder X-ray diffraction (HE-PXRD), which confirmed the stability of compounds after desolvation. …”
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  17. 51337

    Green Synthesis of Zinc Oxide Nanoparticles from Althaea officinalis Flower Extract Coated with Chitosan for Potential Healing Effects on Diabetic Wounds by Inhibiting TNF-&alpha;... by Elhabal SF, Abdelaal N, Saeed Al-Zuhairy SAK, Elrefai MFM, Elsaid Hamdan AM, Khalifa MM, Hababeh S, Khasawneh MA, Khamis GM, Nelson J, Mohie PM, Gad RA, Rizk A, Kabil SL, El-Ashery MK, Jasti BR, Elzohairy NA, Elnawawy T, Hassan FE, El- Nabarawi MA

    Published 2024-03-01
    “…Besides, Fourier transforms infrared (FTIR) was used to qualitatively validate biosynthesized ZnO-NPs, and transmission electron microscope (TEM) showed spherical nanoparticles with mean sizes of 76 nm and Zeta potential +30mV. …”
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  18. 51338
  19. 51339
  20. 51340

    The effect of different levels and methods of flaxseed processing on growth performance, nutrient digestibility, blood parameters and sheep ruminant behavior by Mostafa Hosseinabadi, Taghi Ghoorchi, Abdolhakim Toghdory

    Published 2022-05-01
    “…Microwave by microwave can be done after adding 25% moisture to the grains for 3 minutes in a device containing an infrared lamp. It was also found that micronization could be used to increase the degradable protein content of the rumen. …”
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