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3741
Tentative Approaches for Extraction of Lanthanides from Wastewater with Low Metal Concentration
Published 2023-04-01“…The PVDF membranes showed quite poor results, with only the membrane with oxamate ionic liquid giving some positive results (0.75 mg of Yb, 3 mg of lanthanides per gram of membrane). …”
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3742
Axial Oxygen Ligands Regulating Electronic and Geometric Structure of Zn‐N‐C Sites to Boost Oxygen Reduction Reaction
Published 2023-08-01“…Here, guided by theoretical calculations, five‐fold coordinated single‐atom Zn sites with four in‐plane N ligands is constructed and one axial O ligand (Zn‐N4‐O) by ionic liquid‐assisted molten salt template method. Additional axial O not only triggers a geometry transformation from the planar structure of Zn‐N4 to the non‐planar structure of Zn‐N4‐O, but also induces the electron transfer from Zn center to neighboring atoms and lower the d‐band center of Zn atom, which weakens the adsorption strength of *OH and decreases the energy barrier of rate determining step of ORR. …”
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3743
Wood-Based Cellulose-Rich Ultrafiltration Membranes: Alkaline Coagulation Bath Introduction and Investigation of Its Effect over Membranes’ Performance
Published 2022-05-01“…Flat-sheet membranes were prepared from birch biomass pretreated with deep eutectic solvent and dissolved in ionic liquid-dimethylsulfoxide system via phase inversion method. …”
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3744
Unveiling Novel Chaotropic Chromatography Method for Determination of Pralidoxime in Nerve Agent Antidote Autoinjectors
Published 2024-03-01“…The addition of chaotropic salts (NaPF<sub>6</sub>, NaBF<sub>4</sub>, and NaClO<sub>4</sub>) and an ionic liquid ([EMIM]PF<sub>6</sub>) increased the retention time of pralidoxime chloride. …”
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3745
Ion Gel‐Gated Quasi‐Solid‐State Vertical Organic Electrochemical Transistor and Inverter
Published 2023-06-01“…Indacenodithiophene (IDT) polymers with alkyl (PIDTC16‐BT) and oligoethylene glycol (OEG) substituents (PIDTPEG‐BT) are studied as a channel material, and an ionic liquid in a crosslinked polymer matrix is adopted as a quasi‐solid electrolyte. …”
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3746
Boron nitride-enabled printing of a highly sensitive and flexible iontronic pressure sensing system for spatial mapping
Published 2023-05-01“…Herein, for the first time, we employed a 2-dimensional (2D) hexagonal boron nitride (h-BN) as both an additive and an ionic liquid reservoir in an ionic film, making the sensor printable and significantly improving its sensitivity and sensing range through screen printing. …”
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3747
Effective Combination of the Metal Centers in MOF-Based Materials toward Sustainable Oxidation Catalysts
Published 2023-04-01“…The presence of Zn<sup>2+</sup> in the composite material PMo<sub>12</sub>@ZIF-8 instead of Co<sup>2+</sup> in PMo<sub>12</sub>@ZIF-67 caused a remarkable increase in the catalytic activity that achieved a total oxidative desulfurization of a multicomponent model diesel under moderate and friendly conditions (oxidant: H<sub>2</sub>O<sub>2</sub> and solvent: ionic liquid, IL). Interestingly, the parent ZIF-8-based composite with the Keggin-type polyoxotungstate (H<sub>3</sub>[PW<sub>12</sub>O<sub>40</sub>], PW<sub>12</sub>), PW<sub>12</sub>@ZIF-8, did not show the relevant catalytic activity. …”
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3748
An Engineered Laccase from <i>Fomitiporia mediterranea</i> Accelerates Lignocellulose Degradation
Published 2024-03-01“…The potential of Fom_lac and Fom_CBM to enhance saccharification yields from untreated and ionic liquid pretreated pine was also investigated. Adding Fom_CBM to mixtures of cellulases and hemicellulases improved sugar yields by 140% on untreated pine and 32% on cholinium lysinate pretreated pine when compared to the inclusion of Fom_lac to the same mixtures. …”
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3749
Competitive Li+ Coordination in Ionogel Electrolytes for Enhanced Li‐Ion Transport Kinetics
Published 2023-08-01“…Abstract Developing ionogel electrolytes based on ionic liquid instead of volatile liquid in gel polymer electrolytes is regarded to be effective to diminish safety concerns in terms of overheating and fire. …”
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3750
MnPO4‐coated Li(Ni0.4Co0.2Mn0.4)O2 for lithium(‐ion) batteries with outstanding cycling stability and enhanced lithiation kinetics
Published 2020“…This superior electrochemical behavior of MP-NCM compared to as-synthesized NCM is attributed to the superior stability of the electrode/electrolyte interface and structural integrity when applying a MnPO4 coating. Employing an ionic liquid as an alternative, intrinsically safer electrolyte system allows for outstanding cycling stabilities in a lithium-metal battery configuration with a capacity retention of well above 85% after 2000 cycles. …”
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Journal Article -
3751
Direct one-step controlled partial depolymerization and upcycling of poly(ethylene terephthalate) into hyperbranched oligomeric ionogel
Published 2023“…The key strategy for our approach is using multifunctional cleaving agents such as glycerol in the presence of ionic liquid as a catalyst for controlled partial depolymerization of PET via transesterification using N-Methyl-2-pyrrolidone (NMP) as solvent. …”
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Journal Article -
3752
Polysulfone (PSF) Membrane Incorporated With Polyamide-Tethered Polyhedral Oligomeric Silsequioxane (POSS) For Carbon Dioxide Separation
Published 2017“…Furthermore, the MMMs were modified using ionic liquid (IL) [emim][TF2N] with 0.4 M concentration and polydimethylsiloxane (PDMS) to improve the gas selectivity of these MMMs. …”
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Monograph -
3753
Effect EMIMCl on electrochemical properties based PMMA-PLA hybrid gel polymer electrolyte
Published 2022“…The formulation of a hybrid gel polymer electrolyte (HGPE) system comprising of polymethyl methacrylate (PMMA) and polylactic acid (PLA) as a hybrid host polymer doped with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) has been successfully prepared in this study with the introduction of an ionic liquid, namely 1-Ethyl-3-methylimidazolium chloride (EMIMCl). …”
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3754
Cellulose extraction via acid digester and alkaline digester from empty fruit bunch (efb) and banana trunk
Published 2014“…There are many approaches that have been studied in extraction of cellulose such as steam explosion, ionic liquid, liquid hot water treatment and many more. …”
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Undergraduates Project Papers -
3755
Research and Development of Thermally Durable Electrolyte for Lithium Ion Battery
Published 2021-11-01“…For the liquid phase, a solvate ionic liquid, which is an equimolar complex of lithium bis(trifluoromethanesulfonyl)amide (LiTFSA) and tetraethylene glycol dimethyl ether (G4), Li(G4)TFSA, was used. …”
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3756
Deep Eutectic Solvent Pretreatment of Water Hyacinth for Improved Holocellulosic Saccharification and Fermentative Co-Production of Xylitol and Lipids Using <i>Rhodosporidium torul...
Published 2022-10-01“…In this study, delignification of water hyacinth (WH) using a mild ionic liquid-like chemical deep eutectic solvent (DES) synthesized using choline chloride and urea was conducted and the process parameters were optimized by Box–Behnken design (BBD)-based response surface methodology (RSM). …”
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3757
Biocompatible and Biodegradable Surfactants from Orange Peel for Oil Spill Remediation
Published 2023-08-01“…Herein, two biocompatible and biodegradable surfactants were synthesized from orange peel using the ionic liquid 1-butyl-3-methylimidazolium chloride (BMIMCl) and organic solvent dimethylacetamide (CH3CN(CH3)2) as reaction media. …”
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3758
Molecular dynamics simulation of Pt@Au nanoalloy in various solvents: Investigation of solvation, aggregation, and possible coalescence
Published 2023-09-01“…In this study, a pair of core-shell Pt@Au nanoalloy particles with 309 atoms was simulated in various solvents, including water, benzene, ethanol, water + benzene, and 1-butyl-1,1,1-trimethylammonium methanesulfonate [N1114][C1SO3] ionic liquid (IL) at 300 K and 1 atm. We investigated the aggregation and possible coalescence of Au–Pt nanoalloys based on various thermodynamic, dynamic, and structural simulation results. …”
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3759
Piperacillin/Tazobactam Co-Delivery by Micellar Ionic Conjugate Systems Carrying Pharmaceutical Anions and Encapsulated Drug
Published 2024-01-01“…Previously obtained amphiphilic graft copolymers based on [2-(methacryloyloxy)ethyl]trimethylammonium chloride (TMAMA) ionic liquid were used as the matrices of three types of nanocarriers, i.e., conjugates with ionic piperacillin (PIP) and micelles with tazobactam (TAZ), which represented single systems, and dual systems bearing PIP anions and encapsulated TAZ for co-delivery. …”
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3760
Laser-Induced Interdigital Structured Graphene Electrodes Based Flexible Micro-Supercapacitor for Efficient Peak Energy Storage
Published 2022-01-01“…The flexible and scalable MSCs are fabricated by CO<sub>2</sub>-laser structuring of polyimide-based Kapton <sup>®</sup> HN foils at ambient temperature yielding interdigital LIG-electrodes and using polymer gel electrolyte (PGE) produced by polypropylene carbonate (PPC) embedded ionic liquid of 1-ethyl-3-methyl-imidazolium-trifluoromethansulphonate [EMIM][OTf]. …”
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