Showing 41 - 60 results of 149 for search '"proton coupled electron transfer"', query time: 0.15s Refine Results
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    Replacing a cysteine ligand by selenocysteine in a [NiFe]-hydrogenase unlocks hydrogen production activity and addresses the role of concerted proton-coupled electron transfer in electrocatalytic reversibility by Evans, RM, Krahn, N, Weiss, J, Vincent, KA, Söll, D, Armstrong, FA

    Published 2024
    “…The mechanism of [NiFe]-hydrogenases includes a long-range proton-coupled electron-transfer process involving a specific Ni-coordinated cysteine and the carboxylate of a nearby glutamate. …”
    Journal article
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    Proton coupled electron transfer in tri-molecular system involving 7-Methylbenzo [a] pyrene and different phenol–base pairs: A case study for determining hydrogen bonding equilibrium constant by Venkatesan Munisamy, Prakriti Ranjan Bangal

    Published 2023-12-01
    “…Photo induced proton-coupled electron transfer (PCET) reactions comprehend the concerted transfer of an electron from donor to acceptor and a proton along the hydrogen bonded axis in same time scale. …”
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    Article
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    Use of 2,3,5-F[subscript 3]Y-beta 2 and 3-NH[subscript 2]Y-alpha 2 To Study Proton-Coupled Electron Transfer in Escherichia coli Ribonucleotide Reductase by Seyedsayamdost, Mohammad R., Yee, Cyril S., Stubbe, JoAnne

    Published 2012
    “…The oxidation is proposed to involve a hopping mechanism through aromatic amino acids (Y[subscript 122] → W[subscript 48] → Y[subscript 356] in β2 to Y[subscript 731] → Y[subscript 730] → C[subscript 439] in α2) and reversible proton-coupled electron transfer (PCET). Recently, 2,3,5-F[subscript 3]Y (F[subscript 3]Y) was site-specifically incorporated in place of Y[subscript 356] in β2 and 3-NH[subscript 2]Y (NH[subscript 2]Y) in place of Y[subscript 731] and Y[subscript 730] in α2. …”
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    Extent of carbon nitride photocharging controls energetics of hydrogen transfer in photochemical cascade processes by Oleksandr Savateev, Karlo Nolkemper, Thomas D. Kühne, Vitaliy Shvalagin, Yevheniia Markushyna, Markus Antonietti

    Published 2023-11-01
    “…Strong stabilization of electrons by ammonium cations makes proton-coupled electron transfer uphill, and affords air-stable persistent carbon nitride radicals. …”
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    Article
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    Coordination-induced O-H/N-H bond weakening by a redox non-innocent, aluminum-containing radical by Soumen Sinhababu, Roushan Prakash Singh, Maxim R. Radzhabov, Jugal Kumawat, Daniel H. Ess, Neal P. Mankad

    Published 2024-02-01
    “…Because the O-H and N-H bonds are quite strong (>100 kcal/mol), it is necessary to identify substances that dramatically weaken these bonds to facilitate proton-coupled electron transfer processes required for energy conversion. …”
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    Article