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Graphite-Conjugated Acids Reveal a Molecular Framework for Proton-Coupled Electron Transfer at Electrode Surfaces
Published 2020“…Proton-coupled electron-transfer (PCET) steps play a key role in energy conversion reactions. …”
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Photochemical tyrosine oxidation with a hydrogen-bonded proton acceptor by bidirectional proton-coupled electron transfer
Published 2013“…The degree of quenching depends on the strength of the base, consistent with a proton-coupled electron transfer (PCET) quenching mechanism. Comparative studies of [Re]–Y–OH and [Re]–F enable a detailed mechanistic analysis of a bidirectional PCET process.…”
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Electrochemically induced chemically reversible proton-coupled electron transfer reactions of riboflavin (vitamin B2)
Published 2013“…The electrochemical behavior of the naturally occurring vitamin B2, riboflavin (Flox), was examined in detail in dimethyl sulfoxide solutions using variable scan rate cyclic voltammetry (ν = 0.1 – 20 V s–1) and has been found to undergo a series of proton-coupled electron transfer reactions. At a scan rate of 0.1 V s–1, riboflavin is initially reduced by one electron to form the radical anion (Flrad•–) at E0f = −1.22 V versus Fc/Fc+ (E0f = formal reduction potential and Fc = ferrocene). …”
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Electrochemical ammonium-cation-assisted pyridylation of inert N-heterocycles via dual-proton-coupled electron transfer
Published 2022-05-01“…This protocol gives access to various N-fused heterocycles and bidentate nitrogen ligand compounds, through dual-proton-coupled electron transfer (PCET) and radical cross-coupling in the absence of exogenous metal and redox reagent. …”
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β-Scission by Direct Electrochemical Oxidation: Proton-coupled Electron Transfer Mechanism Dictated by Synthetic Study and Computations
Published 2023-11-01Subjects: “…electrochemical proton-coupled electron transfer…”
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Towards direct electroanalysis in seawater: understanding the role of the buffer capacity of seawater in proton-coupled electron transfer reactions
Published 2021“…The study of electrochemical reactions in seawater requires understanding of the associated coupled chemistry with the components of seawater, especially the role of the carbonate-bicarbonate buffer system in the case of proton coupled electron transfer reactions. We report the comparative paradigmatic voltammetric response of the reversible hydrogen oxidation reaction (HOR) in the absence or presence of dibasic phosphate, formate or bicarbonate. …”
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Electrocatalytic hydrogen evolution upon reduction of pyridoxal semicarbazone and thiosemicarbazone-based Cu(II) complexes
Published 2022-01-01Subjects: Get full text
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Low-Energy Electrochemical Carbon Dioxide Capture Based on a Biological Redox Proton Carrier
Published 2020-05-01Subjects: Get full text
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Catalytic cleavage and functionalization of bulky and inert Csp3–Csp3 bonds via a relayed proton-coupled electron transfer strategy
Published 2022-02-01Subjects: Get full text
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Electrochemical and Mechanistic Study of Superoxide Scavenging by Pyrogallol in <em>N</em>,<em>N</em>-Dimethylformamide through Proton-Coupled Electron Transfer
Published 2022-02-01Subjects: “…proton-coupled electron transfer…”
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The Antioxidant Activity of Quercetin in Water Solution
Published 2017-06-01Subjects: Get full text
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Additive-controlled chemoselective inter-/intramolecular hydroamination via electrochemical PCET process
Published 2024-02-01Subjects: Get full text
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Elephants in the Room, Part 2: Gymnastics for Elementary Particles
Published 2021-03-01Subjects: Get full text
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