Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks
The paper presents the results of experimental studies on the production of fine char powder from sunflower seed husks by a novel method of thermomechanical treatment with pulsed shock waves and supersonic jets of the mixture of ultra-superheated (above 2000 °C) steam and carbon dioxide, as well as...
| Main Authors: | , , , , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-09-01
|
| Series: | Powders |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2674-0516/2/3/39 |
| _version_ | 1827724131489021952 |
|---|---|
| author | Sergey M. Frolov Anton S. Silantiev Ilias A. Sadykov Viktor A. Smetanyuk Fedor S. Frolov Yaroslav K. Hasiak Tatiana V. Dudareva Valentin G. Bekeshev Maksim V. Grishin Evgeniy K. Golubev Dinara Baimukhambetova Vera Ya. Popkova Alexander I. Vezentsev Alexander E. Razdobarin Maxim N. Yapryntsev Pavel V. Sokolovskiy |
| author_facet | Sergey M. Frolov Anton S. Silantiev Ilias A. Sadykov Viktor A. Smetanyuk Fedor S. Frolov Yaroslav K. Hasiak Tatiana V. Dudareva Valentin G. Bekeshev Maksim V. Grishin Evgeniy K. Golubev Dinara Baimukhambetova Vera Ya. Popkova Alexander I. Vezentsev Alexander E. Razdobarin Maxim N. Yapryntsev Pavel V. Sokolovskiy |
| author_sort | Sergey M. Frolov |
| collection | DOAJ |
| description | The paper presents the results of experimental studies on the production of fine char powder from sunflower seed husks by a novel method of thermomechanical treatment with pulsed shock waves and supersonic jets of the mixture of ultra-superheated (above 2000 °C) steam and carbon dioxide, as well as the results of examination of the produced char powder in terms of its chemical, phase, and granulometric composition and structural, morphological, and texture characteristics. The objective of the research is to explore the possibility of using the resulting char powder as a sorption-active material for organic substances. It is shown that the obtained char particles and their agglomerates have an average size of 20–30 nm and 12–24 µm, respectively, have the shape of disks and ellipsoids, consist mainly of amorphous carbon (up to 56 wt%) and oxygen (up to 42 wt%), and have a specific surface area of 1.1–1.7 m<sup>2</sup>/g. It is concluded that such a char powder can be used as an absorbent for organic substances when dried and deagglomerated. |
| first_indexed | 2024-03-10T22:09:55Z |
| format | Article |
| id | doaj.art-0071165069a84a8cb81dfbbd6cd34e28 |
| institution | Directory Open Access Journal |
| issn | 2674-0516 |
| language | English |
| last_indexed | 2024-03-10T22:09:55Z |
| publishDate | 2023-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Powders |
| spelling | doaj.art-0071165069a84a8cb81dfbbd6cd34e282023-11-19T12:37:04ZengMDPI AGPowders2674-05162023-09-012362463810.3390/powders2030039Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed HusksSergey M. Frolov0Anton S. Silantiev1Ilias A. Sadykov2Viktor A. Smetanyuk3Fedor S. Frolov4Yaroslav K. Hasiak5Tatiana V. Dudareva6Valentin G. Bekeshev7Maksim V. Grishin8Evgeniy K. Golubev9Dinara Baimukhambetova10Vera Ya. Popkova11Alexander I. Vezentsev12Alexander E. Razdobarin13Maxim N. Yapryntsev14Pavel V. Sokolovskiy15Federal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaFederal Research Center for Chemical Physics of the Russian Academy of Sciences (FRC), 119991 Moscow, RussiaDepartment of General Chemistry, National Research University “Belgorod State University” (BSU), 308015 Belgorod, RussiaDepartment of General Chemistry, National Research University “Belgorod State University” (BSU), 308015 Belgorod, RussiaDepartment of General Chemistry, National Research University “Belgorod State University” (BSU), 308015 Belgorod, RussiaEnikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393 Moscow, RussiaThe paper presents the results of experimental studies on the production of fine char powder from sunflower seed husks by a novel method of thermomechanical treatment with pulsed shock waves and supersonic jets of the mixture of ultra-superheated (above 2000 °C) steam and carbon dioxide, as well as the results of examination of the produced char powder in terms of its chemical, phase, and granulometric composition and structural, morphological, and texture characteristics. The objective of the research is to explore the possibility of using the resulting char powder as a sorption-active material for organic substances. It is shown that the obtained char particles and their agglomerates have an average size of 20–30 nm and 12–24 µm, respectively, have the shape of disks and ellipsoids, consist mainly of amorphous carbon (up to 56 wt%) and oxygen (up to 42 wt%), and have a specific surface area of 1.1–1.7 m<sup>2</sup>/g. It is concluded that such a char powder can be used as an absorbent for organic substances when dried and deagglomerated.https://www.mdpi.com/2674-0516/2/3/39pulsed detonation gunultra-superheated steam and carbon dioxideagricultural wastewaste recyclingsunflower seed huskchar powder |
| spellingShingle | Sergey M. Frolov Anton S. Silantiev Ilias A. Sadykov Viktor A. Smetanyuk Fedor S. Frolov Yaroslav K. Hasiak Tatiana V. Dudareva Valentin G. Bekeshev Maksim V. Grishin Evgeniy K. Golubev Dinara Baimukhambetova Vera Ya. Popkova Alexander I. Vezentsev Alexander E. Razdobarin Maxim N. Yapryntsev Pavel V. Sokolovskiy Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks Powders pulsed detonation gun ultra-superheated steam and carbon dioxide agricultural waste waste recycling sunflower seed husk char powder |
| title | Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks |
| title_full | Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks |
| title_fullStr | Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks |
| title_full_unstemmed | Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks |
| title_short | Composition and Textural Characteristics of Char Powders Produced by Thermomechanical Processing of Sunflower Seed Husks |
| title_sort | composition and textural characteristics of char powders produced by thermomechanical processing of sunflower seed husks |
| topic | pulsed detonation gun ultra-superheated steam and carbon dioxide agricultural waste waste recycling sunflower seed husk char powder |
| url | https://www.mdpi.com/2674-0516/2/3/39 |
| work_keys_str_mv | AT sergeymfrolov compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT antonssilantiev compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT iliasasadykov compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT viktorasmetanyuk compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT fedorsfrolov compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT yaroslavkhasiak compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT tatianavdudareva compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT valentingbekeshev compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT maksimvgrishin compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT evgeniykgolubev compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT dinarabaimukhambetova compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT verayapopkova compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT alexanderivezentsev compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT alexandererazdobarin compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT maximnyapryntsev compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks AT pavelvsokolovskiy compositionandtexturalcharacteristicsofcharpowdersproducedbythermomechanicalprocessingofsunflowerseedhusks |