Stereoselective synthesis of hernandulcin, peroxylippidulcine A, lippidulcines A, B and C and taste evaluation

Stereoselective synthesis of hernandulcin, peroxylippidulcine A, lippidulcines A, B and C and taste evaluation

The first stereoselective synthesis of lippidulcines A, B and C has been accomplished starting from (+)-hernandulcin, which has been prepared on a multigram scale. The previously assigned absolute configurations have been confirmed. The key steps of this synthesis are based on a modified version of...

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Bibliographic Details
Main Authors: Marco G. Rigamonti, Francesco G. Gatti
Format: Article
Language:English
Published: Beilstein-Institut 2015-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
ADH ketone reduction
cooling agent
Corey–Bakshi–Shibata reduction
dehydrogenation
hernandulcin
Kornblum–DeLaMare rearrangement
lippidulcines
Saegusa–Larock
Online Access:https://doi.org/10.3762/bjoc.11.228

Internet

https://doi.org/10.3762/bjoc.11.228

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