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    Solid-State P NMR, Far-IR, and Structural Studies on Two-Coordinate (Tris(2,4,6-trimethoxyphenyl)phosphine)copper(I) Chloride and Bromide by Bowmaker, Graham A., Cotton, John D., Healy, Peter C., Kildea, John D.

    Published 1989
    “…The reactions of acetonitrile solutions of copper(I) chloride, CuCl, and copper(I) bromide, CuBr, with the sterically hindered, highly basic tertiary phosphine ligand tris(2,4,6-trimethoxyphenyl)phosphine [=P(2,4,6)3] have been shown to form 1:1 monomeric adducts, [P(2,4,6)3 cux],The two compounds are isomorphous, crystallizing in the tetragonal space group P42. for the chloride, a = 15.237 (4) A, c = 12.373 (3) A, Z = 4, and R = 0.029 for 2339 “observed” (/ > 3<r(/)) reflections, while for the bromide, a - 15.312 (8) A, c = 12.457 (6) A, Z = 4, and R = 0.052 for 2148 “observed” reflections. …”
    Article
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