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    Measurement report: Molecular-level investigation of atmospheric cluster ions at the tropical high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivia... by Q. Zha, W. Huang, D. Aliaga, O. Peräkylä, L. Heikkinen, A. M. Koenig, C. Wu, J. Enroth, Y. Gramlich, J. Cai, S. Carbone, A. Hansel, T. Petäjä, M. Kulmala, M. Kulmala, M. Kulmala, D. Worsnop, D. Worsnop, V. Sinclair, R. Krejci, M. Andrade, M. Andrade, C. Mohr, F. Bianchi

    Published 2023-04-01
    “…The negative ions mainly consisted of (H<span class="inline-formula"><sub>2</sub></span>SO<span class="inline-formula"><sub>4</sub></span>)<span class="inline-formula"><sub>0–3</sub><span class="Radical">⚫</span></span>HSO<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M4" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi/><mn mathvariant="normal">4</mn><mo>-</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="9pt" height="16pt" class="svg-formula" dspmath="mathimg" md5hash="1b500fe23d5cc239bca0d49063c52557"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00001.svg" width="9pt" height="16pt" src="acp-23-4559-2023-ie00001.png"/></svg:svg></span></span>, (HNO<span class="inline-formula"><sub>3</sub></span>)<span class="inline-formula"><sub>0–2</sub><span class="Radical">⚫</span></span>NO<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M7" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi/><mn mathvariant="normal">3</mn><mo>-</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="9pt" height="16pt" class="svg-formula" dspmath="mathimg" md5hash="76bbd0535ad9c3e987722e2e722d5d00"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00002.svg" width="9pt" height="16pt" src="acp-23-4559-2023-ie00002.png"/></svg:svg></span></span>, SO<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M8" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi/><mn mathvariant="normal">5</mn><mo>-</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="9pt" height="16pt" class="svg-formula" dspmath="mathimg" md5hash="d5acb8c5414090393138b2c9216cbe15"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00003.svg" width="9pt" height="16pt" src="acp-23-4559-2023-ie00003.png"/></svg:svg></span></span>, (NH<span class="inline-formula"><sub>3</sub></span>)<span class="inline-formula"><sub>1–6</sub><span class="Radical">⚫</span></span>(H<span class="inline-formula"><sub>2</sub></span>SO<span class="inline-formula"><sub>4</sub></span>)<span class="inline-formula"><sub>3–7</sub><span class="Radical">⚫</span></span>HSO<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M14" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi/><mn mathvariant="normal">4</mn><mo>-</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="9pt" height="16pt" class="svg-formula" dspmath="mathimg" md5hash="ce9bfed073ac1235ca758fd388570539"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00004.svg" width="9pt" height="16pt" src="acp-23-4559-2023-ie00004.png"/></svg:svg></span></span>, malonic-acid-derived, and CHO <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M15" display="inline" overflow="scroll" dspmath="mathml"><mo>/</mo></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="8pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="7572a9d7afeaa92ba0e8bb6f686362bd"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00005.svg" width="8pt" height="14pt" src="acp-23-4559-2023-ie00005.png"/></svg:svg></span></span> CHON<span class="inline-formula"><span class="Radical">⚫</span></span>(HSO<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M17" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi/><mn mathvariant="normal">4</mn><mo>-</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="9pt" height="16pt" class="svg-formula" dspmath="mathimg" md5hash="9725e18824b1cdf0628403c2cb6d3801"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00006.svg" width="9pt" height="16pt" src="acp-23-4559-2023-ie00006.png"/></svg:svg></span></span> <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M18" display="inline" overflow="scroll" dspmath="mathml"><mo>/</mo></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="8pt" height="14pt" class="svg-formula" dspmath="mathimg" md5hash="62d2c8208bbdf49afb8db19c9f7b6b50"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00007.svg" width="8pt" height="14pt" src="acp-23-4559-2023-ie00007.png"/></svg:svg></span></span> NO<span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M19" display="inline" overflow="scroll" dspmath="mathml"><mrow><msubsup><mi/><mn mathvariant="normal">3</mn><mo>-</mo></msubsup></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="9pt" height="16pt" class="svg-formula" dspmath="mathimg" md5hash="01db1dfc152077444e810c7eff7103ec"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="acp-23-4559-2023-ie00008.svg" width="9pt" height="16pt" src="acp-23-4559-2023-ie00008.png"/></svg:svg></span></span>) cluster ions. …”
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