Diastereoselective hydroalkylation of aryl alkenes enabled by remote hydride transfer by Gandamana, Dhika Aditya, Gagosz, Fabien, Chiba, Shunsuke

“…Leveraging of 1,5-hydride shift enabled diastereoselective hydroalkylation of aryl alkenes, allowing for construction of consecutive vicinal stereogenic centers in a single process. The transformation is triggered by electrophilic alkylation of aryl alkenes with in-situ generated carbocations, that is followed by diastereoselective 1,5-hydride shift to the resulting benzylic carbocation through a rigid 6-membered ring chair-like transition state.…”
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Disruption of the Broadcast by Packer, Randall

“…And conversely, with the emerging tools of the Web, self-publishing blogs, and social media, artists are increasingly engaged in reporting news and opinion, becoming their own media outlets, distribution centers, and independent news feeds. In this sense, the new media artist uses technological means to take control of media information and broadcast it according to their own perspective.…”
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Tsunami hazard from the subduction megathrust of the South China Sea : Part I. source characterization and the resulting tsunami by Megawati, Kusnowidjaja, Shaw, Felicia, Sieh, Kerry, Huang, Zhenhua, Wu, Tso-Ren, Lin, Yunung, Tan, Soon Keat, Pan, Tso-Chien

“…Results indicate that this megathrust poses a risk of devastating tsunami for the Philippines, southern China, Vietnam and other population centers bordering the South China Sea.…”
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Is the rule-based order in AI dead, or is still kicking? [Conference paper] by Vassilev, Vassil

“…The position of this article is that combining the classical rule-based approach from the early days of AI with more recent developments in AI, such as data-focused machine learning and utility-based reinforcement learning, as well as utilization of the recent technological developments on the cloud and at data centers can be beneficial for widening the real-world application of AI. …”
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Synthesis of heavy cyanide analogs for the design of novel Prussian blue analogs by Yang, E

“…By analogy with classic Grignard reagents, magnesium(II) cyaphide complexes can be used to transfer the cyaphide ion to other metal centers. The synthesis of cyaphide-containing main group and transition metal complexes by cyaphide transfer is detailed. …”

Universal resilience patterns in labor markets by Moro, Esteban, Frank, Morgan R., Pentland, Alex, Rutherford, Alex, Cebrian, Manuel, Rahwan, Iyad

“…Cities are the innovation centers of the US economy, but technological disruptions can exclude workers and inhibit a middle class. …”
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Additive manufacturing: DED process parameters optimization via experiments (E) by Tong, Gao Rui

“…Directed Energy Deposition (DED), a prominent technique within additive manufacturing, is particularly valued for its efficiency in repairing and fabricating components with precision, which is integral in sectors like aerospace, healthcare, and defense. This investigation centers on 316L stainless steel, chosen for its robust tensile strength and resistance to corrosion. …”
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TiO2 thin films by APCVD for photocatalytic applications by Chua, Chin Sheng

“…Other modifications suffered from a loss of photoactivity cause primarily by the introduction of recombination centers and increased in grain size.…”
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Pharmaceutical clinical trial supply chain : modelling and analysis by Tan, Dennis Wei Jie

“…Clinical trials form the work process supply chain where patients receive medical supplies in which drugs are manufactured, packed and shipped globally to distribution centers (DCs) before distributing to clinical trial sites. …”
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Is the rule-based order in AI dead, or is still kicking? by Vassilev, Vassil

“…The position of this article is that combining the classical rulebased approach from the early days of AI with more recent developments in AI, such as data-focused machine learning and utility-based reinforcement learning, as well as utilization of the recent technological developments on the cloud and at data centers can be beneficial for widening the realworld application of AI. …”
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A two-part mixed-effects model for analyzing clustered time-to-event data with clumping at zero by Zhao, Jian, Zhao, Yun, Xiang, Liming, Khanal, Vishnu, Binns, Colin W, Lee, Andy H.

“…Furthermore, subjects are often clustered within hospitals, communities or health service centers, resulting in correlated observations. The framework of the two-part model has been developed and utilized widely to analyze semi-continuous data or count data with excess zeros, but its application to clustered time-to-event data with clumping at zero remains sparse.…”
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The effects of processing conditions on the morphology of single conjugated polymers. by Yeo, Hui Lin.

“…Spun-cast single chains were largely found to give neat intensity traces exhibiting discrete emission levels and clear off-states, suggesting a compact and collapsed disordered conformation favoring efficient energy funneling to one or a few low-energy exciton traps. These emissive centers of the collapsed chain were proposed to be intrachain aggregates consisting of closely π-stacked segments, therefore possessing weak oscillator strength and an extended radiative lifetime. …”
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Epi-microRNA mediated metabolic reprogramming counteracts hypoxia to preserve affinity maturation by Nakagawa, R, Llorian, M, Varsani-Brown, S, Chakravarty, P, Camarillo, JM, Barry, D, George, R, Blackledge, NP, Duddy, G, Kelleher, NL, Klose, RJ, Turner, M, Calado, DP

“…To increase antibody affinity against pathogens, positively selected GC-B cells initiate cell division in the light zone (LZ) of germinal centers (GCs). Among these, higher-affinity clones migrate to the dark zone (DZ) and vigorously proliferate by utilizing energy provided by oxidative phosphorylation (OXPHOS). …”

Undang-undang rawatan dan pemulihan dadah dari sudut pandangan global: Suatu perbandingan by Ahmad, Rusniah, Khalil, Samihah, Abdullah, Siti Alida John, A. Rahman, Aspalella, Md Isa @ Yusuff, Yusramizza, Azrae, Ahmad Nasyran, Mohd Shariff, Roos Niza

“…Viewed from the aspects of entrance into drug rehabilitation centers and arrests made on drug related offences, the problems pertaining to drug abuse and addiction has attracted the attention of authorities everywhere and many national legislative bodies have taken steps by passing legislation in the aspects of drug treatment and rehabilitation in a bid to address this social illness. …”
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Disparity dashboards: an evaluation of the literature and framework for health equity improvement by Gallifant, Jack, Kistler, Emmett Alexander, Nakayama, Luis Filipe, Zera, Chloe, Kripalani, Sunil, Ntatin, Adelline, Fernandez, Leonor, Bates, David, Dankwa-Mullan, Irene, Celi, Leo Anthony

“…In addition, pay-for-equity initiatives, such as those proposed by the Centers for Medicare and Medicaid, will require the reporting of health outcomes across subgroups over time. …”
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Site-Selective Anion Exchange in a Palladophosphorane by Khuichad, Nichakan

“…Treatment with phenol resulted in substitution of the chloride at the P center while the chloride of the Pd stayed intact, giving complex PdClL superscript OPh. …”
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Expanding the structural diversity of discrete polymers accessible through iterative exponential growth by Khokhlov, Khrystofor

“…The configurations of stereogenic centers in IEG-mer backbones are defined by the starting material (R or S epichlorohydrin) and can be further controlled by combining different stereoisomers in desired fashion. …”
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Urban Big Data: City Management and Real Estate Markets by Barkham, Richard, Bokhari, Sheharyar, Saiz, Albert

“…They are likely to make denser urban centers more attractive, but they are also bound to make suburban or exurban locations more accessible.…”
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Multiplexed CRISPR/CAS9‐mediated engineering of pre‐clinical mouse models bearing native human B cell receptors by Wang, Xuesong, Ray, Rashmi, Kratochvil, Sven, Melzi, Eleonora, Lin, Ying‐Cing, Giguere, Sophie, Xu, Liling, Warner, John, Cheon, Diane, Liguori, Alessia, Groschel, Bettina, Phelps, Nicole

“…We demonstrate that B cells from these mice are fully functional: upon transfer to congenic, wild type mice at controlled frequencies, such B cells can be primed by eOD‐GT8 60mer, a germline‐targeting immunogen currently in clinical trials, recruited to germinal centers, secrete class‐switched antibodies, undergo somatic hypermutation, and differentiate into memory B cells. …”
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Investigation on chemical protease, nuclease and catecholase activity of two copper complexes with flexidentate Schiff base ligands by Das, Mriganka, Kundu, Bidyut Kumar, Tiwari, Ritudhwaj, Mandal, Poulami, Nayak, Debasis, Ganguly, Rakesh, Mukhopadhyay, Suman

“…Structural analysis reveals that 1 and 2 are monomeric Cu(II) complex consisting of penta and tetra coordinated Cu(II) centers, respectively. Screening tests were conducted to quantify the binding ability of complexes (1 and 2) towards BSA and DNA as well as the protease and nuclease activity of these complexes using gel electrophoresis technique. …”
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