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Titanium and zirconium permethylpentalene chemistry: ethylene polymerisation and small molecule activation
Published 2018“…<p><strong>Chapter One</strong></p> provides an introduction to the chemistry of pentalene and its derivatives encompassing ligand synthesis, organometallic chemistry, and in particular ethylene polymerisation. …”
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The synthesis of cobalt(I) σ-alkane complex and pincer complex catalysts for the generation of polyaminoborane on scale
Published 2021“…Chapter 1 provides a brief introduction to the organometallic chemistry of cobalt and rhodium.</p> <p>Chapter 2 describes the synthesis of an X-ray crystallographically characterised cobalt σalkane complex, <strong>[Co(Cy2P(CH2)4PCy2)(norbornane)][BArF4]</strong>. …”
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Synthesis, Electrochemical and Photochemical Properties of Sulfanyl Porphyrazine with Ferrocenyl Substituents
Published 2023-07-01“…Ferrocene is useful in modern organometallic chemistry due to its versatile applications in material sciences, catalysis, medicinal chemistry, and diagnostic applications. …”
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349
Development of Biodegradable Polymer Blends Based on Chitosan and Polylactide and Study of Their Properties
Published 2021-08-01Get full text
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350
Group 4 permethylpentalene complexes as polymerisation catalysts
Published 2021“…</p> <p>The thesis begins by offering an introduction to the chemistry of pentalene and its metal derivatives including ligand synthesis, organometallic chemistry and catalytic performances. The application of Cp*TiCl3 (Cp* = -C5Me5) and Pn*(H)TiCl3 (Pn*H = 5-C8Me6H) as olefin polymerisation catalysts, in both solution phase and immobilised on an insoluble methylaluminoxane (sMAO) support is described. …”
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Biocompatible Ir(III) Complexes as Oxygen Sensors for Phosphorescence Lifetime Imaging
Published 2021-05-01“…Synthesis of biocompatible near infrared phosphorescent complexes and their application in bioimaging as triplet oxygen sensors in live systems are still challenging areas of organometallic chemistry. We have designed and synthetized four novel iridium [Ir(N^C)<sub>2</sub>(N^N)]<sup>+</sup> complexes (N^C–benzothienyl-phenanthridine based cyclometalated ligand; N^N–pyridin-phenanthroimidazol diimine chelate), decorated with oligo(ethylene glycol) groups to impart these emitters’ solubility in aqueous media, biocompatibility, and to shield them from interaction with bio-environment. …”
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Modification of Biopolymers Using Palladium Oxidative Addition Complexes
Published 2024“…Other details such as the therapeutic role of key biopolymers, chemical modification strategies, palladium organometallic chemistry, and the recent developments in Pd-mediated bioconjugation are provided as well to give context for the following chapters. …”
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358
Group 4 indenyl complexes for ethylene polymerisation
Published 2015“…</p> <p><strong>Chapter Three</strong> is an account of the group 4 organometallic chemistry of the indenyl ligands from Chapter Two. …”
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359
Pentacoordinate Carbon Atoms in a Ferrocene Dication Derivative—[Fe(Si<sub>2</sub>-<i>η</i><sup>5</sup>-C<sub>5</sub>H<sub>2</sub>)<sub>2</sub>]<sup>2+</sup>
Published 2022-09-01“…Although they are hypothetical at the moment, they support the idea of “hypercoordinate metallocenes” within organometallic chemistry. Moreover, ab initio molecular dynamics simulations carried out at 298 K temperature for 2000 fs suggest that these molecules are kinetically stable.…”
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360
Synthesis and reactivity of rhenium and technetium polyaryl complexes
Published 2009Get full text
Thesis