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981
Electronic structure of paramagnetic transition metal complexes
Published 2017“…In Chapter 3, we address the question of redox-dependent spin transitions in triangular iron complexes. Experiments have shown that one-electron reduction of a pyrazolate-bridged Fe<sup>III</sup><sub>3</sub> cluster drives a transition from high- to low-spin configurations at all three metal centres. …”
Thesis -
982
Functional mesoporous silica nanoparticles for photothermal-controlled drug delivery in vivo
Published 2013“…Remote-controlled movement of the α-cyclodextrin ring (green) upon trans–cis isomerization of the azobenzene axle (red) enables the loading and release of drugs on demand (see scheme). …”
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Journal Article -
983
First cycle voltage hysteresis in Li-rich 3d cathodes associated with molecular O2 trapped in the bulk
Published 2020“…Resonant inelastic X-ray scattering and 17O magic angle spinning NMR spectroscopy show that molecular O2, rather than O22−, forms within the particles on the oxidation of O2− at 4.6 V versus Li+/Li on charge. …”
Journal article -
984
Thickness effect of nickel oxide thin films on associated solution-processed write-once-read-many-times memory devices
Published 2020“…With self-prepared nickel acetate based solution, NiO thin films with different thicknesses have been fabricated by spin coating followed by thermal annealing. By forming a two-terminal Ag/NiO/ITO structure on glass, write-once-read-many-times (WORM) memory devices are realized. …”
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Journal Article -
985
Efficient generation of an array of single silicon-vacancy defects in silicon carbide
Published 2018“…Color centers in silicon carbide have increasingly attracted attention in recent years owing to their excellent properties such as single-photon emission, good photostability, and long spin-coherence time even at room temperature. As compared to diamond, which is widely used for hosting nitrogen-vacancy centers, silicon carbide has an advantage in terms of large-scale, high-quality, and low-cost growth, as well as an advanced fabrication technique in optoelectronics, leading to prospects for large-scale quantum engineering. …”
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Journal Article -
986
Crystalline boron-linked tetraaminoethylene radical cations
Published 2018“…X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B2N4C2 skeleton and the spin density mainly resides on the carbon and boron atoms.…”
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Journal Article -
987
Studies on the synthesis of bisindole Aspidosperma alkaloids
Published 2024“…We envisioned rapid access to these natural alkaloids from a common, symmetrical precursor assembled by methylenation of a D-ring-oxidized variant of the structurally related natural product (–)-deoxoapodine. …”
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Thesis -
988
Insight into actin organization and function in cytokinesis from analysis of fission yeast mutants
Published 2014“…Some of these cytokinesis mutants helped in dissecting the function of specific actin structures during ring assembly. Further genetic analysis of some of these actin mutants revealed multiple genetic interactions with mutants previously known to affect the actomyosin ring assembly. …”
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Journal Article -
989
Lewis acid-catalyzed reactions of alcohol pro-electrophiles as novel strategies for C-C and C-N bond formation
Published 2010“…Chapter IV detailed the gold-catalyzed tandem amination/ring expansion of cyclopropyl methanols with sulfonamides as an expedient route to pyrrolidines. …”
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Thesis -
990
A highly strained Al-Al σ-bond in dianionic aluminum analog of oxirane for molecule activation
Published 2022“…Herein, we report the first synthesis of a dianionic dialane(6) 2 based on the Al2O three-membered ring scaffold, namely, an aluminum analog of oxirane. …”
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Journal Article -
991
Challenges and applications to operando and in situ TEM imaging and spectroscopic capabilities in a cryogenic temperature range
Published 2022“…Such studies are promising for studying the pinning of the ferroelectric and magnetic domains versus temperature, spin-polarized current, and externally applied magnetic field to better manipulate the domain walls. …”
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Journal Article -
992
Narrowband Searches for Continuous and Long-duration Transient Gravitational Waves from Known Pulsars in the LIGO-Virgo Third Observing Run
Published 2024“…Isolated neutron stars that are asymmetric with respect to their spin axis are possible sources of detectable continuous gravitational waves. …”
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Article -
993
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994
Ultra-high bit rate optical soliton communication
Published 2008“…We start the project by first investigating the building blocks of active mode-locked erbium doped fiber ring soliton laser, which includes the laser cavity design, gain medium and pump source, filter and modulator designs. …”
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Research Report -
995
Highly sensitive ferromagnetic resonance measurement systems for magnetic thin films
Published 2013“…We have designed and optimized a vector network analyzer ferromagnetic resonance measurement system that characterizes the spin dynamics and Gilbert damping parameters of thin ferromagnetic film sample. …”
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Final Year Project (FYP) -
996
Exploring New Frontiers in High Energy Physics: Boosted Resonances Decaying To Quarks, Foundation Models, and Heterogeneous Computing at the CMS Experiment
Published 2024“…This analysis presents the most sensitive limits for new spin-1 bosons coupling universally to quarks and spin-0 bosons coupling preferentially to heavier quarks. …”
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Thesis -
997
Minimal power manoeuvring techniques in nano-satellites
Published 2016“…For the second design, a 6⁰ ramp angle & 2.389cm ramp length can spin a nano-satellite of the same dimensions and mass by 1.5⁰/s as well. …”
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Final Year Project (FYP) -
998
Cobalt-catalyzed regio- and diastereoselective formal [3 + 2] cycloaddition between cyclopropanols and allenes
Published 2021“…A cobalt-diphosphine catalyst has been found to promote a formal [3 + 2] cycloaddition reaction between a cyclopropanol and an allene via cyclopropanol ring opening, which affords a 3-alkylidenecyclopentanol derivative with high regio- and diastereoselectivities. …”
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Journal Article -
999
Magneto-optical response in bimetallic metamaterials
Published 2018“…We demonstrate resonant Faraday polarization rotation in plasmonic arrays of bimetallic nano-ring resonators consisting of Au and Ni sections. …”
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Journal Article -
1000
The burden of consciousness : object animism in children's literature
Published 2009“…Animals, plants and objects are often anthropomorphized to delightful effect in children’s literature while adult depictions of the inanimate coming alive almost always occur in the genres of science fiction and horror and have had a much less positive spin. This essay argues that these negative evocations do indeed spill over into children’s texts, manifesting in the common motifs that appear in stories involving object animism, and that enlivened objects are furthermore, representations of Julia Kristeva’s concept of abjection.…”
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Final Year Project (FYP)