Radical and Ionic Mechanisms in Rearrangements of <i>o</i>-Tolyl Aryl Ethers and Amines Initiated by the Grubbs–Stoltz Reagent, Et<sub>3</sub>SiH/KO<i><sup>t</sup></i>Bu

Radical and Ionic Mechanisms in Rearrangements of <i>o</i>-Tolyl Aryl Ethers and Amines Initiated by the Grubbs–Stoltz Reagent, Et<sub>3</sub>SiH/KO<i><sup>t</sup></i>Bu

Rearrangements of <i>o-</i>tolyl aryl ethers, amines, and sulfides with the Grubbs–Stoltz reagent (Et<sub>3</sub>SiH + KO<i><sup>t</sup></i>Bu) were recently announced, in which the ethers were converted to <i>o</i>-hydroxydiarylmethanes, w...

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Bibliographic Details
Main Authors: Krystian Kolodziejczak, Alexander J. Stewart, Tell Tuttle, John A. Murphy
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Molecules
Subjects:
Truce–Smiles rearrangement
Grubbs–Stoltz reagent
radical
electron transfer
aryl substitution
diarylmethanes
Online Access:https://www.mdpi.com/1420-3049/26/22/6879

Internet

https://www.mdpi.com/1420-3049/26/22/6879

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