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121
Topochemical cation exchange reactions of Ruddlesden-Popper oxides
Published 2024“…<p>The work detailed in this thesis focuses on the low-temperature, topochemical cation exchange reactions of a series of some noncentrosymmetric n = 2 pseudo-Ruddlesden-Popper oxides.…”
Thesis -
122
Theory of Cation Solvation and Ionic Association in Nonaqueous Solvent Mixtures
Published 2024“…The complex interplay between these properties can often be elucidated via the coordination environment of the cation. We develop a theory for the coordination shell of cations in nonaqueous solvent mixtures that can be applied with high fidelity, up to extremely high salt concentrations. …”
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Article -
123
Effect of cation composition on the mechanical stability of perovskite solar cells
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Journal Article -
124
Cation-conduction dominated hydrogels for durable zinc–iodine batteries
Published 2024“…Specifically, such a cation-conductive electrolyte results in a high zinc ion transference number (0.81) within the hydrogel and guides epitaxial Zn nucleation. …”
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Journal Article -
125
Oxygen plasma and cation tuning in Ni2P for water oxidation
Published 2019“…Herein, we developed an exceptionally efficient OER electrocatalyst by using core nickel(II) phosphide Ni2P via a series of cation tuning and surface engineering. Interestingly, remarkable results have been shown from the theoretical calculations made through modifications of selective doping of Vanadium together with plasma treatment using oxygen, which increases the overall number of available states at Fermi-level and inproves the overall adsorption of OH− in the Ni sites. …”
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Final Year Project (FYP) -
126
Addition of indoles to oxyallyl cations for facile access to α-indole carbonyl compounds
Published 2013“…A direct coupling of unprotected indoles and α-halo ketones via in situ generated oxyallyl cation intermediates is described. The reactions efficiently afford α-indole carbonyl compounds with good to quantitative yields.…”
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Journal Article -
127
Catalytic hydroboration of carbonyl compounds and pyridine derivatives with the NHC-parent silyliumylidene cation
Published 2020“…This thesis describes the catalytic hydroboration of carbonyl compounds and pyridine derivatives mediated by an N-heterocyclic carbene-parent silyliumylidene cation to give the corresponding borate esters and N-boryl-1,4-dihydropyridine products in good yield, respectively. …”
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Thesis-Master by Research -
128
Cationic carbon monoxide-releasing polymers as antimicrobial and antibiofilm agents by the synergetic activity
Published 2023“…We developed a new-class CO-delivery system by conjugating classical low-molecular-weight CORMs (i.e., [Ru(CO)3Cl2]2 and Mn(CO)5Br) onto a positively charged carrier, polyimidazolium (PIM), giving cationic CO-releasing polymers Ru@PIM and Mn@PIM, respectively. …”
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Journal Article -
129
Elucidation of the ion transport mechanisms in CorA, a divalent cation transporter.
Published 2013“…In this study, I present data showing that M1 is required mainly for protein stabilization leaving M2 acting as a divalent cation sensor. Lastly, I was able to uncover the molecular mechanisms for how Thermotoga maritima CorA selects for Co2+ over Mg2+. …”
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Thesis -
130
Cationic polymer-based antimicrobial and multifunctional hydrogels for enhanced healing of infected wounds
Published 2018Get full text
Final Year Project (FYP) -
131
Chemically bonded cationic β-cyclodextrin derivatives and their applications in supercritical fluid chromatography
Published 2013“…Aromatic cationic moiety on β-CD enabled better enantioseparations than aliphatic cationic moiety. …”
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Journal Article -
132
Interface and surface cation stoichiometry modified by oxygen vacancies in epitaxial manganite films
Published 2013“…Simultaneously, Sr cations migrate towards the film surface and form a SrO rock-salt monolayer. …”
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Journal Article -
133
Understanding electrostatic interaction on strong cation-exchanger via co-ion valency effects
Published 2024“…We performed negative adsorption experiments in high-performance liquid chromatography to measure the excluded volume of co-ions, citrate, or oxalate on strong cation exchange resin. Together with the physical specifications of the column and the deployment of a modified nonlinear Poisson-Boltzmann equation, we identified the effects of the electrolyte composition on the size of the EDL. …”
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Article -
134
Doping and switchable photovoltaic effect in lead-free perovskites enabled by metal cation transmutation
Published 2020“…The effect of heavy metal cation (Bi) transmutation and ionic migration on the defects and carrier properties in a 2D layered perovskite (NH4 )3 (Sb(1-x) Bix )2 I9 system is investigated. …”
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Journal Article -
135
Coion exclusion properties of cation exchange membranes in 2:1 divalent salt solutions
Published 2024“…Commun., 13 (2022)], we analyze cation exchange membrane potential in a 2:1 salt solution, revealing insights into coion selectivity and exclusion mechanisms. …”
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Journal Article -
136
Heavy metal cation probe with signal to noise ratio measurement of fiber Bragg grating
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Journal Article -
137
Cationic cyclodextrins chemically-bonded chiral stationary phases for high-performance liquid chromatography
Published 2013“…Inclusion complexation with CD cavity and columbic/ionic interactions with cationic substituent on the CD rim would afford accentuated retention and enantioseparations of the analytes.…”
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Journal Article -
138
Theory of Layered-Oxide Cathode Degradation in Li-ion Batteries by Oxidation-Induced Cation Disorder
Published 2024“…The general theory of cation-disorder formation may also find applications in electrochemical water treatment and ion separations, such as lithium extraction from brines, based on competitive ion intercalation in battery materials.…”
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Article -
139
Enantioselective epoxidation of protected allylic and homoallylic amines via chiral cationic ion-pairing catalysis
Published 2018Get full text
Thesis-Doctor of Philosophy -
140