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Polyyne rotaxanes
Published 2014“…<p>This thesis describes the synthesis of polyyne rotaxanes and an investigation of their excited state photophysical properties. …”
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Cyclodextrin-based rotaxanes
Published 2002“…<p>A series of novel [2]rotaxanes of general formula 1 has been synthesised, exploiting the hydrophobic effect to cause binding inside α- or β-cyclodextrin cavities, and making use of Suzuki coupling to stopper the rotaxane.…”
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Synthesis of polyyne rotaxanes.
Published 2012“…Active-metal templating has been used to synthesize rotaxanes consisting of a phenanthroline-based macrocycle threaded around a C8, C12, or C20 polyyne chain. …”
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Azo-dye rotaxanes
Published 1997“…The dumbbell-shaped dyes were synthesized inside α-cyclodextrin, β-cyclodextrin, or a cyclophane to yield stable rotaxanes.…”
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Anion-templated rotaxane formation.
Published 2002“…This is interpreted as a function of the anion template used to create the [2]rotaxane superstructure.…”
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Mechanical Chirality of Rotaxanes: Synthesis and Function
Published 2020-01-01Subjects: Get full text
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Stretchable poly[2]rotaxane elastomers
Published 2024-03-01“…Herein, we report stretchable poly[2]rotaxane elastomers (PREs) which integrate numerous mechanical bonds in the polymeric backbone to boost macroscopic mechanical properties. …”
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Anion-templated assembly of [2]rotaxanes.
Published 2006“…Anion templation is used to develop a general method for rotaxane synthesis. The anion-templated synthesis of three new [2]rotaxanes containing positively charged pyridinium axles and neutral isophthalamide macrocyclic components is described. …”
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Porphyrin-polyyne [3] and [5]rotaxanes
Published 2017“…Porphyrin–polyyne [3]- and [5]rotaxanes have been synthesized by condensing aldehyde–rotaxanes with pyrrole or dipyrromethane. …”
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Lanthanide cation-templated synthesis of rotaxanes.
Published 2013“…Stoppering of the pseudo-rotaxane assembly allows for preparation of the [2]rotaxane.…”
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Porphyrin-functionalised rotaxanes for anion recognition.
Published 2012“…The synthesis and anion-recognition properties of two new porphyrin-functionalised [2]rotaxane host molecules are described. The rotaxane compounds are prepared via a chloride-anion-templated clipping strategy. (1)H NMR titration experiments demonstrate that the rotaxane host systems exhibit high binding affinities and general selectivities for chloride anions in DMSO-d(6) or CDCl(3)/CD(3)OD solvent systems. …”
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Anion-templated assembly of [2]rotaxanes
Published 2006“…Anion templation is used to develop a general method for rotaxane synthesis. The anion-templated synthesis of three new [2]rotaxanes containing positively charged pyridinium axles and neutral isophthalamide macrocyclic components is described. …”
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Heteroditopic Rotaxanes and Catenanes for Ion Pair Recognition
Published 2023-01-01Subjects: “…rotaxane…”
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Rotaxane: a switching element in molecular electronics
Published 2010-12-01“…Reversible structural change occurring in rotaxane due to external stimulus is described and its application in nanorecording is also studied. …”
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Rotaxanes capable of recognising chloride in aqueous media.
Published 2010“…A new, versatile chloride-anion-templating synthetic pathway is exploited for the preparation of a series of eight new [2]rotaxane host molecules, including the first sulfonamide interlocked system. (1)H NMR spectroscopic titration investigations demonstrate the rotaxanes' capability to selectively recognise the chloride anion in competitive aqueous solvent media. …”
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A gold-nanoparticle stoppered [2]rotaxane
Published 2018“…Taking advantage of recent progress in the preparation of supramolecular complexes of the cucurbit[7]uril (CB[7]) macrocycle, we have prepared a bis-thiol functionalised pseudo-rotaxane that enables us to prepare a AuNP-stoppered [2]rotaxane in water. …”
Journal article