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Phylogenetic Diversity in the Macromolecular Composition of Microalgae
Published 2017“…The elemental stoichiometry of microalgae reflects their underlying macromolecular composition and influences competitive interactions among species and their role in the food web and biogeochemistry. …”
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162
Direct Observation of Intermediates Involved in the Interruption of the Bischler–Napieralski Reaction
Published 2017“…The reversible formation of diiminium ether intermediates was studied, providing insight into divergent mechanistic pathways as a function of the steric environment of the amide substrate and stoichiometry of reagents. Importantly, when considering base additives during electrophilic amide activation, more hindered α-quaternary tertiary lactams require the use of non-nucleophilic pyridine additives in order to avoid deactivation via a competing desulfonylation reaction. …”
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163
Co-optimization of SnS absorber and Zn(O,S) buffer materials for improved solar cells
Published 2017“…Solar cells were further optimized by varying the stoichiometry of Zn(O,S) and the annealing conditions of SnS. …”
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164
Enhanced transport in transistor by tuning transition-metal oxide electronic states interfaced with diamond
Published 2021“…Regrettably, field-effect transistor operation based on this surface doping has been so far disappointing due to fundamental material obstacles such as (i) carrier scattering induced by nonhomogeneous morphology of TMO surface acceptor layer, (ii) stoichiometry changes caused by typical transistor fabrication process, and (iii) carrier transport loss due to electronic band energy misalignment. …”
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165
An Improved Multi-parametric Programming Algorithm for Flux Balance Analysis of Metabolic Networks
Published 2021“…These improvements are especially effective for metabolic networks because their stoichiometry matrices are generally sparse; thus, fast and efficient algorithms from sparse linear algebra can be leveraged to compute generalized inverses and null-space bases. …”
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166
Active Tuning of Optical Constants in the Visible–UV: Praseodymium‐Doped Ceria—a Model Mixed Ionic–Electronic Conductor
Published 2022“…Mixed ionic–electronic conductors offer chemical and electrical means for active tuning of their optical constants, e.g., with variations in oxygen non-stoichiometry in Pr0.1Ce0.9O2–δ, enabling implementation of adaptive thin film optical devices. …”
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167
Sudden Collapse of Magnetic Order in Oxygen-Deficient Nickelate Films
Published 2022“…In this study, we explored the use of oxygen stoichiometry as an alternative pathway to modify the coupled magnetic and electronic ground state in the family of rare earth nickelates (RENiO_{3-x}). …”
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168
Distributions and perturbations of the marine dissolved cobalt cycle in a changing ocean
Published 2023“…In the North Pacific, elevated cobalt stoichiometries among phytoplankton were linked to nitrogen, iron and phosphate stress protein biomarkers at the boundaries of oceanographic provinces and upwelling zones, providing insight into the flexibility of cobalt stoichiometry. …”
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169
Temporal gene expression and regulation in T4 phage
Published 2024“…Collectively, transcriptional and translational controls lead to precisely tuned protein synthesis rates during infection, as exemplified by the phenomenon that components of T4 protein complexes are synthesized according to their stoichiometry— a principle that has been observed in organisms during steady-state growth. …”
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170
Synthetic incoherent feedforward circuits show adaptation to the amount of their genetic template
Published 2013“…Natural and synthetic biological networks must function reliably in the face of fluctuating stoichiometry of their molecular components. These fluctuations are caused in part by changes in relative expression efficiency and the DNA template amount of the network-coding genes. …”
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171
(Invited) Role of Chemical Heterogeneities on Oxygen Reduction Kinetics on the Surface of Thin Film Cathodes
Published 2013“…We investigated the effects of annealing and A-site stoichiometry on the surface heterostructures at (La0.8Sr0.2)yMnO3 (LSM, y≤1) dense thin films. …”
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172
Non-Gated Laser Induced Breakdown Spectroscopy Provides a Powerful Segmentation Tool on Concomitant Treatment of Characteristic and Continuum Emission
Published 2014“…While use of such a system introduces substantive continuum background in the spectral dataset, we show that appropriate treatment of the continuum and characteristic emission results in accurate discrimination of pharmaceutical formulations of similar stoichiometry. Specifically, our results suggest that near-perfect classification can be obtained by employing suitable multivariate analysis on the acquired spectra, without prior removal of the continuum background. …”
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173
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174
Characterization of a Fe/Y[subscript 2]O[subscript 3] metal/oxide interface using neutron and x-ray scattering
Published 2015“…We find evidence of gradual variations in stoichiometry and magnetization across a Fe/Y[subscript 2]O[subscript 3] metal/oxide heterophase interface using neutron and x-ray reflectometry. …”
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175
Factors that Influence Cation Segregation at the Surfaces of Perovskite Oxides
Published 2015“…Motivated by those results, here we investigated the effects of A-site stoichiometry in La0.8Sr0.2MnO3 (LSM) thin films on the surface chemistry and electrochemical activity. …”
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176
Crystallographic structure of the turbine C-ring from spinach chloroplast F-ATP synthase
Published 2014“…The chloroplast F-ATP synthase (CF1FO-ATP synthase) of plants is integrated into the thylakoid membrane via its FO-domain subunits a, b, b’ and c. Subunit c with a stoichiometry of 14 and subunit a form the gate for H+-pumping, enabling the coupling of electrochemical energy with ATP synthesis in the F1 sector. …”
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Journal Article -
177
Characterization of light and heavy hydrated magnesium carbonates using thermal analysis
Published 2014“…Results show that variations exist within the microstructure and decomposition patterns of the two groups of HMCs, which do not exactly fit into the fixed stoichiometry of the known HMCs in the MgO–CO2–H2O system. …”
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178
Vancomycin determination by disrupting electron-transfer in a fluorescence turn-on squaraine – anthraquinone triad
Published 2020“…When Van is added, the antibiotic molecules bind with high affinity to the -d-Ala-d-Ala ligands in a 2:1 stoichiometry (Van:triad), resulting in fluorescence recovery that is as high as 30 times (“on”-state). …”
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179
Inducing alternating nanoscale rectification in a dielectric material for bidirectional-trigger artificial synapses
Published 2020“…This work demonstrates that the nanoscale stoichiometry in transition metal oxides can be triggered to form asymmetric cationlike vacancy distributions that yield dynamically toggled current rectifying properties. …”
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180
3D reconstruction and flexibility of the hybrid engine Acetobacterium woodii F-ATP synthase
Published 2020“…The Na+-translocating F1FO ATP synthase from Acetobacterium woodii (AwF-ATP synthase) with a subunit stoichiometry of α3:β3:γ:δ:ε:a:b2:(c2/3)9:c1 represents an evolutionary path between ATP-synthases and vacuolar ATPases, by containing a heteromeric rotor c-ring, composed of subunits c1, c2 and c3, and an extra loop (γ195-211) within the rotary γ subunit. …”
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Journal Article