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Microenvironment engineering for the electrocatalytic CO₂ reduction reaction
Published 2022“…Rather than just focusing on the catalyst itself in the electrocatalytic CO2 reduction reaction (eCO2 RR), as previously reviewed elsewhere, we herein extend the discussion to the special topic of the microenvironment around the electrocatalytic center and present a comprehensive overview of recent research progress. …”
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Catalysis for CO2 activation reactions with light alkanes
Published 2016“…However, the results of thermodynamic calculations and process simulations in DMR project illustrate a good opportunity to utilise flue gas in industry through the so-called Tri- Methane Reforming (TMR). In the DHP by <em>CO</em><sub>2</sub> process, the catalysts developed were less promising than the ones in DMR due to the severe side-reactions occurred which significantly decreased the selectivity for the desired product. …”
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Co-metathesis reaction of crude palm oil and ethene
Published 1995“…The co-metathesis reaction of crude palm oil with ethene in the presence of WCL6/Me4Sn, followed by termination of this reaction with methanol, gives terminal alkenes. …”
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Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines
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Combining Co₃S₄ and Ni:Co₃S₄ nanowires as efficient catalysts for overall water splitting: an experimental and theoretical study
Published 2021“…Following a sulfuration process, Co₃O₄ nanowires are entirely converted into Co₃S₄ nanowires showing greatly improved OER catalytic performances with an overpotential of 283 mV (instead of 371 mV for Co₃O₄) to deliver a current density of 10 mA cm⁻². …”
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Defective materials for CO₂ photoreduction: from C₁ to C₂₊ products
Published 2023“…The key roles of various defects for CO2 photoreduction from various aspects are presented, such as light absorption and electronic structure, charge separation and transfer, reactant adsorption and activation, reaction energy barriers, reaction pathways. …”
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Identifying active sites of nitrogen-doped carbon materials for the CO2 reduction reaction
Published 2020“…In addition, the Gibbs free energy calculated by density functional theory further illustrates the pyridinic N as a more favorable site for the CO2 adsorption, *COOH formation, and *CO removal in CO2 reduction.…”
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Supramolecular macrocycle regulated single-atom MoS2@Co catalysts for enhanced oxygen evolution reaction
Published 2024“…Herein, the design and building of single atom Co sites using a supramolecular tailoring strategy are reported, that is, the introduction of pillar[4]arene[1]quinone (P4A1Q) permits mononuclear Co species stereoelectronically assembled on MoS2 matrix to construct an atomically dispersed MoS2@Co catalyst with modulated local electronic structure, definite chemical environment and enhanced oxygen evolution reaction performance. …”
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Heterojunction‐assisted Co3S4@Co3O4 core – shell octahedrons for supercapacitors and both oxygen and carbon dioxide reduction reactions
Published 2020“…Expedition of electron transfer efficiency and optimization of surface reactant adsorption products desorption processes are two main challenges for developing non-noble catalysts in the oxygen reduction reaction (ORR) and CO2 reduction reaction (CRR). A heterojunction prototype on Co3 S4 @Co3 O4 core-shell octahedron structure is established via hydrothermal lattice anion exchange protocol to implement the electroreduction of oxygen and carbon dioxide with high performance. …”
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The reaction of Cp*Ir(CO)(CI)(p-C6F4CN) with nucleophiles.
Published 2010“…The reactions of Cp*Ir(CO)(Cl)(p-C6F4CN) with nucleophiles such as NaOMe and NaH were conducted. …”
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Final Year Project (FYP) -
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Identifying influential parameters of octahedrally coordinated cations in spinel ZnMnₓCo₂–ₓO₄ oxides for the oxidation reaction
Published 2021“…Herein, a series of ZnMnxCo2-xO4 (x = 0-2.0) spinel oxides are investigated, employing CO oxidation as the model reaction, with particular attention being paid to the variation in activity caused by tuning the ratio of octahedrally occupied Mn to Co. …”
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Enlarged Co-O covalency in octahedral sites leading to highly efficient spinel oxides for oxygen evolution reaction
Published 2020“…Cobalt-containing spinel oxides are promising electrocatalysts for the oxygen evolution reaction (OER) owing to their remarkable activity and durability. …”
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Modified Ni-carbonate interfaces for enhanced CO₂ methanation activity: tuned reaction pathway and reconstructed surface carbonates
Published 2022“…A Ni/Zr-La2O2CO3 catalyst with interfaces between Ni metal and Zr-modified carbonate support was used for atmospheric CO2 methanation reaction, exhibiting 81% conversion and 99.6% CH4 selectivity at 300 °C. …”
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Realizing high and stable electrocatalytic oxygen evolution for iron-based perovskites by co-doping-induced structural and electronic modulation
Published 2022“…Oxygen evolution reaction (OER) is a vital electrochemical process for various energy conversion and fuel production technologies. …”
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The formation of aldehydes from the photochemically activated reaction of Cp*Ir(CO)(Cl)(CH2R) complexes with water
Published 2013“…The iridium complexes Cp*Ir(CO)(Cl)(CH2R), which do not contain any β-hydrogen atoms, react with water to form aldehydes. …”
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Electrocatalytic activity of LiCo1-xFexO2 (0 ≤ x ≤ 1) for oxygen evolution reaction in alkaline medium
Published 2016“…The OER activities of LiCoO2, LiFeO2 and the mixed LiCo1-xFexO2 synthesized by low temperature sol-gel method were investigated. …”
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Final Year Project (FYP) -
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Misfit-layered Bi1.85Sr2Co1.85O7.7−δ for the hydrogen evolution reaction : beyond van der Waals heterostructures
Published 2015“…The performance of such misfit-layered chalcogenides in electrochemical applications, specifically the hydrogen evolution reaction, is currently unexplored. Herein, a misfit-layered chalcogenide consisting of CoO2 layers interleaved with an SrO–BiO–BiO–SrO rock-salt block and having the formula Bi1.85Sr2Co1.85O7.7−δ is synthesized and examined for its structural and electrochemical properties. …”
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Organic dye-photocatalyzed acylnitroso ene reaction
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Journal Article