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141
Integrated rocksalt-polyanion cathodes with excess lithium and stabilized cycling
Published 2024“…Following design rules for cation filling and ordering, we demonstrate the bulk incorporation of polyanion groups into the rocksalt lattice. …”
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Article -
142
Positive effect of incorporating Er0.4Bi1.6O3 on the performance and stability of La2NiO4+δ cathode
Published 2020“…The results show the presence of ESB remarkably reduces the contact resistance at the electrode/electrolyte interface and enhances the electrocatalytic activity and cation stability of LNO. The cell with the LNO-ESB cathode generates a peak power density of 852 mW cm-2 at 750°C with reasonable operating stability over 200 h. …”
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Journal Article -
143
Structural Study of the Apatite Nd 8 Sr 2 Si 6 O...
Published 2016“…This comprehensive crystallochemical description of Nd8Sr2Si6O26 provides a baseline to quantify the efficacy of cation vacancies, oxygen superstoichiometry, and symmetry modification for promoting oxygen-ion mobility.…”
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Journal Article -
144
Defective materials for CO₂ photoreduction: from C₁ to C₂₊ products
Published 2023“…Different types of defects are employed to tailor the electronic structure, atomic coordination configuration, carrier concentration or electrical conductivity for CO2 photoreduction, namely anion vacancies, cation vacancies, vacancy pairs, planar defects and volume defects. …”
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Journal Article -
145
Accelerated synthesis of Li(Ni0.8Co0.1Mn0.1)O2 cathode materials using flame-assisted spray pyrolysis and additives
Published 2024“…Both in situ thermal X-ray diffraction (XRD) and ex situ XRD revealed that urea addition weakened the sensitivity of crystallization and cation mixing to calcination conditions. As a result, with only 20 min of calcination at 875 °C and without any preheating and ramping steps, the NCM811 sample showed an ordered layered structure and comparable electrochemical performance to those with long-time calcination. …”
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146
Nanostructured transition metal oxide (TMO) for electrochemical devices
Published 2012“…By having large amount of easy accessible intercalation sites, the chemisorptions of cation at oxide-electrolyte interface and the ion intercalation in oxide lattice were greatly promoted. …”
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Thesis -
147
Investigation of Ni as Zn substitute in CZTS thin film solar cell
Published 2018“…In recent years, developments in achieving higher device performance have been halted due to the inherent Voc deficit of CZTSSe. Recent progress in cation substitution of CZTSSe with other metals such as Cd and Ag have shown promising results. …”
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Final Year Project (FYP) -
148
High-entropy spinel oxides for water oxidation: surface entropy evolution and activity promotion
Published 2024“…Removing any one of the cations from this HEO results in a significant decrease in the OER performance. …”
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Journal Article -
149
Analytical assessment of tar generated during gasification of municipal solid waste : distribution of GC–MS detectable tar compounds, undetectable tar residues and inorganic impuri...
Published 2021“…The GC–MS analysis of three types of tar containing solutions (collected tar, gravimetric tar solution and evaporated condensate), gravimetric tar procedure (rotary evaporation and weighing), three separation/isolation methods (adsorption, dilution and decomposition) and quantification of inorganic compounds (cations and anions) were studied. With this sequential analytical procedure, enhanced detection and quantification (EDQ) of GC–MS detectable tar compounds at low concentration and correction on the GC–MS undetectable tar contents based on quantification of inorganic impurities were achieved. …”
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Journal Article -
150
Self-healing materials for flexible electronic devices
Published 2020“…The different ionic liquids (EMITFB and EMITFSI) was used as compared to EMITFS since these ionic liquids have the same cation but different anions. This chapter depicts the study of the influence of ionic liquids on the different class of polymer structure and its effects on the healing properties. …”
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Thesis-Doctor of Philosophy -
151
Ultramafic Alteration and the Cooling of Earth and Mars
Published 2024“…They are incredibly unstable under Earth's surface conditions where they are altered via incongruent reactions which form clay minerals, iron oxides, and ultimately release cations to the ocean. Due to their instability, they play an out-sized role in Earth's long-term carbon cycle. …”
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Thesis -
152
Structural features that affect β2 integrin expression and regulation of adhesion
Published 2013“…It is established that integrin activation is regulated by the divalent cations. However, Mg2+/EGTA (5 mM Mg2+ and 1.5 mM EGTA) had been shown to promote αLβ2 adhesion to ICAM-1 but not αMβ2 adhesion to denatured BSA. …”
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Thesis -
153
Morphology-independent stable white-light emission from self-assembled two-dimensional perovskites driven by strong exciton–phonon coupling to the organic framework
Published 2020“…Here, we present white-light emission from a 2D hybrid lead chloride perovskite, using the widely known phenethylammonium cation. The single-crystal X-ray structural data, time-resolved photophysical measurements, and density functional theory calculations are consistent with broadband emission arising from strong exciton–phonon coupling with the organic lattice, which is independent of surface defects. …”
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Journal Article -
154
Poly(2,5-dihydroxy-1,4-benzoquinonyl sulfide) as an efficient cathode for high-performance aqueous zinc–organic batteries
Published 2021“…Also, under the electrochemical environment, the malleable polymer structure of PDBS permits the rotation and bending of polymer chains to facilitate the insertion/extraction of Zn2+, manifesting the superiority and uniqueness of organic electrode materials in the polyvalent cation storage. Finally, quasi-solid-state batteries based on aqueous gel electrolyte demonstrate highly stable capacity under different bending conditions.…”
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Journal Article -
155
Understanding the mechanisms of methylammonium-induced thermal instability in mixed-FAMA perovskites
Published 2024“…X-ray diffraction (XRD), proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS), photoluminescence (PL) and UV-visible spectroscopy, and depth-profiling X-ray Photoelectron Spectroscopy (XPS) are employed to show that the observed trend is mainly due to the decomposition of the MA+ cation, as opposed to other effects such as the precursor solvent and film morphologies. …”
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Journal Article -
156
Semiconducting photothermal nanoagonist for remote-controlled specific cancer therapy
Published 2018“…The organic nanoagonists comprise semiconducting polymer nanoparticles (SPNs) and capsaicin (Cap) as the photothermally responsive nanocarrier and the agonist for activation of transient receptor potential cation channel subfamily V member 1 (TRPV1), respectively. …”
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Journal Article -
157
Doped amorphous silica nanoparticles as enhancing agents for surface-assisted time-of-flight mass spectrometry
Published 2011“…Alternatively in the absence of such proton donor/acceptor residues as with hydrophobic particles, the primary ions are released from the particles during desorption and form cation adducts as sodiated and potassiated species in the gas phase above the surface.…”
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Journal Article -
158
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159
A Unified Approach to Learning Ising Models: Beyond Independence and Bounded Width
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Article -
160