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    Expedient synthesis of E-hydrazone esters and 1H-indazole scaffolds through heterogeneous single-atom platinum catalysis by Liu, Cuibo, Chen, Zhongxin, Yan, Huan, Xi, Shibo, Yam, Kah Meng, Gao, Jiajian, Du, Yonghua, Li, Jing, Zhao, Xiaoxu, Xie, Keyu, Xu, Haisen, Li, Xing, Leng, Kai, Pennycook, Stephen J., Liu, Bin, Zhang, Chun, Koh, Ming Joo, Loh, Kian Ping

    Published 2020
    “…Here, we show that Pt single atoms anchored on defect-rich CeO2 nanorods (Pt1/CeO2), in conjunction with the alcoholysis of ammonia borane, promotes exceptionally E-selective hydrogenation of α-diazoesters to afford a wide assortment of N-H hydrazone esters with an overall turnover frequency of up to 566 hours-1 upon reaction completion. …”
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    Journal Article
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