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121
Bond order resolved 3d 5/2 and valence band chemical shifts of Ag surfaces and nanoclusters
Published 2013“…It is clarified that the globally positive energy shifts originate from the undercoordination-induced Goldschmidt–Pauling bond contraction and the associated local quantum entrapment and the heterocoordination-induced bond nature alteration at the particle–substrate interfaces. …”
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Journal Article -
122
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123
Binuclear oxidative addition of Sb-Cl bonds : a facile synthetic route to main group transition element clusters and rings
Published 2014“…Binuclear oxidative addition of Sb–Cl bonds with the clusters Os3(CO)11(NCCH3), 1, or Os3(CO)10(NCCH3)2, 2, was found to be an effective synthetic route to organometallic clusters and rings containing μ2-SbPh2 or μ3-SbPh moieties. …”
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Journal Article -
124
Catalytic asymmetric diarylphosphine addition to α-diazoesters for the synthesis of P-stereogenic phosphinates via P*-N bond formation
Published 2022“…The asymmetric catalytic P-H addition of racemic secondary phosphines to electrophilic α-diazoesters via P*-N bond formation is disclosed for the first time. Interaction between the diazoester and the palladium catalyst resulted in the unusually enhanced electrophilic ability of the terminal nitrogen in the diazo functionality, as opposed to the commonly expected formation of a metal carbene by nitrogen elimination. …”
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Journal Article -
125
Lewis acid-catalyzed reactions of alcohol pro-electrophiles as novel strategies for C-C and C-N bond formation
Published 2010“…Part II is aimed at exploring new strategies for C-C bond formation employing alcohols as pro-electrophiles. …”
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Thesis -
126
The advancement of NHC catalyzed C-C bond formation : application towards chromone synthesis, C-Glycosylation and total synthesis
Published 2012“…The discovery of novel and efficient synthetic methods for carbon–carbon bond formation reactions remains the biggest challenge towards the development of sustainable chemical transformations. …”
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Thesis -
127
Facile access to chiral ketones through metal-free oxidative C-C bond cleavage of aldehydes by O2
Published 2012“…Giving the metal the boot: The title reaction provides facile access to functionalized chiral ketones from chiral α,α′-disubstituted aldehydes in the presence of molecular oxygen (see scheme). The CC bond-cleavage approach offers an alternative or better method relative to the typical bond-forming strategies used in synthesizing chiral ketones.…”
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Journal Article -
128
EBB202 CRYTALLOGRAPHY AND BONDING IN SOLIDS [KRISTALOGRAFI DAN IKATAN DALAM PEPEJAL] SEM 1 SA 2022/2023
Published 2022Get full text
Teaching Resource -
129
The Temperature Dependence of Hydrogen Bonds Is More Uniform in Stable Proteins: An Analysis of NMR h3JNC′ Couplings in Four Different Protein Structures
Published 2024“…The h3JNC′ couplings are transmitted through hydrogen bonds and their sizes are correlated to hydrogen bond lengths. …”
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130
Experimental and numerical investigation of adhesively bonded kfrp/steel double strap joints incorporating eggshell powder-toughened epoxy adhesive
Published 2024“…Testing series includes variations of KFRP bond length, KFRP thickness and eggshell filler volume fractions. …”
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Article -
131
Public's perception of the bus service standards in Singapore.
Published 2008Get full text
Final Year Project (FYP) -
132
Retarding effect of concentration of cementation solution on biocementation of soil
Published 2022Subjects: Get full text
Journal Article -
133
Cobalt-Catalyzed, Imine-Directed Olefin Hydroarylation under Grignard-Free Conditions
Published 2017Subjects: Get full text
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Journal Article -
134
Ortho-allylation of 1-arylpyrazoles with allyl phenyl ether via iron-catalyzed C-H bond activation under mild conditions
Published 2014“…The reaction may proceed via iron-catalyzed ortho C[BOND]H activation to form a metallic intermediate, which then reacts with the allyl ether in a γ selective fashion.…”
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Journal Article -
135
Full-Dimensional Quantum Dynamical Studies of the Cl + HOD → HCl/DCl + OD/OH Reaction: Bond Selectivity and Isotopic Branching Ratio
Published 2016“…Our results confirm the experimental observed vibrationally promoted bond cleavage, in which the breaking of the OH(OD) bond is strongly enhanced by the OH(OD) excitation. …”
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Journal Article -
136
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137
σ-Bonded organochromium(III) complexes. 3. decomposition in acid solution of chromium(III) complexes containing pyridylmethyl and polydentate amine ligands
Published 1986“…The activation parameters and product studies are in support of a homolytic pathway for the Cr-C bond cleavage.…”
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138
Captions from Book Marks, a display held in Blackwell Hall, Weston Library, 24 August - 15 December 2024
Published 2024“…<br> Recent conservation work on Mary Whitehouse’s diaries has inspired two of our conservators – Alice Evans and Andrew Honey – to look for non-textual marks in our collections. …”
Conference item -
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Enlightening of the low-dimensional high-TC superconductivity: bond contraction and electron dual polarization [低维高温超导的启示: 键收缩与电子双重极化]
Published 2022Subjects: Get full text
Journal Article