Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser Irradiation

The effect of KrF excimer laser irradiation on the optical and electrical properties of epitaxial wafers with a <i>p</i>-GaN surface were investigated at different laser energy densities and pulse numbers. The laser-irradiated samples were annealed in oxygen. The laser irradiation-induce...

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Main Authors: Yijian Jiang, Haoqi Tan, Yan Zhao
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Symmetry
Subjects:
Online Access:https://www.mdpi.com/2073-8994/13/10/1935
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author Yijian Jiang
Haoqi Tan
Yan Zhao
author_facet Yijian Jiang
Haoqi Tan
Yan Zhao
author_sort Yijian Jiang
collection DOAJ
description The effect of KrF excimer laser irradiation on the optical and electrical properties of epitaxial wafers with a <i>p</i>-GaN surface were investigated at different laser energy densities and pulse numbers. The laser-irradiated samples were annealed in oxygen. The laser irradiation-induced changes in optical and electrical properties of GaN epitaxial wafers were examined using PL, I–V, XPS, SIMS, and Hall effect measurements. Experimental results show that under an appropriate laser-irradiated condition, optical and electrical properties of the samples were improved to different degrees. The samples which were annealed after laser irradiation have better electrical properties such as the hole concentration and sheet resistance than those without annealing. We hypothesize that the pulsed KrF excimer laser irradiation dissociates the Mg–H complexes and annealing treatment allows the hydrogen to diffuse out more completely under the oxygen atmosphere at a proper temperature, by which the crystalline symmetry of GaN is improved. Under appropriate laser conditions and O<sub>2</sub>-activated annealing, the light output of the laser-irradiated GaN-based LED sample is about 1.44 times that of a conventional LED at 20 mA. It is found that the wall-plug efficiency is 10% higher at 20 mA and the reverse leakage current is 80% lower at 5 V.
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spelling doaj.art-02694263c095410fb10002b229e967cc2023-11-22T20:11:17ZengMDPI AGSymmetry2073-89942021-10-011310193510.3390/sym13101935Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser IrradiationYijian Jiang0Haoqi Tan1Yan Zhao2Institute of Laser Engineering, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, ChinaInstitute of Laser Engineering, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, ChinaInstitute of Laser Engineering, Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing 100124, ChinaThe effect of KrF excimer laser irradiation on the optical and electrical properties of epitaxial wafers with a <i>p</i>-GaN surface were investigated at different laser energy densities and pulse numbers. The laser-irradiated samples were annealed in oxygen. The laser irradiation-induced changes in optical and electrical properties of GaN epitaxial wafers were examined using PL, I–V, XPS, SIMS, and Hall effect measurements. Experimental results show that under an appropriate laser-irradiated condition, optical and electrical properties of the samples were improved to different degrees. The samples which were annealed after laser irradiation have better electrical properties such as the hole concentration and sheet resistance than those without annealing. We hypothesize that the pulsed KrF excimer laser irradiation dissociates the Mg–H complexes and annealing treatment allows the hydrogen to diffuse out more completely under the oxygen atmosphere at a proper temperature, by which the crystalline symmetry of GaN is improved. Under appropriate laser conditions and O<sub>2</sub>-activated annealing, the light output of the laser-irradiated GaN-based LED sample is about 1.44 times that of a conventional LED at 20 mA. It is found that the wall-plug efficiency is 10% higher at 20 mA and the reverse leakage current is 80% lower at 5 V.https://www.mdpi.com/2073-8994/13/10/1935excimer laser irradiationGaN epitaxial wafersGaN-based LEDoptical propertyelectrical property
spellingShingle Yijian Jiang
Haoqi Tan
Yan Zhao
Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser Irradiation
Symmetry
excimer laser irradiation
GaN epitaxial wafers
GaN-based LED
optical property
electrical property
title Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser Irradiation
title_full Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser Irradiation
title_fullStr Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser Irradiation
title_full_unstemmed Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser Irradiation
title_short Improving Optical and Electrical Properties of GaN Epitaxial Wafers and Enhancing Luminescent Properties of GaN-Based Light-Emitting-Diode with Excimer Laser Irradiation
title_sort improving optical and electrical properties of gan epitaxial wafers and enhancing luminescent properties of gan based light emitting diode with excimer laser irradiation
topic excimer laser irradiation
GaN epitaxial wafers
GaN-based LED
optical property
electrical property
url https://www.mdpi.com/2073-8994/13/10/1935
work_keys_str_mv AT yijianjiang improvingopticalandelectricalpropertiesofganepitaxialwafersandenhancingluminescentpropertiesofganbasedlightemittingdiodewithexcimerlaserirradiation
AT haoqitan improvingopticalandelectricalpropertiesofganepitaxialwafersandenhancingluminescentpropertiesofganbasedlightemittingdiodewithexcimerlaserirradiation
AT yanzhao improvingopticalandelectricalpropertiesofganepitaxialwafersandenhancingluminescentpropertiesofganbasedlightemittingdiodewithexcimerlaserirradiation