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    Diboron-carbene complexes derived from a geminal dianion by Fan, Jun, Yang, Ming-Chung, Hooper, Thomas J. N., Su, Ming-Der, So, Cheuk-Wai

    Published 2022
    “…The lability of the boron-carbene bond was found in the reaction of the sterically hindered thiophosphinoyl iminophosphoranyl geminal dianion [C(PPh2NAr)(PPh2S)]2- (Ar = 2,6-iPr2C6H3) with B2Br4(SMe2)2 in toluene to form the diboron-carbene complex 4, where one boron center bonds with two methanediides, leading to an allyl anionic-like C═B←C2- electronic structure, while another boron center is stabilized by two imino substituents. …”
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    Journal Article
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