Developing Photoactive Coumarin-Caged <i>N</i>-Hydroxysulfonamides for Generation of Nitroxyl (HNO)

Developing Photoactive Coumarin-Caged <i>N</i>-Hydroxysulfonamides for Generation of Nitroxyl (HNO)

Photoactive <i>N</i>-hydroxysulfonamides photocaged with the (6-bromo-7-hydroxycoumarin-4-yl)methyl chromophore have been successfully synthesized, and the mechanisms of photodecomposition investigated for two of the compounds. Upon irradiation up to 97% of a diagnostic marker for (H)NO...

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Bibliographic Details
Main Authors: Mohammad S. Rahman, Vinay Bharadwaj, Anau K. H. S. Lautaha, Paul Sampson, Nicola E. Brasch, Alexander J. Seed
Format: Article
Language:English
Published: MDPI AG 2024-08-01
Series:Molecules
Subjects:
nitroxyl
HNO
photochemistry
photocage
<i>N</i>-hydroxysulfonamide
Piloty’s acid
Online Access:https://www.mdpi.com/1420-3049/29/16/3918

Internet

https://www.mdpi.com/1420-3049/29/16/3918

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