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51321
Selective Formation, Reactivity, Redox and Magnetic Properties of Mn<sup>III</sup> and Fe<sup>III</sup> Dinuclear Complexes with Shortened Salen-Type Schiff Base Ligands
Published 2020-10-01“…The selective formation of the dinuclear complexes [M<sub>2</sub>(μ-salmp)<sub>2</sub>], M = Mn (<b>1a</b>), Fe (<b>2a</b>), [M<sub>2</sub>(μ-salmen)<sub>2</sub>(μ-OR)<sub>2</sub>)], R = Et, Me, H and M = Mn (<b>3a</b>–<b>c</b>) or Fe (<b>4a</b>–<b>c</b>), and (M<sub>2</sub>(μ-sal[<i>p</i>-X]ben)<sub>2</sub>(μ-OMe)<sub>2</sub>), X = <i>t</i>Bu, Me, H, F, Cl, CF<sub>3</sub>, NO<sub>2</sub> and M = Mn (<b>5a</b>–<b>g</b>) or Fe (<b>6a</b>–<b>g</b>), could be identified by reaction of the Schiff bases with metal salts and the base NEt<sub>3</sub>, and their characterization through elemental analysis, infrared spectroscopy, mass spectrometry and single-crystal X-ray diffraction of <b>2a</b>·2AcOEt, <b>2a</b>·2CH<sub>3</sub>CN and <b>3c</b>·2DMF was performed. …”
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51322
Investigating the Relationship between Land Cover and Thermal Island Changes Using Single channel Algorithm and Decision Tree Conceptual Method (Case Study: Ahvaz)
Published 2022-01-01“…Data and Method To determine the spatial-place changes of the heated islands of Ahvaz and also to determine its relationship with land use changes, first the Landsat satellite TM sensor images in the last 30 days and Envi software were used and the following main steps were performed: Stage 1 - Preparation of thermal map of the city: To calculate the temperature of the single channel algorithm (SCA) in order to extract LST, an extended infrared thermal band was used and to calculate it, Equation 1 was used. …”
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51323
Ambulatory Monitoring of Cerebrovascular Responses to Upright Posture and Walking in Older Adults With Heart Failure
Published 2023-12-01“…In this study, we monitored central hemodynamics and middle cerebral artery blood velocity (MCAv) and cerebral tissue oxygenation (near-infrared spectroscopy) in 10 individuals with HF (aged 78 ± 4 years; left ventricular ejection fraction 20%-61%) and 13 similar-aged controls (79 ± 8 years; 52%–73%) during 3 randomized transitions, as follows: (i) supine-to-standing; (ii) sitting-to-slow-paced over-ground walking; and (iii) sitting-to-normal-paced over-ground walking. …”
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51324
<i>Moringa concanensis</i>-Mediated Synthesis and Characterizations of Ciprofloxacin Encapsulated into Ag/TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub>/CS Nanocomposite: A Therapeuti...
Published 2022-08-01“…The resulting CS-based nanoparticulate drug delivery system (NDDS), i.e., CIP-Ag/TiO<sub>2</sub>/Fe<sub>2</sub>O<sub>3</sub>/CS, was characterized in vitro by gold standard physical techniques such as X-ray diffractometry (XRD), field emission scanning electron microscopy (FESEM), Fourier-transform infrared (FTIR) spectroscopy. Pharmacological analyses (i.e., LC, EE, ex-vivo drug release behavior) were also assessed. …”
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51325
TiO2 催化剂改性方法对光热催化麻疯树籽油制备 生物燃油的影响
Published 2023-01-01“…To improve the problems of low catalytic efficiency and difficult recovery of TiO2 in the photothermal catalysis process, the Pt/TiO2-HZSM-5 catalysts were prepared by combining TiO2 with HZSM-5 molecular sieve using solid dispersion method and sol-gel method, respectively, and loaded with active metal Pt.The two catalysts were characterized by X-ray diffraction (XRD), N2 adsorption-desorption, high-resolution transmission electron microscopy (HRTEM), ultraviolet-visible light(UV-Vis), X-ray fluorescence (XRF) and pyridine-infrared (Py-IR), and used in the photothermal catalytic hydrogenation of Jatropha oil for the preparation of bio-fuel to investigate the catalytic effects of the two modified catalysts.The results showed that TiO2 was successfully dispersed on the surface of the HZSM-5 molecular sieve,the specific surface area of TiO2 increased, and the pore volume and pore size of the HZSM-5 molecular sieve changed.The modified catalyst showed a significant red shift in the diffraction peak with improved absorption of visible light, and the acidic sites increased.Compared with sol-gel method,Pt/TiO2-HZSM-5 prepared by solid dispersion method had better Pt dispersion and no agglomeration phenomenon, smaller particle size and better catalytic performance. …”
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51326
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51327
TOI-5375 B: A Very Low Mass Star at the Hydrogen-burning Limit Orbiting an Early M-type Star
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51328
BMP-2@PNH-TA hydrogel with osteogenic and antibacterial properties for integrated photothermal therapy
Published 2023-06-01“…Here, a bioactive hydrogel BMP-2@PNH-TA with simultaneously osteogenic and anti-bacterial capacities is presented, which is based on the near infrared (NIR) induced photothermal effect to perform integrated photothermal therapy (PTT). …”
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51329
Magnetic and Electrical Behaviors of the Homo- and Heterometallic 1D and 3D Coordination Polymers Based on the Partial Decomposition of the [Cr(C<sub>2</sub>O<sub>4</sub>)<sub>3</s...
Published 2020-11-01“…One-dimensional (1D) oxalate-bridged homometallic {[Mn(bpy)(C<sub>2</sub>O<sub>4</sub>)]·1.5H<sub>2</sub>O}<i><sub>n</sub></i> (<b>1</b>) (bpy = 2,2’-bipyridine) and heterodimetallic {[CrCu<sub>3</sub>(bpy)<sub>3</sub>(CH<sub>3</sub>OH)(H<sub>2</sub>O)(C<sub>2</sub>O<sub>4</sub>)<sub>4</sub>][Cu(bpy)Cr(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·CH<sub>2</sub>Cl<sub>2</sub>·CH<sub>3</sub>OH·H<sub>2</sub>O}<i><sub>n</sub></i> (<b>2</b>) coordination polymers, as well as the three-dimensional (3D) heterotrimetallic {[CaCr<sub>2</sub>Cu<sub>2</sub>(phen)<sub>4</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>6</sub>]·4CH<sub>3</sub>CN·2H<sub>2</sub>O}<i><sub>n</sub></i> (<b>3</b>) (1,10-phenanthroline) network, have been synthesized by a building block approach using a layering technique, and characterized by single-crystal X-ray diffraction, infrared (IR) and impedance spectroscopies and magnetization measurements. …”
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51330
Magnetite nanoparticles decorated on cellulose aerogel for p-nitrophenol Fenton degradation: Effects of the active phase loading, cross-linker agent and preparation method
Published 2023-11-01“…As-synthesized samples were analysed by various methods, including Powder X-ray diffraction, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy dispersive X-ray analysis and Brunauer–Emmett–Teller. …”
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51331
Updated trends of the stratospheric ozone vertical distribution in the 60° S–60° N latitude range based on the LOTUS regression model
Published 2022-09-01“…Longitudinally resolved merged satellite records are also considered in order to provide a better comparison with trends retrieved from ground-based records, e.g. lidar, ozonesondes, Umkehr, microwave and Fourier transform infrared (FTIR) spectrometers at selected stations where long-term time series are available. …”
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51332
In Vitro Anticancer Activity of Mucoadhesive Oral Films Loaded with <i>Usnea barbata</i> (L.) F. H. Wigg Dry Acetone Extract, with Potential Applications in Oral Squamous Cell Carc...
Published 2022-09-01“…Physico-chemical and structural characterization was achieved by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and atomic force microscopy (AFM). …”
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51333
Solar FTIR measurements of NO<sub><i>x</i></sub> vertical distributions – Part 1: First observational evidence of a seasonal variation in the diurnal increasing rates of stratosphe...
Published 2024-03-01“…Thus, we present in this work the evaluation of NO<span class="inline-formula"><sub>2</sub></span> and NO stratospheric partial columns (<span class="inline-formula">></span> 16 km altitude) retrieved from ground-based Fourier-transform infrared (FTIR) measurements of over 25 years at Zugspitze (47.42° N, 10.98° E; 2964 m a.s.l.) and 18 years at Garmisch (47.47° N, 11.06° E; 745 m a.s.l.), Germany. …”
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51334
Optimization of Ethanolic Extraction of <i>Enantia chloranta</i> Bark, Phytochemical Composition, Green Synthesis of Silver Nanoparticles, and Antimicrobial Activity
Published 2022-10-01“…In this study, using the Box–Behnken model, we optimized the ethanolic extraction of phytochemicals from <i>Enantia chloranta</i> bark for the first time, assessed the composition with HPLC-MS/MS, performed the green synthesis of silver nanoparticles (AgNPs) and characterized them with UV-Vis spectrophotometry, photon cross-correlation spectroscopy, energy-dispersive X-ray fluorescence spectrometry, and Fourier transform infrared spectroscopy. The antibacterial and antibiotic-resistance reversal properties of optimized extract (O-ECB) and AgNPs were assessed on various microorganisms (15 Gram−, 7 Gram+, and 2 fungi) using the well diffusion method and microbroth dilution assay. …”
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51335
Synthesis of 1,2,3-Triazole-Containing Methoxylated Cinnamides and Their Antileishmanial Activity against the <i>Leishmania braziliensis</i> Species
Published 2023-08-01“…The compounds were characterized using infrared, nuclear magnetic resonance, and high-resolution mass spectrometry techniques. …”
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51336
Sr(II) and Ba(II) Alkaline Earth Metal–Organic Frameworks (AE-MOFs) for Selective Gas Adsorption, Energy Storage, and Environmental Application
Published 2023-01-01“…The activation process of the compounds was studied by the combination of in situ heating infrared spectroscopy (IR), thermal analysis (TA) and in situ high-energy powder X-ray diffraction (HE-PXRD), which confirmed the stability of compounds after desolvation. …”
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51337
Green Synthesis of Zinc Oxide Nanoparticles from Althaea officinalis Flower Extract Coated with Chitosan for Potential Healing Effects on Diabetic Wounds by Inhibiting TNF-α...
Published 2024-03-01“…Besides, Fourier transforms infrared (FTIR) was used to qualitatively validate biosynthesized ZnO-NPs, and transmission electron microscope (TEM) showed spherical nanoparticles with mean sizes of 76 nm and Zeta potential +30mV. …”
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51338
SN 2023ixf in Messier 101: A Variable Red Supergiant as the Progenitor Candidate to a Type II Supernova
Published 2023-01-01“…We present preexplosion optical and infrared (IR) imaging at the site of the type II supernova (SN II) 2023ixf in Messier 101 at 6.9 Mpc. …”
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51339
Design, Characterization, and Anticancer and Antimicrobial Activities of Mucoadhesive Oral Patches Loaded with <i>Usnea barbata</i> (L.) F. H. Wigg Ethanol Extract F-UBE-HPMC
Published 2022-09-01“…Scanning electron microscopy (SEM) and atomic force microscopy (AFM) were performed for their morphological characterization, followed by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). …”
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51340
The effect of different levels and methods of flaxseed processing on growth performance, nutrient digestibility, blood parameters and sheep ruminant behavior
Published 2022-05-01“…Microwave by microwave can be done after adding 25% moisture to the grains for 3 minutes in a device containing an infrared lamp. It was also found that micronization could be used to increase the degradable protein content of the rumen. …”
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