Synthesis, Crystal Structure, and Chemical-Bonding Analysis of BaZn(NCN)2

The ternary carbodiimide BaZn(NCN)2 was prepared by a solid-state metathesis reaction between BaF2, ZnF2, and Li2NCN in a 1:1:2 molar ratio, and its crystal structure was determined from Rietveld refinement of X-ray data. BaZn(NCN)2 represents the aristotype of the LiBa2Al(NCN)4 structure which is u...

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Bibliographic Details
Main Authors: Alex J. Corkett, Philipp M. Konze, Richard Dronskowski
Format: Article
Language:English
Published: MDPI AG 2017-12-01
Series:Inorganics
Subjects:
Online Access:https://www.mdpi.com/2304-6740/6/1/1