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NMR spectroscopy of Cu(II) complexes with acrylamide and sodium acrylate copolymer and ω-amino acids
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Rigidity and Flexibility in Rotaxanes and Their Relatives; On Being Stubborn and Easy-Going
Published 2022-04-01“…In this Review, we consider the mechanical properties of rotaxanes by making use of concepts borrowed from physical organic chemistry. Rigid molecules have fewer accessible conformations with higher energy barriers while flexible molecules have more accessible conformations and lower energy barriers. …”
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Biomimetic Models of Radical Stress and Related Biomarkers
Published 2012-06-01“…The biomimetic modeling approach has been coupled with physical organic chemistry methodologies and knowledge of free radical reactivity. …”
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Chemistry of Bridged Lactams: Recent Developments
Published 2019-01-01“…In the present review, which is published as a part of the Special Issue on Amide Bond Activation, we present an overview of the recent developments in the field of bridged lactams that have taken place in the last five years and present a critical assessment of the current status of bridged lactams in synthetic and physical organic chemistry. This review covers the period from 2014 until the end of 2018 and is intended as an update to Chem. …”
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Conceptual Framework of Organic Electronics
Published 2019-04-01“…Despite seemingly diverse charge transport mechanisms and device set-ups, various molecular electronics systems can benefit from the same fundamental principles of physical organic chemistry, based upon the electronic structure and geometry of their molecular building blocks and the intermolecular interactions between them. …”
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Hidden correlation between absorption peaks in achiral carbon nanotubes and nanoribbons
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Mechanism of biomolecular recognition of trimethyllysine by the fluorinated aromatic cage of KDM5A PHD3 finger
Published 2020“…Here we report physical-organic chemistry studies on the recognition of the positively charged trimethyllysine by the electron-rich aromatic cage containing PHD3 finger of KDM5A. …”
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Putting Chemical Knowledge to Work in Machine Learning for Reactivity
Published 2023-02-01“… Machine learning has been used to study chemical reactivity for a long time in fields such as physical organic chemistry, chemometrics and cheminformatics. …”
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Unexpected steric hindrance failure in the gas phase F− + (CH3)3CI SN2 reaction
Published 2022-07-01“…Base-induced elimination (E2) and bimolecular nucleophilic substitution (SN2) are of significant importance in physical organic chemistry. Here, the authors show that the competing factor of E2 as opposed to steric hindrance determines the low reactivity of SN2 in the F− + (CH3)3CI reaction.…”
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Polarization holography in azobenzene polymeric films prepared using the new chemical method
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Simulation of Convection–Diffusion Transport in a Laminar Flow Past a Row of Parallel Absorbing Fibers
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Toward Rational Understandings of α-C–H Functionalization: Energetic Studies of Representative Tertiary Amines
Published 2020-02-01“…. : Organic Chemistry; Organic Synthesis; Physical Organic Chemistry Subject Areas: Organic Chemistry, Organic Synthesis, Physical Organic Chemistry…”
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