Crystal structure of (4,4′-bipyridyl-κN)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc(II)–4,4′-bipyridyl (2/1) and its isostructural cadmium(II) analogue

Crystal structure of (4,4′-bipyridyl-κN)bis[N-(2-hydroxyethyl)-N-isopropyldithiocarbamato-κ2S,S′]zinc(II)–4,4′-bipyridyl (2/1) and its isostructural cadmium(II) analogue

The title structures, [M(C6H12NOS2)2(C10H8N2)]·0.5C10H8N2, for M = Zn, (I), and Cd, (II), feature terminally bound 4,4′-bipyridyl ligands and non-coordinating 4,4′-bipyridyl molecules, with the latter disposed about a centre of inversion. The coordination geometry about the metal atom is defined by...

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Bibliographic Details
Main Authors: Yee Seng Tan, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2017-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zinc
cadmium
dithiocarbamate
4,4′-bipyridine
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017014396

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http://scripts.iucr.org/cgi-bin/paper?S2056989017014396

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