Beyond n-dopants for organic semiconductors: use of bibenzo[d]imidazoles in UV-promoted dehalogenation reactions of organic halides

Beyond n-dopants for organic semiconductors: use of bibenzo[d]imidazoles in UV-promoted dehalogenation reactions of organic halides

2,2’-Bis(4-dimethylaminophenyl)- and 2,2'-dicyclohexyl-1,1',3,3'-tetramethyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d]imidazole ((N-DMBI)2 and (Cyc-DMBI)2) are quite strong reductants with effective potentials of ca. −2 V vs ferrocenium/ferrocene, yet are relatively stable t...

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Bibliographic Details
Main Authors: Kan Tang, Megan R. Brown, Chad Risko, Melissa K. Gish, Garry Rumbles, Phuc H. Pham, Oana R. Luca, Stephen Barlow, Seth R. Marder
Format: Article
Language:English
Published: Beilstein-Institut 2023-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
dehalogenation
n-dopant
reduction
reductive dimerization
Online Access:https://doi.org/10.3762/bjoc.19.142

Internet

https://doi.org/10.3762/bjoc.19.142

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