Rheological and thermal stability of cationic-modified diutan gum biopolymer
Cationic diutan gum (CDG) biopolymer has been developed by incorporating a quaternary amine group on diutan gum (DG) structure to improve the thermal and rheological properties. The modification was performed by mixing DG with different N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride (CHPTA...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Universiti Kebangsaan Malaysia
2020
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/30873/1/Rheological%20and%20thermal%20stability%20of%20cationic-modified%20diutan.pdf |
| _version_ | 1825813761774059520 |
|---|---|
| author | Norhanis, Arbaa′In Rasidi, Roslan Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim |
| author_facet | Norhanis, Arbaa′In Rasidi, Roslan Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim |
| author_sort | Norhanis, Arbaa′In |
| collection | UMP |
| description | Cationic diutan gum (CDG) biopolymer has been developed by incorporating a quaternary amine group on diutan gum (DG) structure to improve the thermal and rheological properties. The modification was performed by mixing DG with different N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride (CHPTAC) concentration to produce CDG in the presence of sodium hydroxide. The FTIR results confirmed the incorporation of cationic moieties onto the CDG chains. The surface morphology observed through FESEM showed that the smooth surface of DG was converted to a connective spherical reticular structure upon CHPTAC modification. The viscosity of CDG gelling fluid was increased after modification due to electrostatic chain interaction. Rheological properties showed that the plateau-like region was observed which signifying a stable gel response towards frequency. Thermal stability analysis using static thermal aging test showed the CDG was stable up to 170 °C suggesting this biopolymer can withstand the high-temperature requirements of the upstream petroleum industry. |
| first_indexed | 2024-03-06T12:48:50Z |
| format | Article |
| id | UMPir30873 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:48:50Z |
| publishDate | 2020 |
| publisher | Universiti Kebangsaan Malaysia |
| record_format | dspace |
| spelling | UMPir308732021-06-30T14:18:07Z http://umpir.ump.edu.my/id/eprint/30873/ Rheological and thermal stability of cationic-modified diutan gum biopolymer Norhanis, Arbaa′In Rasidi, Roslan Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim TP Chemical technology Cationic diutan gum (CDG) biopolymer has been developed by incorporating a quaternary amine group on diutan gum (DG) structure to improve the thermal and rheological properties. The modification was performed by mixing DG with different N-(3-chloro-2-hydroxypropyl) trimethyl ammonium chloride (CHPTAC) concentration to produce CDG in the presence of sodium hydroxide. The FTIR results confirmed the incorporation of cationic moieties onto the CDG chains. The surface morphology observed through FESEM showed that the smooth surface of DG was converted to a connective spherical reticular structure upon CHPTAC modification. The viscosity of CDG gelling fluid was increased after modification due to electrostatic chain interaction. Rheological properties showed that the plateau-like region was observed which signifying a stable gel response towards frequency. Thermal stability analysis using static thermal aging test showed the CDG was stable up to 170 °C suggesting this biopolymer can withstand the high-temperature requirements of the upstream petroleum industry. Universiti Kebangsaan Malaysia 2020-10 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/30873/1/Rheological%20and%20thermal%20stability%20of%20cationic-modified%20diutan.pdf Norhanis, Arbaa′In and Rasidi, Roslan and Izan Izwan, Misnon and Mohd Hasbi, Ab. Rahim (2020) Rheological and thermal stability of cationic-modified diutan gum biopolymer. Sains Malaysiana, 49 (10). pp. 2547-2557. ISSN 0126-6039. (Published) http://dx.doi.org/10.17576/jsm-2020-4910-20 http://dx.doi.org/10.17576/jsm-2020-4910-20 |
| spellingShingle | TP Chemical technology Norhanis, Arbaa′In Rasidi, Roslan Izan Izwan, Misnon Mohd Hasbi, Ab. Rahim Rheological and thermal stability of cationic-modified diutan gum biopolymer |
| title | Rheological and thermal stability of cationic-modified diutan gum biopolymer |
| title_full | Rheological and thermal stability of cationic-modified diutan gum biopolymer |
| title_fullStr | Rheological and thermal stability of cationic-modified diutan gum biopolymer |
| title_full_unstemmed | Rheological and thermal stability of cationic-modified diutan gum biopolymer |
| title_short | Rheological and thermal stability of cationic-modified diutan gum biopolymer |
| title_sort | rheological and thermal stability of cationic modified diutan gum biopolymer |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/30873/1/Rheological%20and%20thermal%20stability%20of%20cationic-modified%20diutan.pdf |
| work_keys_str_mv | AT norhanisarbaain rheologicalandthermalstabilityofcationicmodifieddiutangumbiopolymer AT rasidiroslan rheologicalandthermalstabilityofcationicmodifieddiutangumbiopolymer AT izanizwanmisnon rheologicalandthermalstabilityofcationicmodifieddiutangumbiopolymer AT mohdhasbiabrahim rheologicalandthermalstabilityofcationicmodifieddiutangumbiopolymer |