Single-Molecule Magnets Based on Heteroleptic Terbium(III) Trisphthalocyaninate in Solvent-Free and Solvent-Containing Forms

Single-Molecule Magnets Based on Heteroleptic Terbium(III) Trisphthalocyaninate in Solvent-Free and Solvent-Containing Forms

Binuclear heteroleptic triple-decker terbium(III) phthalocyaninate (Pc)Tb[(15C5)<sub>4</sub>Pc]Tb(Pc), where Pc<sup>2−</sup> is phthalocyaninate dianion and 15C5 is a 15-crown-5 moiety, has been synthesized as a solvent-free powder (<b>1</b>) and a well-defined cr...

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Bibliographic Details
Main Authors: Maxim A. Faraonov, Alexander G. Martynov, Marina A. Polovkova, Salavat S. Khasanov, Yulia G. Gorbunova, Aslan Yu. Tsivadze, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev
Format: Article
Language:English
Published: MDPI AG 2023-01-01
Series:Magnetochemistry
Subjects:
terbium
binuclear complex
phthalocyanine
single-molecule magnet
ferromagnetic coupling
spin-reversal energy barriers
Online Access:https://www.mdpi.com/2312-7481/9/2/36

Internet

https://www.mdpi.com/2312-7481/9/2/36

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