Crystal structures of 2-benzylamino-4-(4-bromophenyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile and 2-benzylamino-4-(4-chlorophenyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile

Crystal structures of 2-benzylamino-4-(4-bromophenyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile and 2-benzylamino-4-(4-chlorophenyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile

In the title compounds, C24H22BrN3, (I), and C24H22ClN3, (II), the 2-aminopyridine ring is fused with a cycloheptane ring, which adopts a half-chair conformation. The planes of the phenyl and benzene rings are inclined to that of the central pyridine ring [r.m.s. deviations = 0.0083 (1) and 0.0093 (...

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Bibliographic Details
Main Authors: R. A. Nagalakshmi, J. Suresh, S. Maharani, R. Ranjith Kumar, P. L. Nilantha Lakshman
Format: Article
Language:English
Published: International Union of Crystallography 2015-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
cyclohepta[b]pyridine
carbonitrile
hydrogen bonding
π–π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989014025936

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http://scripts.iucr.org/cgi-bin/paper?S2056989014025936

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