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  1. 161

    Azadihomocorannulene as a heptagon-embedded diradicaloid by Hamamoto, Yosuke, Wang, Weifan, Li, Yongxin, Ito, Shingo

    Published 2025
    “…The synthesis was achieved through a mechanochemical C(sp2)-H/C(sp3)-H coupling in the presence of sodium as a key reaction. Electron spin resonance studies revealed that the neutral azapentabenzodihomocorannulene adopts a singlet diradical (diradicaloid) ground state with a small singlet-triplet energy gap of 2.1 kcal/mol. …”
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    Journal Article
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    An endergonic synthesis of single Sondheimer–Wong diyne by local probe chemistry by Kawai, Shigeki, Sang, Hongqian, Kantorovich, Lev, Takahashi, Keisuke, Nozaki, Kyoko, Ito, Shingo

    Published 2023
    “…Recent advances in scanning probe microscopy on surface enable not only direct observation of molecular structures but also local probe reactions, in which unstable short-lived products have been synthesized and analyzed. …”
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    Journal Article