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7681
Development of Biochars Derived from Water Bamboo (<i>Zizania latifolia</i>) Shoot Husks Using Pyrolysis and Ultrasound-Assisted Pyrolysis for the Treatment of Reactive Black 5 (RB...
Published 2021-06-01“…Scanning electron microscope (SEM) images indicated that the UBC morphology surface was more porous, with the structure of the combination of denser mesopores enhancing physiochemical properties of UBC. …”
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7682
Preparation of coffee residual based biochar and its removal of fluoride ions from mine water
Published 2021-12-01“…In recent years, the problem of excessive fluoride in mine water is particularly prominent, which not only affects the water quality of reuse after treatment, but also endangers human health.Therefore, the study herein developed a novel adsorbent for fluoride -coffee residual based biochar(CRB)by applying the waste coffee residue as raw material and chemical activation, to realize the purpose of solid waste resource utilization and fluoride removal from mine water at the same time.The authors firstly optimized the preparation protocols of CRB through single factor, including the type of activator, activator concentration and activation temperature; then evaluated the adsorption efficiency of fluoride for CRB before and after optimization by kinetic and isothermal adsorption experiments; finally investigated the adsorption mechanism of fluoride for CRB after optimization(O-CRB)by surface physicochemical characterization.The results showed that the more favorable CRB for fluoride was prepared at the ZnCl<sub>2</sub> concentration of 4 mol/L and the activation temperature of 400 ℃.The maximum adsorption capacity of O-CRB for fluoride was 2.20 mg/g, which was 1.30 times higher than that of CRB before activation.In addition, compared with CRB, O-CRB exhibited higher amount of mesopore volume and specific surface area, as well as more oxygen containing functional groups(-COOH)and surface Zeta potential.Thus, the amount of chloride on the O-CRB surface decreased obviously(3.27 % to 0.61 %)after fluoride adsorption, whereas the amount of fluoride increased significantly(0.76 % to 10.34 %).This suggested that the adsorption of fluoride for O-CRB was mainly attributed to the electrostatic adsorption and ion exchange.…”
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7683
Production of biochar from oil palm frond by steam pyrolysis for removal of residual contaminants in palm oil mill effluent final discharge
Published 2020“…The total suspended solids affected the adsorption capacity of granular biochar by blocking residual macropores that provide access to adsorption sites in micropores and mesopores. At 30 g L−1, the micro-fine biochar exhibited an effective reduction of chemical oxygen demand from 224 to 41.6 mg g−1 and color from 344 to 15 Pt–Co g−1 making the wastewater suitable for reuse in palm oil mills and safe for discharge into the aquatic environment.…”
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7684
From Feather to Adsorbent: Keratin Extraction, Chemical Modification, and Fe(III) Removal from Aqueous Solution
Published 2021-12-01“…The GA-FK gel was found to have a three-dimensional network structure with abundant mesopores. Its pore size range is 1.8~90 nm; average pore size is 19.6 nm. …”
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7685
Testing of activated carbon for water and non-volatile LNAPL quantitative determination in porous media under laboratory conditions
Published 2014-12-01“…Activated carbon material has been artificially processed as a set of plates, within which two different types of pores are present: micropores (< 2 nm) and transport pores (macropores > 50 nm and mesopores 2-50 nm). The transport pores bring molecules of different substances (organic compounds) into the micropores, which are basically the active centres where the adsorption takes place. …”
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7686
Permeability model for shale and ultra-tight gas formations: Critical insights into the impact of dynamic adsorption
Published 2021-11-01“…For instance, surface diffusion constituted over 50% of the apparent permeability below the 10 MPa and 5.0 MPa conditions in micro- and mesopore systems, respectively, while the Darcy scale phenomenon controlled the transport of gas in macropores. …”
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7687
Fabrication of High Surface Area TiO<sub>2</sub>-MoO<sub>3</sub> Nanocomposite as a Photocatalyst for Organic Pollutants Removal from Water Bodies
Published 2023-02-01“…Sorption of nitrogen isotherms revealed a significant increase in the number and pore widths of mesopores in the NC. Water sorption isotherms revealed enhanced affinity of the nanocomposites for water relative to the pure metal oxides. …”
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7688
Facile Synthesis of Functionalized Porous Carbon by Direct Pyrolysis of <i>Anacardium occidentale</i> Nut-Skin Waste and Its Utilization towards Supercapacitors
Published 2023-05-01“…The as-prepared AO-PC material possessed interconnected micropore/mesopore structures and exhibited a high specific surface area of 615 m<sup>2</sup> g<sup>−1</sup>. …”
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7689
Role of the solvent evaporating temperature on the NiMo/TiO2-Al2O3 catalyst and the hydrodesulfurization performance for 4,6-dimenthyldibenzothiophehe
Published 2022-08-01“…The results revealed that the synthesized TA-x serial composites are amorphous mixtures of TiO2 and Al2O3 with highly ordered two-dimensional hexagonal mesopores. Both the mesostructures and the acidities of the synthesized TA-x composites changed at different evaporation temperature of the solvent. …”
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7690
A research on the preparation of oil-adsorbing hydrophobic porous resins by high internal phase emulsions (HIPEs) template
Published 2019-01-01“…The hierarchical porous structure of HPRs contained macropores ranging from 0.3 μm to 4 μm and mesopores of 11.26 nm. HPRs have rough and hydrophobic surface (water contact angle of 130∘) with specific surface area of 15.06 m2/g and pore volume of 0.0349 cm3/g. …”
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7691
Use of plantain peel adsorbents for the reduction of carbon monoxide from biogas for use as chick heating energy in an egg production industry
Published 2023-06-01“…In addition, the surface morphology allows the observation of asperities on the surface of the adsorbents which can be either macropores, mesopores or micropores. The adsorption curves showed that AC-Fe has the longest saturation time of 615 minutes compared to 191 minutes and 188 minutes for BC and AC-K respectively. …”
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7692
Catalytic Evaluation of Hafnium Modified SiO<sub>2</sub> for the Dehydration of Alcohols
Published 2023-07-01“…The influence of hafnium metal (Hf) and sulfate ions (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mi mathvariant="normal">S</mi><mi mathvariant="normal">O</mi></mrow><mrow><mn>4</mn></mrow><mrow><mn>2</mn><mo>−</mo></mrow></msubsup></mrow></semantics></math></inline-formula>) on the acidic properties of SiO<sub>2</sub> mesopores synthesized by a non-hydrothermal method was studied using the following characterization techniques; TG-DTG, XRD, BET, SEM, TEM, EDS, FTIR, n-butylamine titration, FTIR-pyridine, and alcohol dehydration. …”
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7693
Comparing the Pore Networks of Coal, Shale, and Tight Sandstone Reservoirs of Shanxi Formation, Qinshui Basin: Inspirations for Multi-Superimposed Gas Systems in Coal-Bearing Strat...
Published 2023-03-01“…Thus, they become influential factors controlling the relationship between the gas-bearing subsystems with different fluid pressures. The lack of mesopores in shale and relatively weaker heterogeneity between layers lead to the phenomenon that continuously developed shales of a specific thickness are more likely to be the interlayers that divide the superimposed gas-bearing system. …”
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7694
Nanoarchitectonics of Lotus Seed Derived Nanoporous Carbon Materials for Supercapacitor Applications
Published 2020-11-01“…Lotus seed-derived activated carbon materials display hierarchically porous structures comprised of micropore and mesopore architectures, and exhibited excellent supercapacitance performances. …”
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7695
Modified Approach Using <i>Mentha arvensis</i> in the Synthesis of ZnO Nanoparticles—Textural, Structural, and Photocatalytic Properties
Published 2022-01-01“…Upon increasing the plant extract concentration, the relative proportion of mesopores in the BS-Zn samples also increased. It was established that the photocatalytic performance of the biosynthesized powders was dependent on the <b>MA</b> concentration in the precursor solution. …”
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7696
Modulation of ODH Propane Selectivity by Zeolite Support Desilication: Vanadium Species Anchored to Al-Rich Shell as Crucial Active Sites
Published 2022-05-01“…The modification of zeolite via caustic treatment is an effective method of adjusting its basicity—a parameter that plays an important role in the ODH process. The developed mesopore surface ensured the attachment of vanadium species to silanol groups and formation of isolated (SiO)<sub>2</sub>(HO)V=O and (SiO)<sub>3</sub>V=O sites or polymeric, highly dispersed forms located in the zeolite micropores. …”
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7697
Nanoporous Activated Carbon Material from <i>Terminalia chebula</i> Seed for Supercapacitor Application
Published 2023-11-01“…The amorphous carbon materials obtained exhibit excellent performance as electrical double-layer capacitor electrodes in aqueous electrolyte (1 M sulfuric acid) due to high specific surface areas (as high as 1382.6 m<sup>2</sup> g<sup>−1</sup>) based on well-developed micropore and mesopore structures, and partial graphitic structure containing oxygenated surface functional groups. …”
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7698
The adsorption performance of aluminum onto powdered activated carbons: Effects of pH and carbon properties
Published 2023-06-01“…When pH was 6.5, Al adsorption by PAC was mainly due to the surface deposition, consequently, mesopore and total pore volume were critical properties. …”
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7699
Reservoir characteristics and formation model of Upper Carboniferous bauxite series in eastern Ordos Basin, NW China
Published 2024-02-01“…Both bauxitic mudstone and bauxite reservoirs develop dissolution pores, intercrystalline pores, and microfractures as the dominant gas storage space, with the porosity less than 10% and mesopores in dominance. The bauxite series in the North China Craton, which can be divided into five sections, i.e., ferrilite (Shanxi-style iron ore, section A), bauxitic mudstone (section B), bauxite (section C), bauxite mudstone (debris-containing, section D) and dark mudstone-coal section (section E). …”
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7700
Facile and Rapid Synthesis of Durable SSZ-13 Catalyst Using Choline Chloride Template for Methanol-to-Olefins Reaction
Published 2021-10-01“…The synthesized catalyst demonstrated excellent porous features with a total specific surface area and mesopore volume of 641.71 m<sup>2</sup>·g<sup>−1</sup> and 0.04 cm<sup>3</sup>·g<sup>−1</sup>, respectively. …”
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