Showing 101 - 120 results of 173 for search '"physical organic chemistry"', query time: 0.25s Refine Results
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    Rigidity and Flexibility in Rotaxanes and Their Relatives; On Being Stubborn and Easy-Going by Rachel E. Fadler, Amar H. Flood

    Published 2022-04-01
    “…In this Review, we consider the mechanical properties of rotaxanes by making use of concepts borrowed from physical organic chemistry. Rigid molecules have fewer accessible conformations with higher energy barriers while flexible molecules have more accessible conformations and lower energy barriers. …”
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    Biomimetic Models of Radical Stress and Related Biomarkers by Chryssostomos Chatgilialoglu, Carla Ferreri, Annalisa Masi, Michele Melchiorre, Anna Sansone, Michael A. Terzidis, Armida Torreggiani

    Published 2012-06-01
    “…The biomimetic modeling approach has been coupled with physical organic chemistry methodologies and knowledge of free radical reactivity. …”
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  8. 108

    Chemistry of Bridged Lactams: Recent Developments by Roman Szostak, Michal Szostak

    Published 2019-01-01
    “…In the present review, which is published as a part of the Special Issue on Amide Bond Activation, we present an overview of the recent developments in the field of bridged lactams that have taken place in the last five years and present a critical assessment of the current status of bridged lactams in synthetic and physical organic chemistry. This review covers the period from 2014 until the end of 2018 and is intended as an update to Chem. …”
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  9. 109

    Conceptual Framework of Organic Electronics by Ganna Gryn'ova, Clémence Corminboeuf

    Published 2019-04-01
    “…Despite seemingly diverse charge transport mechanisms and device set-ups, various molecular electronics systems can benefit from the same fundamental principles of physical organic chemistry, based upon the electronic structure and geometry of their molecular building blocks and the intermolecular interactions between them. …”
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    Mechanism of biomolecular recognition of trimethyllysine by the fluorinated aromatic cage of KDM5A PHD3 finger by Pieters, BJGE, Wuts, MHM, Poater, J, Kumar, K, White, PB, Kamps, JJAG, Sherman, W, Pruijn, GJM, Paton, RS, Beuming, T, Bickelhaupt, FM, Mecinovic, J

    Published 2020
    “…Here we report physical-organic chemistry studies on the recognition of the positively charged trimethyllysine by the electron-rich aromatic cage containing PHD3 finger of KDM5A. …”
    Journal article
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    Putting Chemical Knowledge to Work in Machine Learning for Reactivity by Kjell Jorner

    Published 2023-02-01
    “… Machine learning has been used to study chemical reactivity for a long time in fields such as physical organic chemistry, chemometrics and cheminformatics. …”
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    Unexpected steric hindrance failure in the gas phase F− + (CH3)3CI SN2 reaction by Xiaoxiao Lu, Chenyao Shang, Lulu Li, Rongjun Chen, Bina Fu, Xin Xu, Dong H. Zhang

    Published 2022-07-01
    “…Base-induced elimination (E2) and bimolecular nucleophilic substitution (SN2) are of significant importance in physical organic chemistry. Here, the authors show that the competing factor of E2 as opposed to steric hindrance determines the low reactivity of SN2 in the F− + (CH3)3CI reaction.…”
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    Toward Rational Understandings of α-C–H Functionalization: Energetic Studies of Representative Tertiary Amines by Wenzhi Luo, Jin-Dong Yang, Jin-Pei Cheng

    Published 2020-02-01
    “…. : Organic Chemistry; Organic Synthesis; Physical Organic Chemistry Subject Areas: Organic Chemistry, Organic Synthesis, Physical Organic Chemistry…”
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